Graphene-Modified Carbon Fiber Fabrication at Reduced Temperatures

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Solution Overview

Problem

Conventional methods for producing high-performance carbon fiber require graphitization at extremely high temperatures, making the process costly and limiting the production of high-performance carbon fibers like PAN-based and pitch-based fibers.

Innovation Solution

A graphene carbon fiber composition incorporating nano-sized graphene powder is used, which serves as a seed for forming nano ribbon-shaped graphite during the graphitization process, allowing for high-performance carbon fiber production at temperatures lower than 2,500°C, specifically between 1,500°C to 2,000°C.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If conventional graphitization process is used to fabricate high-performance carbon fiber, then tensile modulus of 350 GPa or more is achieved, but graphitization temperature must be maintained at 2,500°C or higher

Engineering Contradiction:
Improvetensile modulusVSAvoidgraphitization temperature
Core Design Contradiction:
StrengthVSTemperature

Solution Approach 1:

Graphene nanopowder is introduced as an intermediary substance that facilitates graphitization at lower temperatures. The graphene particles act as catalysts or nucleation sites, enabling the formation of graphite structures and achieving high tensile modulus without requiring conventional high-temperature graphitization of 2,500°C or higher

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The invention changes the chemical composition parameters of the carbon fiber precursor by incorporating graphene nanopowder. This compositional modification alters the graphitization behavior, allowing the material to achieve graphite crystalline structure at reduced temperatures (below 2,500°C) while maintaining the required mechanical properties

Inventive Principle:
Principle #35Parameter changes

2Strength

If graphitization is performed at 2,500°C or higher to produce high-performance carbon fiber, then excellent physical properties are obtained, but production cost increases significantly

Engineering Contradiction:
Improvephysical propertiesVSAvoidproduction cost
Core Design Contradiction:
StrengthVSEase of manufacture

Solution Approach 1:

By modifying the chemical composition through graphene addition, the processing temperature parameter is reduced from 2,500°C to below 2,500°C. This parameter change directly lowers energy consumption and equipment requirements, thereby reducing production cost while preserving physical properties

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

Graphene nanopowder serves as a mediating substance that enables low-temperature graphitization. Its presence allows the system to achieve the same graphitization effect at lower temperatures, eliminating the need for expensive high-temperature processing infrastructure and reducing overall manufacturing costs

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach reduces the graphitization temperature, enabling the fabrication of high-performance carbon fibers with excellent physical properties, such as a tensile modulus of 350 GPa or more, while minimizing production costs.

Implementation Method 1

a graphitization process should be performed at a very high temperature of about 2,500° C. or greater during the preparation process

Methodology Applied
Scientific EffectGraphitization:

Implementation Method 2

graphene powder, wherein the graphene powder serves as a seed of graphite to be formed during carbon fiber fabricating processes

Methodology Applied
Scientific EffectNucleation: Nucleation

Implementation Method 3

a heat treatment step of fabricating nano ribbon-shaped graphite by graphitization the stabilized the fibers at a temperature less than 2,500° C.

Methodology Applied
Scientific EffectHeat treatment: Heat Treatment

Data Source

PatentUS10407801B2Carbon fiber composition including graphene nano-powder and fabrication method for carbon fiber using the same
Publication Date: 2019.09.10 KOREA INST OF SCI & TECH
  • US10407801B2 patent drawing
  • US10407801B2 patent drawing
  • US10407801B2 patent drawing

AI summary

The present disclosure relates to a carbon fiber composition and a fabrication method for high-performance carbon fiber using the same. The method can fabricate high-performance carbon fiber (or graphite fiber) with lowering a graphitization temperature by using graphene carbon fiber composition including nano-sized graphene.