Graphene Carbon Nanostructure Heating Element for Automotive Defrosting

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Solution Overview

Problem

Resistance heating elements, such as those used in automobile rear windows, face challenges in achieving conductivity and durability comparable to silver-based elements while being cost-effective and environmentally friendly.

Innovation Solution

A resistance heating element composed of 10% to 45% graphene, 0.25% to 45% carbon nanostructure material, and the remainder glass frit, with a coupling agent bonding the graphene and carbon nanostructure with the glass frit, replacing metallic silver and using a low-melting glass frit to sinter and bond with the substrate.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If metallic silver is used as the heating element material, then conductivity and durability are improved, but material cost and environmental impact worsen

Engineering Contradiction:
Improveconductivity and durabilityVSAvoidmaterial cost and environmental impact
Core Design Contradiction:
ReliabilityVSQuantity of substance

Solution Approach 1:

The patent changes the material composition parameters by replacing metallic silver with a composite of graphene (10-45 wt%), carbon nanostructure material (0.25-45 wt%), and glass frit (remainder). This parameter substitution maintains electrical conductivity and durability while reducing material cost and environmental impact, as carbon-based materials are more abundant and less expensive than silver

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs a composite material system combining graphene, carbon nanotubes (or other carbon nanostructures), and glass frit. The coupling agent bonds these components together to form a continuous electrically conductive path. This composite approach achieves silver-comparable performance through synergistic combination of materials with complementary properties

Inventive Principle:
Principle #40Composite materials

2Quantity of substance

If graphene and carbon nanostructure material are used to replace silver, then material cost is reduced, but achieving comparable conductivity and durability becomes more difficult

Engineering Contradiction:
Improvematerial costVSAvoidconductivity and durability
Core Design Contradiction:
Quantity of substanceVSReliability

Solution Approach 1:

The patent introduces a coupling agent as an intermediary substance that bonds graphene and carbon nanostructure material with glass frit. This coupling agent is critical for achieving proper adhesion and forming continuous conductive paths, enabling the carbon-based composite to reach conductivity and durability levels comparable to silver-based elements

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The glass frit component serves multiple functions: it acts as a binder holding the conductive materials together, provides adhesion to the substrate (e.g., glass window), and contributes to the overall structural integrity. This multi-functionality helps achieve silver-comparable durability while maintaining cost advantages

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution provides a durable and conductive heating element with performance similar to silver-based elements, while reducing material costs and environmental impact by using less dense carbon-based materials and a low-melting glass frit, forming a continuous electrically conductive path.

Implementation Method 1

The graphene and the CNS material include a coupling agent bonding the graphene and the carbon nanostructure material with at least the glass frit

Methodology Applied
Scientific EffectChemical Bonding: Chemical Bonding

Implementation Method 2

The paste is then heated to sinter and bond the silver and glass frit, thereby forming a continuous electrically conductive path

Methodology Applied
Scientific EffectJoule Heating: Joule Heating

Implementation Method 3

The paste is then heated to sinter and bond the silver and glass frit

Methodology Applied
Scientific EffectMelting: Melting

Implementation Method 4

The paste is then heated to sinter and bond the silver and glass frit

Methodology Applied
Scientific EffectSintering: Sintering

Data Source

PatentUS20230051813A1Graphene/carbon nanostructure heating element
Publication Date: 2023.02.16 FORD GLOBAL TECH LLC
  • US20230051813A1 patent drawing
  • US20230051813A1 patent drawing

AI summary

An article includes a substrate and a resistance heating element bonded to the substrate. The resistance heating element is comprised of, by weight, 10 to 45% of graphene, 0.25 to 45% of carbon nanostructure (CNS) material different than the graphene, and a remainder of glass frit. The graphene and the CNS material include a coupling agent that bonds the graphene and the CNS material with at least the glass frit.