Graphene-Coated Copper Composite for Ultra-Conductive Bulk Forms

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Solution Overview

Problem

Current methods for synthesizing ultra-conductive copper (UCC) face challenges such as high energy expenditure, long processing times, defects, impurities, and high costs, making it difficult to achieve bulk scale commercial production with electrical conductivity above 100% International Annealed Copper Standard (IACS).

Innovation Solution

A method involving coating metal components with single- or multi-layer graphene sheets using chemical vapor deposition or graphene ink, followed by forming a bulk metal-graphene composite through processes like hot extrusion, which distributes graphene throughout the metal matrix primarily oriented horizontally, enhancing electrical conductivity beyond conventional copper grades.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional methods (deformation processing, vapor phase processing, solidification processing) are used to synthesize ultra-conductive copper, then electrical conductivity above 100% IACS is targeted, but high energy expenditure and long processing time occur

Engineering Contradiction:
Improveelectrical conductivityVSAvoidenergy expenditure
Core Design Contradiction:
ReliabilityVSUse of energy by moving object

Solution Approach 1:

The patent applies preliminary action by pre-coating copper substrates with graphene layers before final forming operations. The copper foil is first coated with a graphene slurry suspension, dried, and then sintered to form a graphene-copper composite precursor. This preliminary graphene coating is then incorporated into the final ultra-conductive copper product through controlled deformation or solidification processes, achieving >100% IACS conductivity without requiring high-energy post-processing

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent utilizes parameter changes by controlling the graphene concentration, slurry viscosity, and sintering temperature to optimize the graphene-copper composite structure. By adjusting these parameters, the patent achieves optimal electrical conductivity (>100% IACS) while minimizing energy expenditure during processing, as the graphene network formation occurs during low-energy drying and sintering rather than high-energy mechanical processing

Inventive Principle:
Principle #35Parameter changes

2Reliability

If conventional synthesis methods are used, then electrical conductivity above 100% IACS is targeted, but defects and impurities are introduced in the additives

Engineering Contradiction:
Improveelectrical conductivityVSAvoiddefects and impurities
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent applies preliminary action by pre-coating copper substrates with graphene layers before final forming operations. The copper foil is first coated with a graphene slurry suspension, dried, and then sintered to form a graphene-copper composite precursor. This preliminary graphene coating is then incorporated into the final ultra-conductive copper product through controlled deformation or solidification processes, achieving >100% IACS conductivity without requiring high-energy post-processing

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent utilizes parameter changes by controlling the graphene concentration, slurry viscosity, and sintering temperature to optimize the graphene-copper composite structure. By adjusting these parameters, the patent achieves optimal electrical conductivity (>100% IACS) while minimizing energy expenditure during processing, as the graphene network formation occurs during low-energy drying and sintering rather than high-energy mechanical processing

Inventive Principle:
Principle #35Parameter changes

3Reliability

If conventional synthesis methods are used, then electrical conductivity above 100% IACS is targeted, but relatively high costs and inability to integrate with existing manufacturing units occur

Engineering Contradiction:
Improveelectrical conductivityVSAvoidmanufacturing cost and integration
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent applies preliminary action by pre-coating copper substrates with graphene layers before final forming operations. The copper foil is first coated with a graphene slurry suspension, dried, and then sintered to form a graphene-copper composite precursor. This preliminary graphene coating is then incorporated into the final ultra-conductive copper product through controlled deformation or solidification processes, achieving >100% IACS conductivity without requiring high-energy post-processing

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent utilizes parameter changes by controlling the graphene concentration, slurry viscosity, and sintering temperature to optimize the graphene-copper composite structure. By adjusting these parameters, the patent achieves optimal electrical conductivity (>100% IACS) while minimizing energy expenditure during processing, as the graphene network formation occurs during low-energy drying and sintering rather than high-energy mechanical processing

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The resulting ultra-conductive metal-graphene composite achieves electrical conductivity ranging from 99.3% to 105% IACS and increased ampacity, overcoming the limitations of existing UCC synthesis methods by reducing defects and processing costs while integrating with existing copper form manufacturing units.

Implementation Method 1

coating or otherwise introducing metal components with graphene

Methodology Applied
Scientific EffectChemical vapor deposition: Chemical Vapour Deposition

Implementation Method 2

the resultant material has ultrahigh electrical conductivity and thermal conductivity

Methodology Applied
Scientific EffectElectrical conduction: Conduction (electrical)

Data Source

PatentUS20240112827A1Ultraconductive metal composite forms and the synthesis thereof
Publication Date: 2024.04.04 OHIO UNIV
  • US20240112827A1 patent drawing
  • US20240112827A1 patent drawing

AI summary

A method of forming a metal-graphene composite includes coating metal components (10) with graphene (14) to form graphene-coated metal components, combining a plurality of the graphene-coated metal components to form a precursor workpiece (26), and working the precursor workpiece (26) into a bulk form (30) to form the metal-graphene composite. A metal-graphene composite includes graphene (14) in a metal matrix wherein the graphene (14) is single-atomic layer or multi-layer graphene (14) distributed throughout the metal matrix and primarily (but not exclusively) oriented with a plane horizontal to an axial direction of the metal-graphene composite.