Graphene-Copper Composite Electron-Path Tunnels

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Solution Overview

Problem

Current methods for improving the electrical conductivity of copper have only achieved a limited 3% increase over the past 100 years, despite extensive research, and the theoretical benefits of graphene in enhancing conductivity have not been experimentally verified for bulk metal composites.

Innovation Solution

A composite structure is developed with copper layers sandwiched between graphene layers, which form electron-path tunnels, enhancing electrical conductivity by promoting grain re-orientation and crystallinity, and providing electron doping effects, resulting in a multilayer composite with electrical conductivity up to 116% of the International Annealed Copper Standard.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If traditional methods are used to improve copper electrical conductivity through purity refinement, then conductivity increases slightly, but the improvement is limited to only about 3% despite extensive research over 100 years

Engineering Contradiction:
Improveelectrical conductivityVSAvoidrate of improvement
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The patent applies composite materials by combining copper with graphene to create a Cu-Gr-Cu multilayer composite structure. This composite approach enables electrical conductivity enhancement of up to 116% IACS, dramatically exceeding the limited 3% improvement achieved through traditional purity refinement methods alone.

Inventive Principle:
Principle #40Composite materials

2Reliability

If graphene layers are deposited on copper substrates, then electrical conductivity is enhanced through electron doping and grain re-orientation, but the manufacturing process complexity increases

Engineering Contradiction:
Improveelectrical conductivityVSAvoidmanufacturing process complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent segments the copper conductor into a multilayer Cu-Gr-Cu composite structure with alternating copper and graphene layers. This segmentation allows the graphene layers to be strategically positioned at interfaces where they can maximize electron doping effects and grain re-orientation, thereby enhancing conductivity while maintaining a relatively manageable manufacturing process through sequential deposition.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The graphene layers serve as intermediary elements between copper substrates, mediating electron transport through doping effects and facilitating grain re-orientation at interfaces. This intermediary role of graphene enables significant conductivity enhancement (up to 116% IACS) while the deposition process, though added, follows established thin-film fabrication techniques.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The graphene-copper composite achieves a significant enhancement in electrical conductivity, with interface conductivity three orders of magnitude higher than pure copper and bulk conductivity up to 16% higher, demonstrating potential for improved electrical and thermal applications.

Implementation Method 1

providing electron doping effects

Methodology Applied
Scientific EffectElectron doping: Dopants

Implementation Method 2

form electron-path tunnels, enhancing electrical conductivity

Methodology Applied
Scientific EffectElectron transport: Conduction (electrical)

Implementation Method 3

The as-obtained foils were then hot-pressed into 150-μm thick sheets

Methodology Applied
Scientific EffectHot pressing: Hot Isostatic Pressing

Data Source

PatentUS11127509B2Graphene-copper composite structure and manufacturing method
Publication Date: 2021.09.21 ULTRA CONDUCTIVE COPPER CO INC
  • US11127509B2 patent drawing
  • US11127509B2 patent drawing
  • US11127509B2 patent drawing

AI summary

A composite structure comprises a copper layer and first and second graphene layers sandwiching the copper layer, wherein the composite structure provides electron-path tunnels between the copper layer and the first and second graphene layers. The electron-path tunnels may enhance the electrical conductivity. A multilayer composite structure comprises a first copper layer, a first graphene layer on the first copper layer, a second graphene layer on the first graphene layer, and a second copper layer on the second graphene layer.