Graphene-Copper Contact Coating for Sulfur-Resistant Conductivity

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Solution Overview

Problem

Silver-plated copper electrical contacts are expensive and sensitive to sulfur-containing atmospheres, limiting their corrosion resistance and operational life in arcing and non-arcing applications.

Innovation Solution

A graphene-copper composite coating with a low graphene content (0.1-2 wt%) is applied to the substrate using electrodeposition, enhancing corrosion resistance and conductivity, reducing friction, and improving wear resistance without the need for intermediate layers or lubricants.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If silver-plated copper is used as electrical contact material, then corrosion resistance and anti-oxidation property are improved, but cost increases and sensitivity to sulfur-containing atmosphere worsens

Engineering Contradiction:
Improvecorrosion resistanceVSAvoidsensitivity to sulfur-containing atmosphere
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent applies composite materials by combining copper substrate with graphene coating to create a new material system that exhibits properties superior to both individual components. The graphene-copper composite coating provides enhanced corrosion resistance and sulfur tolerance while maintaining electrical conductivity, resolving the contradiction between reliability and sensitivity to harmful atmospheric factors.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent utilizes parameter changes by controlling graphene concentration (0.1-2 wt%) and applying electrodeposition parameters to optimize the coating structure. By adjusting these parameters, the coating achieves optimal balance between corrosion protection, electrical conductivity, and sulfur-containing atmosphere resistance, eliminating the need for silver plating.

Inventive Principle:
Principle #35Parameter changes

2Ease of manufacture

If graphene-copper composite coating is used instead of silver plating, then cost is reduced, but achieving equivalent corrosion resistance requires optimization of coating composition

Engineering Contradiction:
ImprovecostVSAvoidcoating composition optimization
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The patent applies parameter changes by establishing specific ranges for graphene concentration (0.1-2 wt%) and electrodeposition parameters that optimize both cost and performance. This systematic parameter optimization reduces manufacturing complexity by providing clear guidance for achieving equivalent corrosion resistance to silver plating at lower cost.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent applies self-service through the electrodeposition process, which automatically achieves uniform coating distribution and optimal composition through electrochemical principles. The process self-regulates to produce consistent results within the specified parameter ranges, reducing the need for complex quality control and manual adjustments.

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The graphene-copper composite coating provides improved corrosion resistance, low contact resistance, and extended operational life, comparable to silver-plated contacts, while being more cost-effective and reducing oxide growth, thus maintaining conductivity over time.

Implementation Method 1

The method also comprises coating the substrate by electrodeposition whereby the graphene and copper ions are co-deposited to form a graphene-copper composite coating on the substrate

Methodology Applied
Scientific EffectElectrodeposition: Electrodeposition

Data Source

PatentEP4089691B1Graphene-copper coated electrical contact
Publication Date: 2024.08.07 ABB (SCHWEIZ) AG
  • EP4089691B1 patent drawingFigure 1~3
  • EP4089691B1 patent drawingFigure 4~5

AI summary

The present disclosure relates to an electrical contact (1) comprising a substrate (5) of an electrically conductive material, and a graphene-copper composite coating (6) on the substrate. The graphene content in the coating is within the range of 0.1 to 2 wt%.