Graphene-Core Die Attach Adhesive for Heat and Vibration

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Solution Overview

Problem

Semiconductor devices in high power applications face challenges in maintaining reliable bonding between semiconductor die and leadframes under extreme conditions such as high temperature, vibration, and physical shock, due to limitations in existing bonding materials like Ag epoxy.

Innovation Solution

The use of an adhesive layer containing graphene core shells embedded within a matrix, which provides enhanced thermal and electrical conductivity, flexibility, and shock absorption, improving die attach properties and reducing manufacturing costs.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If Ag epoxy is used as bonding material, then electrical conductivity is improved, but thermal conductivity and shock resistance deteriorate

Engineering Contradiction:
Improvebonding reliabilityVSAvoidheat dissipation
Core Design Contradiction:
ReliabilityVSTemperature

Solution Approach 1:

The patent uses a composite adhesive layer combining polymer matrix with graphene and metal particle fillers. This composite structure achieves simultaneous improvement in thermal conductivity (graphene provides high thermal conduction paths), electrical conductivity (metal particles provide conductive networks), and mechanical flexibility (polymer matrix provides shock absorption), resolving the contradiction between electrical conductivity and thermal management in traditional Ag epoxy materials.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent modifies the physical and chemical parameters of the bonding material by incorporating graphene with specific aspect ratios and metal particles with controlled sizes and distributions. By adjusting these parameters, the material achieves optimized thermal conductivity, electrical conductivity, and mechanical properties simultaneously, overcoming the limitations of conventional Ag epoxy.

Inventive Principle:
Principle #35Parameter changes

2Strength

If rigid bonding material is used, then bonding strength is improved, but shock absorption and vibration resistance deteriorate

Engineering Contradiction:
Improvebonding strengthVSAvoidshock and vibration resistance
Core Design Contradiction:
StrengthVSObject-affected harmful factors

Solution Approach 1:

The patent employs a flexible polymer matrix (such as epoxy or silicone-based adhesives) as the bonding layer between semiconductor die and substrate. This flexible matrix can deform under shock and vibration loads, absorbing mechanical energy while maintaining bonding integrity. The flexibility compensates for thermal expansion mismatches and prevents brittle failure, resolving the contradiction between bonding strength and shock resistance.

Inventive Principle:
Principle #30Flexible shells and thin films

Solution Approach 2:

The composite structure combines rigid fillers (graphene, metal particles) for strength with a flexible polymer matrix for shock absorption. The rigid components provide bonding strength and electrical/thermal conductivity, while the flexible matrix provides ductility and vibration resistance, achieving both strong bonding and shock tolerance simultaneously.

Inventive Principle:
Principle #40Composite materials

3Reliability

If traditional adhesive materials are used, then manufacturing cost is reduced, but thermal management and electrical performance deteriorate

Engineering Contradiction:
Improveelectrical and thermal performanceVSAvoidmanufacturing cost
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent optimizes the concentration, size, and distribution parameters of graphene and metal particles in the adhesive layer to achieve desired electrical and thermal performance at reasonable manufacturing costs. By controlling these parameters, the patent balances performance requirements with manufacturing feasibility, avoiding excessive costs while meeting reliability targets for high-power semiconductor applications.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The graphene core shell adhesive layer enhances heat dissipation, shock absorption, and vibration dampening, ensuring reliable bonding and improved performance in high-stress environments, while lowering manufacturing costs.

Implementation Method 1

The plurality of cores may be arranged within the matrix so that graphene coatings covering adjacent cores contact one another to form a continuous connecting path between the leadframe and the semiconductor die

Methodology Applied
Scientific EffectThermal conduction: Conduction (thermal)

Implementation Method 2

The adhesive layer may include a plurality of cores with graphene coating embedded within a matrix

Methodology Applied
Scientific EffectElectrical conduction: Conduction (electrical)

Implementation Method 3

The use of an adhesive layer containing graphene core shells embedded within a matrix, which provides enhanced thermal and electrical conductivity, flexibility, and shock absorption

Methodology Applied
Scientific EffectShock absorption: Damping

Data Source

PatentUS20240194628A1Semiconductor Device and Method of Die Attach with Adhesive Layer Containing Graphene-Coated Core
Publication Date: 2024.06.13 STATS CHIPPAC LTD
  • US20240194628A1 patent drawing
  • US20240194628A1 patent drawing
  • US20240194628A1 patent drawing

AI summary

A semiconductor device has a substrate and an adhesive layer with a graphene core shell deposited over a surface of the substrate. An electrical component is affixed to the substrate with the adhesive layer. A bond wire is connected between the electrical component and substrate. The graphene core shell has a copper core and graphene coating over the copper core. The graphene coated core shell is embedded within a matrix. The graphene core shells within the adhesive layer to form a thermal path. The matrix can be a thermoset material or polymer or composite epoxy type matrix. The graphene core shell is embedded within the thermoset material or polymer or composite epoxy type matrix. The adhesive layer with graphene core shell is useful for die attachment. The graphene core adhesive layer provides exceptional heat dissipation, shock absorption, and vibration dampening.