Graphene Dispersion via Polymerizable Monomer

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Solution Overview

Problem

The challenge lies in achieving well-dispersed graphene in polymer matrices due to strong cohesive forces among graphene sheets, limiting the enhancement of polymer performance.

Innovation Solution

A graphene dispersion is created using a polymerizable monomer with a specific structure, featuring a benzene ring and a polar functional group, which enables effective exfoliation and uniform dispersion of graphene, eliminating the need for additional dispersants.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If graphene sheets are used to enhance polymer performance, then mechanical properties and gas-impermeability are improved, but strong cohesive forces among graphene sheets prevent thorough intermixing and uniform dispersion

Engineering Contradiction:
Improvemechanical propertiesVSAvoiduniform dispersion
Core Design Contradiction:
StrengthVSStability of the object's composition

Solution Approach 1:

The patent uses a surfactant as an intermediary substance to mediate between graphene sheets and polymer matrix. The surfactant adsorbs onto graphene surfaces, reducing cohesive forces between sheets and enabling uniform dispersion throughout the polymer matrix, thus resolving the contradiction between maintaining graphene's reinforcing properties and achieving uniform distribution

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent creates a composite system consisting of graphene sheets, surfactant, and polymer matrix. This multi-component composite approach allows the surfactant to modify the interface between graphene and polymer, enabling simultaneous achievement of good dispersion and enhanced mechanical properties

Inventive Principle:
Principle #40Composite materials

2Stability of the object's composition

If additional dispersants are used to improve graphene dispersion, then uniform distribution is achieved, but the complexity of the system increases

Engineering Contradiction:
Improveuniform dispersionVSAvoidsystem complexity
Core Design Contradiction:
Stability of the object's compositionVSDevice complexity

Solution Approach 1:

The surfactant performs multiple functions simultaneously: it acts as a dispersant to separate graphene sheets, a compatibilizer to improve interface with polymer matrix, and a process aid to facilitate mixing. This multi-functionality reduces the need for multiple separate additives, thereby limiting the increase in system complexity while achieving uniform dispersion

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach results in a well-dispersed graphene reinforced polymer with improved mechanical properties and gas-impermeability, overcoming the limitations of poor dispersibility in existing technologies.

Implementation Method 1

The structure of the polymerizable monomer includes a first part at one end of the structure and includes at least one benzene ring

Methodology Applied
Scientific EffectPi-pi stacking interaction:

Implementation Method 2

the second part is at another end of the structure and has polarity

Methodology Applied
Scientific EffectPolar interaction:

Data Source

PatentUS10077351B2Graphene dispersion and graphene reinforced polymer
Publication Date: 2018.09.18 GLOBAL GRAPHENE GROUP INC
  • US10077351B2 patent drawing
  • US10077351B2 patent drawing
  • US10077351B2 patent drawing

AI summary

A graphene dispersion includes a graphene material and a polymerizable monomer. The polymerizable monomer has a structure including the first part and the second part. The first part is at one end of the structure and includes at least one benzene ring, and the second part is at another end of the structure and has polarity.