Large-Sized Graphene Transfer via Edge Gap Extraction

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Solution Overview

Problem

Current methods for manufacturing and transferring larger-sized graphene layers are inefficient due to time-consuming wet etching and limitations in the stamp method, which struggles with larger sizes.

Innovation Solution

A method involving forming a graphene layer on a substrate with a catalyst layer, protection layer, and adhesive layer, followed by substrate removal using a hydrophilic liquid to weaken adhesion, and then transferring the graphene layer onto another substrate using a contact solution and sequential removal of layers.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If wet etching is used to remove substrate from larger-sized graphene layer, then substrate removal is achieved, but processing time becomes excessively long

Engineering Contradiction:
Improvesubstrate removal speedVSAvoidetching time
Core Design Contradiction:
ProductivityVSLoss of time

Solution Approach 1:

The invention extracts and removes the substrate from beneath the graphene layer through a gap created at the edge, allowing rapid removal without time-consuming etching of the entire substrate area. The substrate is separated by introducing a liquid through the gap and peeling away the substrate from the catalyst layer.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The invention performs preliminary actions by forming a gap at the edge of the substrate before substrate removal. This gap is created by selectively removing material or creating a separation zone, which enables subsequent rapid substrate extraction without requiring complete etching of the substrate.

Inventive Principle:
Principle #10Preliminary action

2Ease of operation

If stamp method is used to transfer graphene layer, then transfer process is simplified, but it is not conducive to transferring larger-sized graphene layers

Engineering Contradiction:
Improvetransfer process simplicityVSAvoidgraphene layer size
Core Design Contradiction:
Ease of operationVSArea of stationary object

Solution Approach 1:

The invention segments the transfer process into distinct stages: forming a gap at the edge, introducing liquid through the gap, peeling the substrate away, and then transferring the graphene layer to the target substrate. This segmentation allows handling of large-area graphene layers that cannot be transferred using conventional stamp methods.

Inventive Principle:
Principle #1Segmentation

3Productivity

If conventional manufacturing methods are used for larger-sized graphene, then graphene layer formation is achieved, but processing efficiency is low

Engineering Contradiction:
Improvemanufacturing efficiencyVSAvoidprocess complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The invention performs preliminary actions by forming protection and adhesive layers on the graphene layer before substrate removal. These pre-formed layers facilitate subsequent substrate extraction and graphene transfer operations, enabling efficient processing of large-area graphene without increasing overall process complexity.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables the efficient transfer and manufacturing of larger-sized graphene layers, such as those exceeding 6 inches, with improved processing time and scalability.

Implementation Method 1

penetrating a hydrophilic liquid into a gap between the catalyst layer and the substrate

Methodology Applied
Scientific EffectCapillary action: Capillary Action

Implementation Method 2

coating a contact solution on the transferring substrate; and sliding the graphene layer onto the transferring substrate

Methodology Applied
Scientific EffectWetting: Wetting

Data Source

PatentUS9108848B2Methods of manufacturing and transferring larger-sized graphene
Publication Date: 2015.08.18 SAMSUNG ELECTRONICS CO LTD
  • US9108848B2 patent drawing
  • US9108848B2 patent drawing
  • US9108848B2 patent drawing

AI summary

Example embodiments relate to methods of manufacturing and transferring a larger-sized graphene layer. A method of transferring a larger-sized graphene layer may include forming a graphene layer, a protection layer, and an adhesive layer on a substrate and removing the substrate. The graphene layer may be disposed on a transferring substrate by sliding the graphene layer onto the transferring substrate.