Graphene-Based Transparent Electrode for Flexible Displays

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Conventional transparent electrodes, such as ITO, in organic electroluminescent display devices suffer from signal delay due to high resistance and are unsuitable for flexible display devices, which limits their performance and flexibility.

Innovation Solution

A conductive material is formed by oxidizing graphite to create liquid graphene oxide, reducing it, and mixing it with a conductive monomer containing an aromatic benzene ring to form cross-linkages among graphene flakes, which are then applied as a transparent electrode, eliminating the need for expensive vacuum equipment and high-temperature processes.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If ITO is used as a transparent electrode, then transparency is achieved, but resistance is high causing signal delay

Engineering Contradiction:
Improvesignal transmission qualityVSAvoidelectrical resistance
Core Design Contradiction:
ReliabilityVSQuantity of substance

Solution Approach 1:

The patent uses a composite structure combining reduced graphene oxide flakes with conductive polymers (such as polyaniline or polythiophene) to create a transparent electrode material that achieves both low resistance and high transparency. The graphene oxide provides structural framework while the conductive polymer fills gaps and enhances electrical pathways, resolving the contradiction between transparency and conductivity.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent changes the physical and chemical parameters of the electrode material by reducing graphene oxide to restore its sp2 carbon structure and enhance electrical conductivity. The reduction process transforms graphene oxide (insulating) into reduced graphene oxide (conductive), while maintaining transparency. Additional doping with conductive polymers further adjusts the electrical parameters to achieve low resistance.

Inventive Principle:
Principle #35Parameter changes

2Adaptability or versatility

If ITO is used as an electrode, then transparency is maintained, but flexibility is poor

Engineering Contradiction:
ImproveflexibilityVSAvoidmechanical flexibility
Core Design Contradiction:
Adaptability or versatilityVSStrength

Solution Approach 1:

The patent employs thin film structures of reduced graphene oxide that can be deposited on flexible substrates. The two-dimensional nature of graphene oxide flakes allows them to form flexible, bendable transparent electrodes that maintain electrical conductivity even when bent or stretched, unlike rigid ITO coatings that crack under deformation.

Inventive Principle:
Principle #30Flexible shells and thin films

Solution Approach 2:

The patent uses flexible polymer matrices or binders as intermediaries to hold the reduced graphene oxide flakes together, creating a flexible composite electrode. These polymer intermediaries allow the electrode to bend and deform without breaking the conductive network, providing the needed flexibility while maintaining electrical performance.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Manufacturing precision

If conventional vacuum deposition is used for electrode fabrication, then film quality is achieved, but manufacturing complexity and cost increase

Engineering Contradiction:
Improvefilm qualityVSAvoidfabrication process complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent replaces complex vacuum deposition equipment with solution-based processing methods. Reduced graphene oxide dispersions can be applied using simple techniques such as spin coating, dip coating, or inkjet printing, eliminating the need for expensive vacuum chambers and high-temperature deposition equipment while achieving high-quality transparent electrodes.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent uses solution-processable reduced graphene oxide materials that can be applied at low cost using disposable or simple application tools. The material can be processed from aqueous or organic solutions, allowing for low-cost manufacturing compared to expensive ITO materials that require vacuum deposition equipment, simplifying the overall fabrication process.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The resulting graphene-based electrodes exhibit low resistance, enhanced conductivity, and flexibility, improving the performance and manufacturing efficiency of display devices, particularly in flexible organic electroluminescent and liquid crystal display devices.

Implementation Method 1

forming liquid graphene oxide by oxidizing a graphite

Methodology Applied
Scientific EffectOxidation: Oxidation

Implementation Method 2

reducing the graphene oxide

Methodology Applied
Scientific EffectReduction: Reduction

Implementation Method 3

forming cross-linkages among graphene flakes by mixing a conductive monomer including an aromatic benzene ring with the reduced graphene

Methodology Applied
Scientific EffectCross-linking: Chemical Bonding

Data Source

PatentUS10162385B2Conductive material, method of fabricating electrode, and display device having the same
Publication Date: 2018.12.25 LG DISPLAY CO LTD
  • US10162385B2 patent drawing
  • US10162385B2 patent drawing
  • US10162385B2 patent drawing

AI summary

Disclosed is a conductive material fabricated with a reduced fabrication cost and through simplified processes. The conductive material comprises: liquid graphene including flakes; and a conductive monomer including an aromatic benzene ring, the conductive monomer being mixed with the liquid grapheme to form cross-linkages among the flakes.