Graphene-Ionic Liquid Composite Electrodes for Energy Storage

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Solution Overview

Problem

Current graphene-containing energy storage devices lack the necessary properties for practical use in high-capacity, low-cost, and high-efficiency applications such as batteries and capacitors, particularly in portable electronic devices and electrical vehicles.

Innovation Solution

A method of creating graphene-ionic liquid composites by combining a graphene source with an ionic liquid and heating the mixture above 130°C, which is then applied to a substrate, forming electrodes that enhance energy storage capabilities.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If graphene-containing devices are manufactured using conventional methods, then device structure is formed, but the devices lack necessary properties for practical use (insufficient energy density, conductivity, and capacitance)

Engineering Contradiction:
Improveenergy storage performanceVSAvoidmanufacturing complexity
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent combines graphene with ionic liquids to create a composite material that integrates the high surface area and conductivity of graphene with the high ionic conductivity and electrochemical stability of ionic liquids. This composite structure enables practical energy storage performance by synergistically combining the advantages of both materials, achieving high energy density and power density simultaneously.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent optimizes specific parameters including heating temperature (above melting point of ionic liquid), heating time (sufficient for complete evaporation of solvent), and ratio of graphene to ionic liquid. These parameter optimizations transform the material properties to achieve desired electrical conductivity, surface area, and energy storage capacity while maintaining manufacturing feasibility.

Inventive Principle:
Principle #35Parameter changes

2Quantity of substance

If graphene is used alone in energy storage devices, then high surface area is achieved, but insufficient electrical conductivity and energy density result

Engineering Contradiction:
Improvesurface areaVSAvoidelectrical conductivity
Core Design Contradiction:
Quantity of substanceVSReliability

Solution Approach 1:

The composite combines graphene's two-dimensional high surface area structure with ionic liquid's high ionic conductivity. The ionic liquid fills the spaces between graphene sheets and provides conductive pathways, while graphene provides the high surface area for electrochemical reactions. This composite approach simultaneously achieves both high surface area and high electrical conductivity.

Inventive Principle:
Principle #40Composite materials

3Ease of manufacture

If conventional electrode materials are used, then manufacturing is straightforward, but energy density and power density are insufficient for high-capacity applications

Engineering Contradiction:
Improvemanufacturing simplicityVSAvoidenergy density
Core Design Contradiction:
Ease of manufactureVSProductivity

Solution Approach 1:

The patent performs preliminary actions by pre-mixing graphene with ionic liquid in a solvent to form a homogeneous dispersion before deposition. The solvent facilitates uniform distribution of ionic liquid on graphene surfaces. After deposition on the substrate, thermal treatment evaporates the solvent and consolidates the composite, creating a pre-optimized electrode structure that achieves high energy density without complex post-processing.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method produces electrodes with improved specific capacitance and reduced equivalent surface resistance, enabling higher energy density and efficiency in energy storage devices.

Implementation Method 1

The ionic liquid can be dissolved or suspended in a solvent

Methodology Applied
Scientific EffectDissolution: Solvation

Implementation Method 2

The resulting blend can be applied to a substrate and then heated to remove volatile components (such as solvents)

Methodology Applied
Scientific EffectEvaporation: Evaporation

Implementation Method 3

Heating reduces graphite oxide to graphene and can reduce or anneal graphene

Methodology Applied
Scientific EffectThermal reduction: Reduction

Implementation Method 4

Heating reduces graphite oxide to graphene and can reduce or anneal graphene

Methodology Applied
Scientific EffectAnnealing: Annealing

Data Source

PatentUS10068716B2Graphene-ionic liquid composites
Publication Date: 2018.09.04 VORBECK MATERIALS CORP
  • US10068716B2 patent drawing
  • US10068716B2 patent drawing
  • US10068716B2 patent drawing

AI summary

Method of making a graphene-ionic liquid composite. The composite can be used to make electrodes for energy storage devices, such as batteries and supercapacitors.