Graphene Electronic Device Manufacturing via Metal Compound Catalyst

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Solution Overview

Problem

The existing methods for depositing large-area graphene layers are complex due to the requirement of a catalyst layer, which complicates the process and limits the scalability of graphene-based semiconductor devices.

Innovation Solution

A method involving the formation of a metal compound layer with catalyst elements like copper, cobalt, or nickel, which includes oxygen or sulfur, is used to grow a graphene layer on a substrate, simplifying the process by converting the catalyst layer into a metal compound layer through heat treatment, and further integrating electrodes and insulating layers to form a graphene electronic device.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Area of stationary object

If a catalyst layer is used to deposit large-area graphene layers, then the graphene deposition area is improved, but the manufacturing process complexity increases

Engineering Contradiction:
Improvegraphene layer areaVSAvoidmanufacturing process complexity
Core Design Contradiction:
Area of stationary objectVSDevice complexity

Solution Approach 1:

The patent extracts and eliminates the separate catalyst layer from the graphene deposition process. Instead of using a distinct catalyst layer that requires additional deposition and removal steps, the invention uses a metal compound layer (such as CuO, Cu2O, CuS, or Cu2S) that directly serves as the catalyst substrate, thereby simplifying the manufacturing process while maintaining large-area graphene deposition capability

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The metal compound layer performs multiple functions: it serves as the catalyst substrate for graphene growth, provides thermal and electrical conductivity, and acts as a buffer layer between the substrate and graphene. This multi-functionality eliminates the need for separate catalyst layer deposition and subsequent removal steps, reducing process complexity

Inventive Principle:
Principle #6Universality (Multi-functionality)

2Reliability

If a catalyst layer is used for graphene deposition, then graphene growth is enabled, but the number of manufacturing steps increases

Engineering Contradiction:
Improvegraphene growth capabilityVSAvoidmanufacturing efficiency
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The patent merges the catalyst layer formation with the metal compound layer deposition into a single step. The metal compound layer (containing Cu, CuO, Cu2O, CuS, or Cu2S) is deposited directly onto the substrate and simultaneously serves as the catalyst for graphene growth, eliminating the need for separate catalyst layer deposition and removal steps, thereby improving manufacturing efficiency

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The metal compound layer is prepared in advance with the appropriate crystal structure and composition to enable direct graphene growth without requiring a separate catalyst layer. The preliminary preparation of the metal compound layer with correct stoichiometry and phase structure ensures that graphene can grow directly on it, reducing the number of manufacturing steps

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach simplifies the manufacturing process of graphene electronic devices by using a metal compound layer as a catalyst for graphene growth, enabling the production of both monolayer and multilayer graphene devices with improved thermal and electric conductivity, thus addressing the complexity of large-area graphene deposition.

Implementation Method 1

a catalyst layer including a metal element in the metal compound layer, growing a graphene layer on the catalyst layer

Methodology Applied
Scientific EffectCatalysis: Catalysis

Implementation Method 2

The converting may include heat treating the catalyst layer

Methodology Applied
Scientific EffectHeat treatment: Heat Treatment

Data Source

PatentUS10157989B2Graphene electronic device and manufacturing method thereof
Publication Date: 2018.12.18 SAMSUNG ELECTRONICS CO LTD
  • US10157989B2 patent drawing
  • US10157989B2 patent drawing
  • US10157989B2 patent drawing

AI summary

A method of manufacturing a graphene electronic device may include forming a metal compound layer and a catalyst layer on a substrate, the catalyst layer including a metal element in the metal compound layer, growing a graphene layer on the catalyst layer, and converting the catalyst layer into a portion of the metal compound layer.