Graphene Multijunction Solar Cell for High Efficiency

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Solution Overview

Problem

Current photovoltaic technology faces limitations in efficiency and cost, with maximum energy conversion at about 25% due to high semiconductor material costs and handling difficulties, and is not competitive with fossil-fuel technologies.

Innovation Solution

A multijunction solar cell design using graphene-based sub-cells with varying band gaps, stacked with n-type and p-type semiconductive graphene to form a graphene p-n junction, allowing for increased photon absorption and reduced material usage, with a thin-film approach on flexible substrates to decrease production costs and enhance efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If traditional semiconductor materials are used in photovoltaic cells, then the device can convert light to electricity, but the production cost is high and handling is difficult

Engineering Contradiction:
Improveproduction costVSAvoidenergy conversion efficiency
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent changes the fundamental material parameter from traditional semiconductors to graphene, which has unique electronic and optical properties. Graphene's zero-bandgap structure and high carrier mobility enable new photovoltaic mechanisms that reduce production costs while maintaining or improving efficiency

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses composite structures combining graphene with other materials to create multijunction solar cells. The combination of different graphene-based junctions (p-n, p-i-n) with varying bandgaps creates a composite system that optimizes both cost and efficiency

Inventive Principle:
Principle #40Composite materials

2Reliability

If traditional photovoltaic technology is used, then the device can generate electricity from solar energy, but the maximum energy conversion efficiency is limited to about 25%

Engineering Contradiction:
Improveenergy conversion efficiencyVSAvoidstructure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent divides the solar cell into multiple junctions (multijunction structure) with different bandgap energies. Each junction segment captures a specific portion of the solar spectrum, and the segments are stacked in series to achieve overall efficiency exceeding 25% while managing structural complexity through modular design

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention transitions from traditional planar photovoltaic structures to vertically stacked multijunction configurations. This dimensional arrangement allows multiple bandgap transitions to occur in series along the vertical dimension, capturing broader solar spectrum without requiring lateral expansion

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

3Reliability

If multiple sub-cells with different band gaps are stacked, then energy conversion efficiency increases, but the device complexity increases

Engineering Contradiction:
Improveenergy conversion efficiencyVSAvoidnumber of sub-cells
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent systematically varies the bandgap parameter across different graphene-based junctions in the stack. By controlling doping levels and material composition to achieve specific bandgap values (e.g., 0.3 eV, 0.5 eV, 1.1 eV), the design optimizes photon capture across the solar spectrum while maintaining manufacturability

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

Each sub-cell in the multijunction stack is designed with locally optimized properties - different bandgaps, doping concentrations, and thicknesses - tailored to capture specific wavelength ranges. This local quality differentiation maximizes overall efficiency while the modular nature of each sub-cell keeps individual components relatively simple

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The graphene-based multijunction solar cell achieves higher energy conversion efficiency, potentially reaching 85% with multiple junctions, while reducing production costs and improving handling and installation ease, offering advantages over traditional III-V semiconductor materials.

Implementation Method 1

devices for conversion of light to electricity using graphene-based solar cells

Methodology Applied
Scientific EffectPhotovoltaic effect: Photovoltaic Effect

Implementation Method 2

Apparatus and method for converting electromagnetic radiation into an electrical current, applying the combination of a photovoltaic and a thermovoltaic element are known

Methodology Applied
Scientific EffectPhotovoltaic conversion: Photovoltaic Effect

Data Source

PatentEP2691992B1Graphene-based multi-junctions flexible solar cell
Publication Date: 2016.05.04 CALIFORNIA INST OF TECH
  • EP2691992B1 patent drawingFigure 1A~1B
  • EP2691992B1 patent drawingFigure 2
  • EP2691992B1 patent drawingFigure 3

AI summary

This disclosure relates to structures for the conversion of light into energy. More specifically, the disclosure describes devices for conversion of light to electricity using photovoltaic cells comprising graphene.