Graphene Oxide Ionic Liquid Polymer Separation Membrane

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Solution Overview

Problem

Conventional separation membranes have limitations in achieving high separation performance for gas mixtures containing acid gases, particularly those with gases of larger molecular sizes.

Innovation Solution

A separation membrane comprising a separation functional layer made of graphene oxide, an ionic liquid, and a polymer, applied as a coating liquid to a substrate and dried to form a membrane with enhanced separation capabilities.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a conventional separation membrane is used, then the membrane structure is simple, but the separation performance for gas mixtures containing acid gases is insufficient

Engineering Contradiction:
Improveseparation performanceVSAvoidmembrane structure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent applies composite materials by combining graphene oxide, ionic liquid, and polymer in the separation functional layer. This composite structure enables high separation performance for acid gases while managing the complexity through systematic material integration rather than simple single-material layers.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent implements local quality by creating a separation functional layer with specific local composition (graphene oxide, ionic liquid, polymer) that provides enhanced separation performance specifically at the membrane interface where gas separation occurs, while other layers maintain simpler structures.

Inventive Principle:
Principle #3Local quality

2Reliability

If the separation functional layer uses only polymer and ionic liquid, then the membrane is easy to manufacture, but the separation performance for gases with larger molecular sizes is insufficient

Engineering Contradiction:
Improveseparation performanceVSAvoidmanufacturing complexity
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent enhances the separation functional layer by incorporating graphene oxide into the polymer-ionic liquid composite. This composite material approach improves separation performance for gases with larger molecular sizes while maintaining manufacturability through the coating method.

Inventive Principle:
Principle #40Composite materials

3Reliability

If a gel layer including polymer and ionic liquid is used as separation functional layer, then the membrane can separate acid gas, but the separation performance needs further improvement

Engineering Contradiction:
Improveseparation performanceVSAvoidseparation efficiency
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The patent transforms the gel layer into a composite separation functional layer by adding graphene oxide to the polymer-ionic liquid system. This composite structure enhances both separation performance and productivity by providing additional pathways for acid gas separation while maintaining selectivity.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent utilizes the porous structure of graphene oxide in the separation functional layer to enhance gas transport efficiency. The porous material provides increased surface area and multiple transport pathways, improving both separation performance and productivity simultaneously.

Inventive Principle:
Principle #31Porous materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The membrane exhibits improved separation performance for gas mixtures containing acid gases, including those with larger molecular sizes, such as carbon dioxide and nitrogen, with a high separation factor and permeation rate.

Implementation Method 1

drying the coating film

Methodology Applied
Scientific EffectEvaporation: Evaporation

Implementation Method 2

a separation functional layer including: graphene oxide; an ionic liquid; and a polymer

Methodology Applied
Scientific EffectPermeation: Permeation

Data Source

PatentUS20230347284A1Separation membrane, separation membrane manufacturing method, and coating liquid for manufacturing separation membrane
Publication Date: 2023.11.02 NITTO DENKO CORP
  • US20230347284A1 patent drawing
  • US20230347284A1 patent drawing
  • US20230347284A1 patent drawing

AI summary

The present invention provides a separation membrane having high separation performance in terms of a gas mixture containing an acid gas. A separation membrane 10 of the present invention includes a separation functional layer 1 including: graphene oxide; an ionic liquid; and a polymer. The ionic liquid is, for example, hydrophilic and contains an imidazolium ion and tetrafluoroborate. A method for manufacturing the separation membrane 10 of the present invention includes: applying a coating liquid containing the graphene oxide, the ionic liquid, and the polymer to a substrate to obtain a coating film; and drying the coating film.