Graphene Oxide Acrylic Rubber Composition for Heat-Resistant Strength

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Solution Overview

Problem

Acrylic rubbers and their vulcanizates require enhanced tensile properties and heat resistance to meet modern demands, particularly in applications like automobile engine components, where emission controls and higher engine power are necessary.

Innovation Solution

Incorporating graphene oxide at a nanoscale into the acrylic rubber composition, which can be cured or vulcanized, improves tensile properties and heat resistance, with specific ratios of graphene oxide to acrylic rubber and functional groups optimizing the performance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If conventional acrylic rubber is used, then basic physical properties are maintained, but tensile properties and heat resistance are insufficient

Engineering Contradiction:
Improvetensile propertiesVSAvoidheat resistance
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent applies composite materials by incorporating graphene oxide into acrylic rubber to create a new material system. The graphene oxide forms a three-dimensional network structure within the rubber matrix, combining the elasticity of rubber with the strength and thermal stability of graphene oxide, thereby simultaneously improving both tensile properties and heat resistance

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent changes the physical and chemical parameters of the rubber system by controlling the particle size of graphene oxide at the nanoscale (1-100 nm) and optimizing its content (0.1-50 parts by mass per 100 parts of acrylic rubber). This parameter optimization enables effective dispersion and maximizes the reinforcing effect on tensile strength and heat resistance

Inventive Principle:
Principle #35Parameter changes

2Strength

If nanosized filler is dispersed in rubber, then physical properties improve, but manufacturing complexity increases

Engineering Contradiction:
Improvetensile propertiesVSAvoiddispersion process complexity
Core Design Contradiction:
StrengthVSDevice complexity

Solution Approach 1:

The patent uses silane coupling agents as intermediary substances to facilitate the dispersion of graphene oxide in acrylic rubber. The silane coupling agent acts as a bridge between the hydrophobic graphene oxide surface and the polymer matrix, improving interfacial adhesion and enabling uniform distribution without requiring excessively complex dispersion equipment or processes

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent controls the particle size parameter of graphene oxide within the specific range of 1-100 nm, which is small enough to achieve good dispersion through conventional mixing equipment while still large enough to maintain structural integrity and reinforcing effect. This parameter optimization balances dispersion ease with performance enhancement

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The resulting acrylic rubber composition exhibits significantly improved tensile properties and heat resistance, making it suitable for high-performance applications such as rubber hoses, sealing parts, and vibration isolators.

Implementation Method 1

by finely dispersing the carbon material on the nanosize level, tensile properties and heat resistance can be improved

Methodology Applied
Scientific EffectNanodispersion:

Data Source

PatentEP3483213B1Acrylic rubber composition
Publication Date: 2021.04.07 DENKA CO LTD
  • EP3483213B1 patent drawing
  • EP3483213B1 patent drawing

AI summary

Provided are an acrylic rubber composition having higher tensile properties and higher heat resistance and a vulcanizate thereof. The present invention provides an acrylic rubber composition comprising 0.1 to 50 parts by mass of a carbon material comprising graphene oxide, relative to 100 parts by mass of an acrylic rubber.