Graphene Device Fabrication via Sacrificial Layer Transfer

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Solution Overview

Problem

The integration and performance of silicon-based semiconductor devices are limited, making it difficult to manufacture high-quality graphene devices due to challenges in growing graphene on insulating thin films and transferring it without defects or pollution.

Innovation Solution

A graphene device is fabricated using a substrate with a channel layer of graphene, source and drain electrodes formed from a catalyst material, a capping layer to protect the graphene, and a gate insulating layer, with a method involving a sacrificial layer for transferring the graphene structure from one substrate to another to prevent damage and pollution.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If graphene is grown on a metal thin film and then transferred onto an insulator, then graphene can be formed, but the graphene may have defects or be exposed to pollutants during transfer and is difficult to handle

Engineering Contradiction:
Improvegraphene qualityVSAvoidtransfer process complexity
Core Design Contradiction:
Manufacturing precisionVSEase of manufacture

Solution Approach 1:

A sacrificial layer is introduced as an intermediary between the substrate and the graphene/catalyst structure. This sacrificial layer enables easy separation and transfer of the graphene device to the target substrate without direct contact between graphene and the original substrate, preventing damage and pollution while simplifying the transfer process.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The device structure is segmented into distinct layers (substrate, sacrificial layer, catalyst layer, graphene layer, insulating layer) that can be independently processed and separated. This segmentation allows the graphene structure to be transferred as a complete unit without contamination from the substrate.

Inventive Principle:
Principle #1Segmentation

2Reliability

If existing transfer methods are used to form graphene on insulators, then graphene can be placed on the insulator, but the graphene is exposed to pollutants and suffers damage during transfer

Engineering Contradiction:
Improvegraphene integrityVSAvoidpollution and damage during transfer
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

An insulating layer is formed beforehand on the graphene layer before transfer. This insulating layer acts as a protective cushion that prevents direct exposure of the graphene to pollutants and damage during the transfer process, while still allowing the transfer to proceed.

Inventive Principle:
Principle #11Beforehand cushioning (Prior cushioning)

Solution Approach 2:

The sacrificial layer serves as a mediator that facilitates transfer without requiring direct manipulation of the graphene itself. The graphene structure remains protected on its support layers throughout the transfer process.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Ease of manufacture

If graphene is grown directly on an insulating thin film, then the process is simplified, but it is difficult to grow high-quality graphene on the insulator

Engineering Contradiction:
Improvegrowth process simplicityVSAvoidgraphene quality
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

A catalyst layer is introduced as an intermediary substrate for graphene growth. The catalyst layer provides suitable conditions for high-quality graphene growth, while the insulating layer beneath it provides the required electrical insulation. After growth, the catalyst layer can be removed or retained depending on the application.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

Different layers are assigned different functions: the catalyst layer provides optimal conditions for graphene growth locally, while the insulating layer provides electrical isolation. This local differentiation of properties allows both high-quality growth and proper electrical characteristics.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables the production of high-performance graphene devices with reduced damage and pollution, allowing for self-aligned electrodes and improved device design, while simplifying the manufacturing process and maintaining the integrity of the graphene layer.

Implementation Method 1

separating the first substrate by etching the sacrificial layer

Methodology Applied
Scientific EffectEtching:

Implementation Method 2

The source electrode and the drain electrode may be formed of a catalyst material for growing graphene

Methodology Applied
Scientific EffectCatalysis: Catalysis

Data Source

PatentUS9293596B2Graphene devices and methods of manufacturing the same
Publication Date: 2016.03.22 SAMSUNG ELECTRONICS CO LTD
  • US9293596B2 patent drawing
  • US9293596B2 patent drawing
  • US9293596B2 patent drawing

AI summary

A graphene device may include a channel layer including graphene, a first electrode and second electrode on a first region and second region of the channel layer, respectively, and a capping layer covering the channel layer and the first and second electrodes. A region of the channel layer between the first and second electrodes is exposed by an opening in the capping layer. A gate insulating layer may be on the capping layer to cover the region of the channel layer, and a gate may be on the gate insulating layer.