Graphene Solid Electrolyte for Flexible Batteries

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Solution Overview

Problem

Lithium-ion storage batteries face issues with internal short circuits due to low ionic conductivity at low temperatures and potential fires at high temperatures, and existing solid electrolytes are not flexible enough for deformable electronic devices.

Innovation Solution

A graphene compound with substituted or unsubstituted chain groups containing ester or carboxyl groups bonded through a Si atom is used as a solid electrolyte, providing high ion conductivity, flexibility, and heat resistance, suitable for a wide temperature range and deformable devices.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Adaptability or versatility

If a polymer electrolyte such as PEO is used as a solid electrolyte, then the battery can operate at low temperatures with better flexibility, but the ionic conductivity decreases significantly at low temperatures and the material melts at high temperatures (melting point approximately 60°C)

Engineering Contradiction:
Improvetemperature rangeVSAvoidionic conductivity
Core Design Contradiction:
Adaptability or versatilityVSReliability

Solution Approach 1:

The patent uses a composite structure combining polymer matrix with nanofillers (such as metal oxides, carbon nanotubes, or graphene) to create a solid electrolyte that maintains ionic conductivity at low temperatures while resisting melting at high temperatures. The nanofillers provide thermal stability and prevent polymer chain collapse, while the polymer matrix ensures flexibility and low-temperature operation.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent modifies the chemical composition and physical parameters of the polymer electrolyte by adding cross-linking agents, plasticizers, or functionalized nanoparticles to enhance ionic conductivity at low temperatures and raise the melting point. This includes adjusting molecular weight, cross-linking density, and compositional ratios to optimize performance across temperature ranges.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If a ceramic solid electrolyte is used, then higher ionic conductivity is achieved, but the material becomes brittle and is easily broken or separated from active material when bent

Engineering Contradiction:
Improveionic conductivityVSAvoidflexibility
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The patent creates a composite solid electrolyte where ceramic particles or nanofillers are dispersed within a polymer matrix. This combination provides the high ionic conductivity of ceramics while the polymer continuous phase maintains flexibility and prevents brittleness. The composite structure allows the material to bend without cracking while maintaining efficient ion transport pathways.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent creates local regions with different properties within the solid electrolyte: ceramic-rich regions provide high ionic conductivity, while polymer-rich regions provide flexibility and toughness. This spatial distribution of properties allows the material to simultaneously achieve high ionic conductivity and mechanical flexibility, preventing separation from active materials during bending.

Inventive Principle:
Principle #3Local quality

3Quantity of substance

If an organic solvent is used as an electrolyte solution to achieve high energy density, then the battery has high energy density, but the electrolyte may catch fire at high temperatures causing safety issues

Engineering Contradiction:
Improveenergy densityVSAvoidfire risk
Core Design Contradiction:
Quantity of substanceVSObject-affected harmful factors

Solution Approach 1:

The patent replaces the liquid organic electrolyte system with a solid electrolyte system, fundamentally changing the physical state from liquid to solid. This substitution eliminates the fire hazard associated with volatile organic solvents while maintaining ionic conductivity through solid-state ion transport mechanisms. The solid electrolyte provides intrinsic safety by removing the flammable component entirely.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent addresses the fire risk by using solid electrolytes that inherently resist combustion. The solid-state structure prevents the vaporization and ignition that plague liquid organic electrolytes at high temperatures. This converts the potential harm of high-temperature operation with flammable liquids into a safe operating condition with non-flammable solid materials.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The graphene compound enhances the safety and flexibility of lithium-ion storage batteries by maintaining high ion conductivity and heat resistance across various temperatures, preventing internal short circuits and enabling the use in deformable electronic devices.

Implementation Method 1

a solid electrolyte capable of exhibiting the above-mentioned basic properties even at high temperatures is needed in order to obtain a practical all-solid-state lithium-ion storage battery

Methodology Applied
Scientific EffectIon conductivity: Conduction (electrical)

Implementation Method 2

The chain group is bonded to the graphene layer through the Si atom

Methodology Applied
Scientific EffectChemical bonding: Chemical Bonding

Data Source

PatentUS10529980B2Graphene compound, method for forming graphene compound, and power storage device
Publication Date: 2020.01.07 SEMICON ENERGY LAB CO LTD
  • US10529980B2 patent drawing
  • US10529980B2 patent drawing
  • US10529980B2 patent drawing

AI summary

A material that can be used in a wide temperature range and a manufacturing method thereof are provided. A graphene compound has a substituted or unsubstituted chain group. The chain group has one or more ester groups or carboxyl groups and contains a Si atom. The chain group is bonded to a graphene layer through the Si atom. A method for forming a graphene compound includes a step of stirring graphene oxide and a Lewis base and a step of mixing a silicon compound having one or more ester groups or carboxyl groups into the mixed solution and stirring the obtained mixed solution. The Lewis base is butylamine, pentylamine, hexylamine, diethylamine, dipropylamine, dibutylamine, triethylamine, tripropylamine, or pyridine.