Graphenic Yarns Hollow Core Structure for Low Density High Strength

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Solution Overview

Problem

Carbon fibers used in aerospace and automotive applications are heavy due to high density, leading to increased payload and propulsion requirements, and have low failure strain, making them unsuitable for many applications.

Innovation Solution

Development of graphenic yarns with bundled graphenic filaments that have lower densities (≤1.5 g/cc) and higher tensile strengths (≥0.5 GPa), offering improved strength-to-weight ratios compared to carbon fibers, achieved through electrospinning and thermal treatment processes.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If carbon fibers are used to achieve high tensile strength, then strength is improved, but density increases leading to higher weight

Engineering Contradiction:
Improvetensile strengthVSAvoiddensity
Core Design Contradiction:
StrengthVSWeight of moving object

Solution Approach 1:

The patent changes the material composition parameters by incorporating hollow cores and void spaces within the fiber structure, reducing density from typical carbon fiber values (1.8-2.0 g/cc) to below 1.0 g/cc while maintaining tensile strength through strategic placement of reinforcing elements and controlled wall thickness in the hollow structure

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite structure combining solid and hollow regions, where the outer shell provides structural integrity and tensile strength while the hollow interior reduces mass. This composite approach allows the fiber to achieve strength-to-weight ratios superior to both solid carbon fibers and conventional lightweight materials

Inventive Principle:
Principle #40Composite materials

2Strength

If carbon fibers are used to achieve high tensile strength, then strength is improved, but failure strain decreases making them more brittle

Engineering Contradiction:
Improvetensile strengthVSAvoidfailure strain
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent divides the fiber into segmented regions including hollow cores, solid walls, and intermediate zones. This segmentation allows stress to be distributed across multiple pathways, preventing catastrophic failure and enabling progressive deformation that increases failure strain while maintaining overall tensile strength

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent employs thin-walled hollow structures that provide flexibility and ductility. The thin walls can deform elastically under stress, increasing the material's ability to withstand strain before failure, thereby improving reliability without sacrificing the strength provided by the overall fiber architecture

Inventive Principle:
Principle #30Flexible shells and thin films

3Weight of moving object

If preliminary attempts are made to manufacture graphene fibers with low density, then density is reduced, but tensile strength decreases significantly

Engineering Contradiction:
ImprovedensityVSAvoidtensile strength
Core Design Contradiction:
Weight of moving objectVSStrength

Solution Approach 1:

The patent implements a nested structure where hollow cores are positioned within the fiber cross-section, and reinforcing elements are embedded within the wall structure. This nesting allows maximum material utilization where every element contributes to strength, achieving tensile strength comparable to solid fibers while maintaining low density through the hollow architecture

Inventive Principle:
Principle #7Nested doll (Nesting)

Solution Approach 2:

The patent transitions from two-dimensional planar graphene sheets to three-dimensional hollow fiber structures. By creating vertical walls and hollow chambers, the structure gains volumetric efficiency, providing strength in multiple directions while the hollow configuration reduces mass, effectively decoupling the strength-density relationship

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The graphenic yarns provide a lightweight alternative with enhanced strength and reduced brittleness, suitable for applications where high strength and low mass are critical, such as in aerospace and automotive industries.

Implementation Method 1

achieved through electrospinning and thermal treatment processes

Methodology Applied
Scientific EffectElectrospinning: Electrohydrodynamics

Implementation Method 2

achieved through electrospinning and thermal treatment processes

Methodology Applied
Scientific EffectThermal treatment: Heat Treatment

Data Source

PatentUS12017961B2Graphenic fibers, yarns, composites, and methods of making the same
Publication Date: 2024.06.25 CORNELL UNIVERSITY
  • US12017961B2 patent drawing
  • US12017961B2 patent drawing
  • US12017961B2 patent drawing

AI summary

Provided in certain embodiments are high performance graphene fibers and yarns, including components and precursors thereof, and composites comprising the same. Also provided herein are methods of manufacturing such fibers, yarns, composites, and components/precursors thereof.