Graphite Adhesive Cathode Paste for Electron Emission Stability

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Solution Overview

Problem

Conventional methods for manufacturing electron emitting devices face issues with low adhesion and stability due to the use of vulnerable filler materials in high-temperature environments, leading to non-uniform electron emission.

Innovation Solution

A method involving a graphite adhesive material composed of graphite filler and binder is used to enhance adhesion and electric conductivity between the substrate and electron emitting nanomaterials, involving the preparation of a paste by mixing nanomaterials with graphite filler and binder, followed by drying and forming a thin film on a cathode substrate.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If conventional filler materials (organic, insulating, or metallic) are used in paste processing, then adhesion enhancement is achieved, but material degradation occurs in high-temperature environments through outgassing or melting

Engineering Contradiction:
ImproveadhesionVSAvoidmaterial stability
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent uses graphite as a filler material in the paste composition. Graphite is a carbon-based material that combines both adhesion enhancement properties and high-temperature stability, resolving the contradiction between needing strong adhesion and maintaining material stability at high temperatures. The graphite particles serve dual functions: improving paste adhesion to the substrate and withstanding the high-temperature processing without degradation.

Inventive Principle:
Principle #40Composite materials

2Manufacturing precision

If direct deposition method is used to vertically deposit electron emitting material, then electron emission structure is formed, but adhesion between substrate and nanomaterial remains low

Engineering Contradiction:
Improvevertical deposition structureVSAvoidadhesion
Core Design Contradiction:
Manufacturing precisionVSStrength

Solution Approach 1:

The patent introduces a paste composition as an intermediary medium between the substrate and the electron emitting nanomaterial. This paste contains graphite fillers that enhance adhesion to the substrate while also accommodating the vertically oriented nanomaterial structures. The paste acts as a bonding layer that secures the vertically deposited nanomaterial to the substrate, solving the adhesion problem inherent in direct deposition methods.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Ease of manufacture

If paste processing method is used to coat nanomaterial on substrate, then coating is achieved, but adhesion and electric conductivity are insufficient

Engineering Contradiction:
Improvecoating processVSAvoidadhesion and conductivity
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The paste composition is formulated as a composite material containing graphite fillers, binders, and solvents. The graphite provides both adhesion enhancement and electric conductivity, while the binder ensures proper coating formation. This composite approach allows the paste to be easily applied through coating methods while simultaneously achieving the required adhesion and conductivity performance.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent optimizes the paste composition parameters including graphite particle size distribution, binder type and concentration, and solvent selection. By adjusting these parameters, the paste achieves optimal adhesion, conductivity, and coating quality. The specific formulation parameters are tuned to ensure proper flow characteristics for coating while maintaining high adhesion and electrical conductivity after drying.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach improves adhesion and electric conductivity, resulting in enhanced stability and high emission current density, with the graphite filler's high-temperature resistance preventing material degradation and allowing for effective high-temperature processing.

Implementation Method 1

a graphite adhesive material composed of graphite filler and binder

Methodology Applied
Scientific EffectAdhesive bonding: Adhesive

Implementation Method 2

the graphite adhesive material (graphite filler and graphite binder) which is a conductive material can improve the electric conductivity between the nanomaterial for electron emission and the cathode substrate

Methodology Applied
Scientific EffectElectrical conduction: Conduction (electrical)

Implementation Method 3

Electron emission refers to the release of electrons from a surface of an anode due to a lowered energy barrier in a vacuum when a strong electric field is applied between an anode and the cathode in a vacuum

Methodology Applied
Scientific EffectElectron emission: Photoelectric Effect

Data Source

PatentUS10049847B2Electron emitting device using graphite adhesive material and manufacturing method for the same
Publication Date: 2018.08.14 KOREA UNIV RES & BUSINESS FOUND
  • US10049847B2 patent drawing
  • US10049847B2 patent drawing
  • US10049847B2 patent drawing

AI summary

The present disclosure relates to a manufacturing method for an electron emitting device using a graphite adhesive material. A method of preparing paste for forming a cathode of an electron emitting device includes: mixing and dispersing a nanomaterial for electron emission and a graphite filler in a solvent; drying a mixed solution in which the nanomaterial and the graphite filler are mixed; and preparing paste by mixing a graphite binder with the dried mixture.