Continuous Graphite Film Production via Segmented Heating

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Solution Overview

Problem

Conventional methods for producing graphite films through continuous carbonization result in fragile carbonized films that are prone to wrinkling and cracking due to shrinkage during the process, making them difficult to wind and use effectively.

Innovation Solution

A method involving a continuous carbonization step with multiple heating spaces, where the polymer film is heat-treated in a temperature range of 500°C to 1000°C, with controlled temperature differences between stages and optional cooling spaces, to minimize shrinkage and reduce wrinkling and cracking.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If continuous carbonization is performed in a single heating space, then productivity is improved, but the carbonized film becomes fragile with wrinkles and cracks due to shrinkage

Engineering Contradiction:
Improvecontinuous production capabilityVSAvoidfilm integrity
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The continuous carbonization process is divided into multiple heating spaces (first heating space and second heating space) with different temperature conditions. The first heating space operates at a lower temperature (500-800°C) to carbonize the polymer film while the second heating space operates at a higher temperature (800-1000°C) to graphitize the carbonized film. This segmentation allows gradual transformation that reduces shrinkage-induced wrinkles and cracks while maintaining continuous production capability.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention changes the temperature parameter progressively across different heating spaces. By controlling the temperature gradient (lower in the first heating space, higher in the second heating space) and adjusting the heating rate, the film undergoes controlled carbonization and graphitization that minimizes abrupt shrinkage. This parameter change strategy resolves the contradiction by enabling continuous processing while maintaining film integrity.

Inventive Principle:
Principle #35Parameter changes

2Productivity

If high temperature heating is applied to carbonize the polymer film, then carbonization efficiency is improved, but shrinkage increases causing wrinkles and cracks

Engineering Contradiction:
Improvecarbonization efficiencyVSAvoidfilm surface quality
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The heating process is segmented into two distinct stages in two different heating spaces. The first heating space provides milder heating (500-800°C) for initial carbonization with controlled shrinkage, while the second heating space provides intense heating (800-1000°C) for complete carbonization and graphitization. This segmentation allows efficient carbonization while maintaining surface quality by avoiding abrupt high-temperature exposure.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The first heating space performs preliminary carbonization at a controlled temperature before the film enters the second heating space. This preliminary action partially carbonizes the film in a controlled manner, reducing subsequent shrinkage when exposed to higher temperatures in the second heating space, thereby preventing wrinkles and cracks while maintaining carbonization efficiency.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach effectively reduces wrinkling and cracking in the carbonized films, allowing for more manageable and flexible graphite films with improved thermal diffusivity, enabling them to be wound around smaller diameters without defects.

Implementation Method 1

a continuous carbonization step of continuously baking a polymer film that continues lengthwise

Methodology Applied
Scientific EffectCarbonization: Pyrolysis

Implementation Method 2

two or more heating spaces

Methodology Applied
Scientific EffectThermal heating: Heating

Implementation Method 3

the inclusion of cooling spaces to minimize shrinkage

Methodology Applied
Scientific EffectThermal cooling: Cooling

Data Source

PatentUS8999286B2Method for producing graphite film and method for producing carbonized film
Publication Date: 2015.04.07 KANEKA CORP
  • US8999286B2 patent drawing
  • US8999286B2 patent drawing
  • US8999286B2 patent drawing

AI summary

A graphite film with fewer wrinkles and/or undulations is obtained providing two or more stages of heating space and carrying out continuous baking. Especially when a cooling space is provided between each of the heating spaces and another, a graphite film can be obtained which is excellent in flatness and has a high thermal diffusivity.