Graphitized Carbon Nanotube Field Emitter Bonding

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Solution Overview

Problem

Carbon nanotube field emitters have poor stability and short life due to weak binding forces between the carbon nanotube array and the cathode substrate, as well as growth defects in the nanotubes, leading to inadequate performance in field emission applications.

Innovation Solution

A method involving the formation of a super-aligned carbon nanotube array on a substrate, followed by graphitization and fixation using a conductive adhesive layer to enhance bonding, and subsequent ultrasonic cleaning to improve structural integrity and emission efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If carbon nanotubes are grown directly on the cathode substrate by chemical vapor deposition, then the field emitter can be formed quickly, but the binding force between the carbon nanotube array and the cathode substrate is poor resulting in poor stability

Engineering Contradiction:
Improveformation speedVSAvoidstability
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent applies preliminary action by forming a conductive adhesive layer on the cathode substrate before transferring and bonding the carbon nanotube array. This preparatory step ensures strong binding force is established in advance, preventing the stability issues that would otherwise occur with direct growth methods.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The conductive adhesive layer serves as an intermediary between the cathode substrate and the carbon nanotube array. This intermediate layer provides the necessary bonding interface that directly connects the two components with strong adhesion, resolving the binding force problem inherent in direct growth methods.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Device complexity

If carbon nanotubes are grown directly on the cathode substrate, then the fabrication process is simplified, but the carbon nanotubes have growth defects leading to short life

Engineering Contradiction:
Improvefabrication process complexityVSAvoidservice life
Core Design Contradiction:
Device complexityVSDuration of action of stationary object

Solution Approach 1:

The fabrication process is segmented into distinct steps: growing carbon nanotubes on a separate growth substrate, forming a conductive adhesive layer on the cathode substrate, transferring the nanotube array, and bonding them together. This segmentation allows each step to be optimized independently, eliminating growth defects while maintaining process feasibility.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent extracts the carbon nanotube growth process from the final device structure by growing nanotubes on a separate growth substrate. This extraction allows the nanotubes to be grown under optimal conditions without the constraints of the final device architecture, thereby eliminating growth defects while simplifying the overall fabrication process.

Inventive Principle:
Principle #2Taking out (Extraction)

3Reliability

If a conductive adhesive layer is formed and carbon nanotube array is bonded to the cathode substrate, then stability and lifespan are improved, but the device complexity increases

Engineering Contradiction:
ImprovestabilityVSAvoidfabrication process complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The conductive adhesive layer is formed in advance on the cathode substrate before the carbon nanotube array is transferred and bonded. This preliminary action simplifies the overall process by preparing the bonding interface beforehand, making the subsequent assembly steps more straightforward despite adding an additional material layer.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method results in a carbon nanotube field emitter with improved stability and extended lifespan by firmly bonding the graphitized carbon nanotubes to the substrate, enhancing electron emission efficiency and reducing defects.

Implementation Method 1

a conductive adhesive layer is formed on a surface of the cathode substrate; making one end of the graphitized carbon nanotube array contact with the conductive adhesive layer, and solidifying the conductive adhesive layer to fix the graphitized carbon nanotube array on the cathode substrate

Methodology Applied
Scientific EffectAdhesion: Adhesive

Implementation Method 2

subsequent ultrasonic cleaning to improve structural integrity and emission efficiency

Methodology Applied
Scientific EffectUltrasonic vibration: Ultrasonic Vibration

Data Source

PatentUS10811211B1Carbon nanotube field emitter and preparation method thereof
Publication Date: 2020.10.20 HON HAI PRECISION INDUSTRY CO LTD
  • US10811211B1 patent drawing
  • US10811211B1 patent drawing

AI summary

A method for making a carbon nanotube field emitter is provided. A carbon nanotube array and a cathode substrate are provided. The carbon nanotube array is heated to form a graphitized carbon nanotube array. A conductive adhesive layer is formed on a surface of the cathode substrate. One end of the graphitized carbon nanotube array is contact with the conductive adhesive layer. The conductive adhesive layer is solidified to fix the graphitized carbon nanotube array on the cathode substrate.