Graphitized Carbon Nanotube Polymer Composite Structure

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Solution Overview

Problem

Conventional carbon nanotube structures, primarily in particle or powder forms, lack the mechanical strength necessary for macro-scale applications, limiting their use in structures like carbon nanotube wires due to reliance on van der Waals attractive forces for bonding.

Innovation Solution

A method involving the composition of carbon nanotube structures with polymers, followed by graphitization, to create a composite structure that integrates carbon nanotubes with graphite, enhancing mechanical strength through carbon-carbon bonds in addition to van der Waals forces.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If carbon nanotubes are joined only by van der Waals attractive force, then the structure can be formed, but the mechanical strength is insufficient

Engineering Contradiction:
Improvemechanical strengthVSAvoidbonding mechanism complexity
Core Design Contradiction:
StrengthVSDevice complexity

Solution Approach 1:

The patent creates a composite structure by growing graphite crystals within the carbon nanotube array. This composite approach combines the high strength-to-weight ratio of carbon nanotubes with the strong covalent bonding of graphite, achieving enhanced mechanical strength that exceeds what van der Waals forces alone can provide. The graphite crystals are embedded within the nanotube structure, creating a multi-phase material with superior mechanical properties.

Inventive Principle:
Principle #40Composite materials

2Ease of operation

If conventional particle or powder forms of carbon nanotubes are used, then the material is easy to handle, but macro-scale applications are limited

Engineering Contradiction:
Improveease of handlingVSAvoidmacro-scale structure formation
Core Design Contradiction:
Ease of operationVSLength of moving object

Solution Approach 1:

The patent maintains the individual nanotube segments within the array while enabling them to function as a macro-scale structure. The carbon nanotubes remain as discrete, handleable units that can be processed using conventional techniques, while the overall array structure provides macro-scale integrity and formability. This segmentation allows the material to bridge the gap between microscopic handling and macroscopic application.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

By creating a composite structure with graphite crystals embedded in the carbon nanotube array, the patent achieves macro-scale structural integrity while maintaining the ease of handling characteristics of carbon nanotube materials. The composite structure provides both the mechanical strength needed for macro applications and the processability required for practical manipulation.

Inventive Principle:
Principle #40Composite materials

3Length of moving object

If carbon nanotube wires are drawn from carbon nanotube arrays, then macro-scale structures can be formed, but the mechanical strength needs improvement

Engineering Contradiction:
Improvemacro-scale wire formationVSAvoidmechanical strength
Core Design Contradiction:
Length of moving objectVSStrength

Solution Approach 1:

The patent enhances the mechanical strength of drawn carbon nanotube wires by incorporating graphite crystals within the nanotube array before drawing. This composite structure provides reinforcement that maintains or improves mechanical strength during the drawing process and in the final macro-scale wire product, overcoming the limitation of conventional drawn wires that rely solely on van der Waals forces.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent performs preliminary structuring by growing graphite crystals within the carbon nanotube array before the drawing process. This preliminary action pre-reinforces the nanotube structure with strong covalent bonds, ensuring that the subsequent drawing into macro-scale wires maintains high mechanical strength without requiring additional strengthening steps afterward.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composite carbon nanotube structure exhibits improved mechanical strength and durability, allowing for the formation of free-standing structures and increased surface area, accommodating more polymer and enabling the creation of robust macro-scale structures like wires and films.

Implementation Method 1

graphitizing the polymer composited with the carbon nanotube structure

Methodology Applied
Scientific EffectGraphitization:

Implementation Method 2

The carbon nanotubes joined end to end by van der Waals attractive force therebetween

Methodology Applied
Scientific EffectVan der Waals force: Van der Waals Force

Data Source

PatentUS9561963B2Method for making composite carbon nanotube structure
Publication Date: 2017.02.07 HON HAI PRECISION INDUSTRY CO LTD
  • US9561963B2 patent drawing
  • US9561963B2 patent drawing
  • US9561963B2 patent drawing

AI summary

A method for making a composite carbon nanotube structure is introduced. The method includes the following steps. A carbon nanotube structure and a polymer are provided. The polymer and the carbon nanotube structure are composited together. The composite carbon nanotube structure composited with polymer and the carbon nanotube is then graphitized.