Gravity Electrolyte Drainage for Redox Flow Battery Standby Protection

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Solution Overview

Problem

Iron redox flow batteries face issues with electrolyte degradation due to prolonged immersion in stagnant acid during stand-by mode, and reliance on uninterruptible power supplies (UPS) for electrolyte drainage, which increases system cost and footprint, and may fail if the UPS degrades.

Innovation Solution

A gravity drainage subsystem is introduced, featuring an electrolyte sump tank positioned below the cell stacks and controlled by three-way valves to drain electrolyte via gravity, eliminating the need for additional pumping devices and large UPS systems.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a drain pump is used to drain electrolyte from cell stacks during stand-by mode, then component degradation is reduced, but system complexity and cost increase due to requiring UPS and additional pumping devices

Engineering Contradiction:
Improvecomponent integrityVSAvoidsystem complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The drain pump is extracted from the system and replaced with a passive gravity drainage mechanism. The sump tank is positioned below the cell stacks to enable electrolyte drainage without mechanical pumping, eliminating the need for UPS and reducing system complexity while maintaining component protection during stand-by mode

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The system uses gravity as a free resource to enable automatic electrolyte drainage from cell stacks to the sump tank during stand-by mode. This self-service mechanism requires no external power source or active control, yet effectively prevents component degradation by removing electrolyte contact during idle periods

Inventive Principle:
Principle #25Self-service

2Reliability

If a large UPS is installed to power the drain pump during power loss, then drainage reliability is improved, but system footprint and cost increase

Engineering Contradiction:
Improvedrainage reliabilityVSAvoidsystem footprint
Core Design Contradiction:
ReliabilityVSArea of stationary object

Solution Approach 1:

The large UPS system is extracted from the design by replacing the active pump-based drainage system with a passive gravity-driven system. The sump tank's lower position enables drainage without electrical power, eliminating the need for large UPS infrastructure and reducing system footprint

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The electrical-mechanical drainage system (pump + UPS) is replaced with a gravitational-mechanical system. The height difference between cell stacks and sump tank creates the driving force for electrolyte flow, substituting electrical power requirements with gravitational potential energy

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Use of energy by moving object

If electrolyte circulation is halted during stand-by mode, then energy consumption is reduced, but component degradation occurs due to prolonged immersion in stagnant acid

Engineering Contradiction:
Improveenergy consumptionVSAvoidcomponent integrity
Core Design Contradiction:
Use of energy by moving objectVSReliability

Solution Approach 1:

The system implements periodic drainage and refilling cycles. During stand-by mode, electrolyte is periodically drained to the sump tank to prevent degradation, then refilled when operation resumes. This periodic action maintains component integrity while minimizing energy consumption compared to continuous circulation

Inventive Principle:
Principle #19Periodic action

Solution Approach 2:

The sump tank is pre-positioned below the cell stacks and pre-filled with air or inert gas to create a receiving volume for electrolyte. This preliminary arrangement enables immediate gravity-driven drainage when stand-by mode is activated, protecting components before degradation can occur

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This solution effectively reduces component degradation, simplifies system design, and maintains battery integrity by ensuring electrolyte removal during stand-by mode without relying on large UPS systems, thus extending the battery's useful life and reducing costs.

Implementation Method 1

an electrolyte sump tank positioned below cell stacks of the redox flow battery system, the electrolyte sump tank configured to receive electrolyte from the cell stacks during operation of the redox flow battery system in a stand-by mode

Methodology Applied
Scientific EffectGravity: Gravitation

Data Source

PatentUS20240234760A9Gravity drainage subsystem for redox flow battery system
Publication Date: 2024.07.11 ESS TECH INC
  • US20240234760A9 patent drawing
  • US20240234760A9 patent drawing
  • US20240234760A9 patent drawing

AI summary

Systems and methods are provided for a redox flow battery system. In one example, the redox flow battery system includes an electrolyte sump tank positioned below cell stacks of the redox flow battery system. The electrolyte sump tank may be configured to receive electrolyte from the cell stacks during operation of the redox flow battery system in a stand-by mode. The redox flow battery system may further include three-way valves arranged in a flow path of the electrolyte between the cell stacks and the electrolyte sump tank to control a flow of the electrolyte to the electrolyte sump tank.