Green Solvent Cleaning Composition for Stain Removal

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Solution Overview

Problem

Commercially available cleaners often contain hazardous volatile organic compounds (VOCs) that pose health and environmental risks, are flammable, and lack effectiveness in removing tough stains like permanent marker ink from various surfaces, while eco-friendly alternatives compromise on performance.

Innovation Solution

A cleaning composition comprising a blend of dibasic esters, such as dialkyl methylglutarate and dialkyl adipate or ethylsuccinate, combined with surfactants and optionally d-limonene, which is non-toxic, non-flammable, and biodegradable, effectively removes stains from diverse surfaces including plastics, paints, and textiles.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional VOC-based solvents are used, then cleaning performance is improved, but health and environmental safety deteriorates

Engineering Contradiction:
Improvecleaning performanceVSAvoidhealth and environmental safety
Core Design Contradiction:
ProductivityVSObject-affected harmful factors

Solution Approach 1:

The patent changes the chemical composition parameters by replacing VOC-based solvents with green solvent alternatives (dibasic esters, glycol ethers, alcohols) that have lower toxicity and environmental impact. This parameter change maintains cleaning performance while improving health and environmental safety.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses composite cleaning formulations that combine multiple green solvent components (dibasic esters, glycol ethers, alcohols) with surfactants and other additives to achieve the cleaning performance previously provided by VOC-based solvents, while maintaining non-flammability and low toxicity.

Inventive Principle:
Principle #40Composite materials

2Productivity

If aggressive solvents are used, then stain removal capability is improved, but substrate damage increases

Engineering Contradiction:
Improvestain removal capabilityVSAvoidsubstrate damage
Core Design Contradiction:
ProductivityVSObject-affected harmful factors

Solution Approach 1:

The patent modifies the chemical aggressiveness parameters by using milder green solvents (dibasic esters, glycol ethers) instead of aggressive VOCs, while adjusting formulation parameters (surfactant content, pH) to maintain effective stain removal without causing substrate damage.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent introduces surfactants and other auxiliary components as intermediaries that enhance the cleaning action of green solvents, allowing mild solvents to achieve effective stain removal without requiring aggressive chemistry that would damage substrates.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Object-affected harmful factors

If eco-friendly solvents are used, then environmental safety is improved, but cleaning effectiveness deteriorates

Engineering Contradiction:
Improveenvironmental safetyVSAvoidcleaning effectiveness
Core Design Contradiction:
Object-affected harmful factorsVSProductivity

Solution Approach 1:

The patent creates composite formulations combining multiple green solvent components (dibasic esters, glycol ethers, alcohols) with surfactants and additives to achieve cleaning effectiveness comparable to or exceeding conventional VOC-based cleaners, while maintaining environmental safety.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent replaces the chemical mechanism of VOC-based solvents with alternative chemical mechanisms using green solvents, utilizing different molecular interaction patterns (hydrogen bonding, dipole-dipole interactions) to achieve effective cleaning without relying on volatile organic compounds.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

4Productivity

If flammable VOC solvents are used, then cleaning power is improved, but fire hazard increases

Engineering Contradiction:
Improvecleaning powerVSAvoidfire hazard
Core Design Contradiction:
ProductivityVSObject-affected harmful factors

Solution Approach 1:

The patent fundamentally changes the flammability parameter by selecting green solvent components (dibasic esters, glycol ethers, alcohols) with inherently higher flash points and lower volatility than VOCs, eliminating fire hazards while maintaining cleaning power through formulation optimization.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition meets low VOC exemption criteria, is environmentally friendly, and provides high cleaning efficacy on a range of stains without damaging surfaces, outperforming conventional cleaners in removing permanent marker ink and other tough stains.

Implementation Method 1

a cleaning composition comprising a blend of dibasic esters

Methodology Applied
Scientific EffectSolvation: Solvation

Implementation Method 2

one or more surfactants selected from the group consisting of an anionic surfactant, a cationic surfactant, an amphoteric surfactant, a zwitterionic surfactant, a nonionic surfactant

Methodology Applied
Scientific EffectSurfactant action: Surfactant

Data Source

PatentUS8222194B2Cleaning compositions incorporating green solvents and methods for use
Publication Date: 2012.07.17 SPECIALTY OPERATIONS FRANCE
  • US8222194B2 patent drawing
  • US8222194B2 patent drawing
  • US8222194B2 patent drawing

AI summary

An environmentally-friendly cleaning composition for industrial and consumer applications comprising (a) a blend of dibasic esters, (b) one or more surfactants (c) and, optionally, (d) water or a solvent. The dibasic esters are be derived from a blend of adipic, glutaric, and succinic diacids, and, in one particular embodiment, the blend comprises dialkyl adipate, dialkyl methylglutarate and dialkyl ethylsuccinate, wherein the alkyl groups individually comprise a C1-C12 hydrocarbon group. The one or more surfactants are typically chosen from alcohol alkoxylate, an alkyl phenol ethoxylate, a terpene, a terpene alkoxylate or any derivates thereof. Optionally, additional components or additives including delaminates such as pinene and d-limonene, fragrances, whiteners, stabilizers, thickeners and the like can be added to the composition. The industrial or consumer application selected from the group consisting of a graffiti cleaner, a painted-substrate cleaner, an ink cleaner, a metal substrate cleaner, a plastic substrate cleaner, an environmentally friendly cleaner, a stain-spot cleaner, an industrial hand cleaner, a resin cleaner, a tar resin cleaner, a textile cleaner, a paint stripper and any combination thereof.