Graded Index Optics via Laser-Ablated Nanoparticle Redeployment

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Solution Overview

Problem

Current large optics fabrication techniques, such as diamond turning polishing and Magnetorheological Finishing, lack flexibility for freeform optics and have limited surface quality and laser damage resilience, while existing methods for creating graded refractive index surfaces are either time-consuming or unable to modify the refractive index effectively.

Innovation Solution

A method and system for forming a graded index (GRIN) surface by controlling the fluence profile of optical energy to ablate and redeposit metal nanoparticles on a substrate, allowing for the creation of freeform optics with spatially varying refractive index.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If diamond turning polishing is used to fabricate large optics, then the surface figure can be achieved, but the surface quality and laser damage resilience are limited

Engineering Contradiction:
Improvesurface figureVSAvoidlaser damage resilience
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The patent changes the physical-chemical state of the metal layer by controlling laser fluence parameters. By varying the fluence profile (energy density) of the laser beam, the metal layer transitions through different states (melting, vaporization, ablation) to create nanostructures with enhanced optical properties and laser damage resistance while maintaining the desired surface figure.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent utilizes phase transitions of the metal layer under laser irradiation. The metal layer undergoes phase transitions from solid to liquid to vapor and back to condensed nanostructures. These controlled phase transitions enable the formation of nanostructured surfaces that improve both surface quality and laser damage resilience beyond what conventional polishing can achieve.

Inventive Principle:
Principle #36Phase transitions

2Manufacturing precision

If MRF is used to finish optics, then high quality surface is produced, but the process is time consuming and optical function modulation is limited

Engineering Contradiction:
Improvesurface qualityVSAvoidprocessing time
Core Design Contradiction:
Manufacturing precisionVSProductivity

Solution Approach 1:

The patent replaces the mechanical MRF process with an optical-laser based ablation process. Instead of using magnetorheological fluid and mechanical contact for material removal, the patent uses controlled laser ablation to remove and redeposit metal layer material, significantly reducing processing time while maintaining or improving surface quality and enabling additional optical function modulation through nanostructure formation.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Reliability

If Reactive Ion Etching is used to create nanostructured AR layer, then the refractive index can be modified, but spatial shaping capability is lost

Engineering Contradiction:
Improvelaser-induced damage thresholdVSAvoidspatial shaping capability
Core Design Contradiction:
ReliabilityVSAdaptability or versatility

Solution Approach 1:

The patent applies local quality by creating spatially varying nanostructures through controlled laser fluence profiling. Different regions of the metal layer receive different fluence levels, resulting in localized variations in nanoparticle size, density, and distribution. This enables spatial shaping of the refractive index while maintaining the high laser-induced damage threshold of the nanostructured AR layer.

Inventive Principle:
Principle #3Local quality

4Adaptability or versatility

If masks with nano-sized features are manufactured, then freeform flexibility can be achieved, but the manufacturing complexity increases

Engineering Contradiction:
Improvefreeform flexibilityVSAvoidmask manufacturing complexity
Core Design Contradiction:
Adaptability or versatilityVSDevice complexity

Solution Approach 1:

The patent extracts the mask function from the fabrication process by using the metal layer itself as the source of nanostructures. Instead of requiring separate masks to define nanoparticle patterns, the laser fluence profile directly controls where and how nanoparticles form from the metal layer, eliminating mask manufacturing complexity while maintaining freeform flexibility.

Inventive Principle:
Principle #2Taking out (Extraction)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables the efficient fabrication of freeform optics with enhanced laser damage resilience and optical functionalities, such as meta-surfaces for high power laser systems, by producing masks with nano-sized features and scalable techniques for complex optical components.

Implementation Method 1

controlling a fluence profile of optical energy applied to the metal layer to substantially ablate the metal layer and create a vaporized metal layer

Methodology Applied
Scientific EffectLaser ablation: Laser Ablation

Implementation Method 2

controlling a fluence profile of optical energy applied to the metal layer to substantially ablate the metal layer

Methodology Applied
Scientific EffectHeating: Heating

Implementation Method 3

as the vaporized metal layer condenses and forms metal nanoparticles

Methodology Applied
Scientific EffectCondensation: Condensation

Implementation Method 4

the metal nanoparticles being deposited back on the substrate to form a GRIN surface on the substrate

Methodology Applied
Scientific EffectPhysical vapor deposition: Physical Vapour Deposition

Data Source

PatentEP3776020B1System and method for ablation assisted nanostructure formation for graded index surfaces for optics
Publication Date: 2023.07.05 LAWRENCE LIVERMORE NAT SECURITY LLC
  • EP3776020B1 patent drawingFigure 1~4
  • EP3776020B1 patent drawingFigure 4A~5
  • EP3776020B1 patent drawingFigure 6A~6B

AI summary

A system and method is disclosed for forming a graded index (GRIN) on a substrate. In one implementation the method may involve applying a metal layer to the substrate. A fluence profile of optical energy applied to the metal layer may be controlled to substantially ablate the metal layer to create a vaporized metal layer. The fluence profile may be further controlled to control a size of metal nanoparticles created from the vaporized metal layer as the vaporized metal layer condenses and forms metal nanoparticles, the metal nanoparticles being deposited back on the substrate to form a GRIN surface on the substrate.