Grindable Silicone Elastomer Adhesive for Workpiece Sanding

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Solution Overview

Problem

Existing methods for temporarily adhering sensitive workpieces like gemstones, optical lenses, and semiconductor wafers for sanding or polishing often cause damage due to mechanical fastening, and require adhesives that are sandable, temperature-stable, chemically stable, and easily removable without residue.

Innovation Solution

Crosslinkable silicone elastomer compositions with specific formulations that include nonreinforcing fillers, branched silicone resins, and a combination of aliphatic carbon-carbon multiple bonds and Si-bonded hydrogen atoms, allowing for temporary bonding while maintaining mechanical properties that enable sandability and polishability without damaging the workpieces.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If mechanical fastening is used to secure workpieces for sanding, then the workpiece is firmly held, but the workpiece may be damaged

Engineering Contradiction:
Improvefastening strengthVSAvoidworkpiece damage
Core Design Contradiction:
StrengthVSObject-affected harmful factors

Solution Approach 1:

The patent replaces mechanical fastening systems (clamps, vices, screws) with a chemical adhesive bonding system. The silicone elastomer composition forms a temporary adhesive bond between the workpiece and support substrate, eliminating mechanical contact points that could damage sensitive workpieces while providing sufficient holding strength for sanding operations.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The adhesive's mechanical properties are dynamically adjusted through its service lifecycle: initially providing strong bonding to hold the workpiece, then becoming sandable and removable after curing. The composition changes from a viscous noncrosslinked state (easy to apply) to a crosslinked elastomeric state (sandable and removable), resolving the contradiction between strong fastening and easy removal.

Inventive Principle:
Principle #35Parameter changes

2Strength

If traditional adhesives are used for temporary bonding, then the workpiece is securely attached, but the adhesive cannot be sanded without damaging the sanding apparatus

Engineering Contradiction:
Improveadhesive bonding strengthVSAvoidsanding apparatus damage
Core Design Contradiction:
StrengthVSObject-affected harmful factors

Solution Approach 1:

The adhesive undergoes a fundamental parameter change in its physical state and chemical structure. The noncrosslinked silicone elastomer composition is applied in a soft, moldable state, then crosslinks to form a sandable elastomeric network. This crosslinked structure can be ground away with abrasives without damaging the sanding apparatus, yet maintains sufficient bonding strength during the sanding process.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The adhesive is formulated as a composite material combining silicone elastomer base polymers with specific crosslinking agents and fillers. This composite structure provides the unique property combination of adhesive strength, sandability, and removability - the crosslinked network gives structural integrity for bonding, while the elastomeric nature allows it to be ground away cleanly.

Inventive Principle:
Principle #40Composite materials

3Strength

If high bonding strength is achieved, then the workpiece is securely held, but the adhesive becomes difficult to remove without residue

Engineering Contradiction:
Improvebonding strengthVSAvoidremovability
Core Design Contradiction:
StrengthVSEase of operation

Solution Approach 1:

The adhesive's removal properties are enabled by parameter changes in its chemical structure and thermal behavior. The crosslinked silicone elastomer network can be heated to temperatures where it softens and becomes pliable, allowing complete removal from the workpiece without residue. The elastomeric nature of the cured adhesive allows it to be stretched and pulled away cleanly, unlike rigid adhesives that leave fragments.

Inventive Principle:
Principle #35Parameter changes

4Object-affected harmful factors

If the adhesive is made sandable, then the sanding apparatus remains clean, but the adhesive may lack sufficient mechanical strength

Engineering Contradiction:
Improveapparatus soilingVSAvoidadhesive strength
Core Design Contradiction:
Object-affected harmful factorsVSStrength

Solution Approach 1:

The adhesive is formulated as a composite material combining silicone elastomer base polymers with specific crosslinking agents and fillers. This composite structure provides the unique property combination of adhesive strength, sandability, and removability - the crosslinked network gives structural integrity for bonding, while the elastomeric nature allows it to be ground away cleanly.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The adhesive undergoes a fundamental parameter change in its physical state and chemical structure. The noncrosslinked silicone elastomer composition is applied in a soft, moldable state, then crosslinks to form a sandable elastomeric network. This crosslinked structure can be ground away with abrasives without damaging the sanding apparatus, yet maintains sufficient bonding strength during the sanding process.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The silicone elastomer compositions provide a stable, removable, and residue-free bonding solution that withstands high temperatures, is chemically stable, and minimizes volatile by-products, ensuring the integrity of both the workpieces and the sanding/polishing apparatus.

Implementation Method 1

crosslinkable silicone elastomer compositions... comprising (E) 35-80% by weight of at least one compound selected from the group containing nonreinforcing fillers, branched silicone resins or mixtures thereof

Methodology Applied
Scientific EffectCrosslinking: Chemical Bonding

Implementation Method 2

a good temperature stability at up to more than 300° C. is necessary, in order to withstand the friction, and hence increase in temperature, caused by the sanding or polishing

Methodology Applied
Scientific EffectThermal stability: Thermal Expansion

Data Source

PatentUS8696861B2Grindable silicone elastomer composition and the use thereof
Publication Date: 2014.04.15 NISSAN CHEM CORP

AI summary

Temporary adhesive compositions used to adhesively bond a substrate to be abraded or polished onto a substrate are themselves abradable or polishable, and contain a non-reinforcing filler or particulate silicone resin in a curable organopolysiloxane composition, and have defined physical characteristics in addition to being thermally stable.