H2O2 Etchant for Flat Recess Profiles in Semiconductor Substrates

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Solution Overview

Problem

Conventional semiconductor processes using ammonia water to etch recesses in MOS transistors result in V-shaped profiles, leading to circuit leakages and diminished electrical quality, especially as device dimensions scale down.

Innovation Solution

A semiconductor process employing an etchant comprising H2O2 or a mixture of NH4OH/H2O2 to form a flat-bottomed recess, which reduces etching rates and prevents circuit leakages by smoothing the recess profile.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If ammonia water is used as an etchant to etch the specific area, then the etching process is simple and cost-effective, but the recess profile becomes V-shaped leading to circuit leakages and diminished electrical quality

Engineering Contradiction:
Improveetching process simplicityVSAvoidrecess profile flatness
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The patent changes the chemical composition parameters of the etchant by incorporating H2O2 (hydrogen peroxide) into the ammonia water solution. This parameter modification transforms the etching chemistry to produce a flat-bottomed recess profile while maintaining the simplicity and cost-effectiveness of wet etching processes.

Inventive Principle:
Principle #35Parameter changes

2Ease of manufacture

If ammonia water is used as an etchant, then the etching cost is low, but the electrical quality of the semiconductor device is diminished due to V-shaped recess profile

Engineering Contradiction:
Improveetching costVSAvoidelectrical quality
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent modifies the chemical parameters of the etchant solution by adding H2O2 to ammonia water, which changes the etching mechanism to produce flat-bottomed recesses. This improves electrical quality and prevents circuit leakages while keeping the process cost-effective compared to alternative methods.

Inventive Principle:
Principle #35Parameter changes

3Length of stationary object

If conventional etching methods are used to etch deep recesses, then the etching depth is sufficient, but the recess profile becomes V-shaped causing circuit leakages

Engineering Contradiction:
Improverecess depthVSAvoidrecess profile
Core Design Contradiction:
Length of stationary objectVSShape

Solution Approach 1:

The patent changes the chemical composition parameters of the etchant to include H2O2, which modifies the etching kinetics to achieve both sufficient depth and a flat-bottomed profile. The altered chemistry enables uniform etching across the recess bottom while maintaining adequate etching depth for device requirements.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The process effectively forms a flat-bottomed recess, enhancing the electrical quality of semiconductor devices by reducing etching time and costs while preventing circuit leakages.

Implementation Method 1

performing an etch process to etch the specific area for forming a recess by using an etchant including H2O2

Methodology Applied
Scientific EffectChemical etching: Chemical Bonding

Data Source

PatentUS8329547B2Semiconductor process for etching a recess into a substrate by using an etchant that contains hydrogen peroxide
Publication Date: 2012.12.11 UNITED MICROELECTRONICS CORP
  • US8329547B2 patent drawing
  • US8329547B2 patent drawing
  • US8329547B2 patent drawing

AI summary

A semiconductor process is disclosed. The semiconductor process includes the steps of: providing a substrate having a specific area defined thereon; and performing an etch process by using an etchant comprising H2O2 to etch the specific area for forming a recess.