In Situ H2O2-Nitrite Disinfection With Retarded Active Release

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Solution Overview

Problem

Existing disinfection methods using hydrogen peroxide (H2O2) and nitrite (NO2−) solutions face high initial reaction rates upon mixing, leading to excessive reactant consumption before the disinfection process, increasing costs and safety risks due to unintended biocidal effects, and requiring high initial concentrations.

Innovation Solution

A method involving a solvent with a boiling temperature below 100°C is used to retard the reaction rate between H2O2 and NO2−, allowing for controlled and prolonged processing times by forming active disinfectants in situ, with additives like solvents, buffers, and dyes, and a device for simultaneous delivery of H2O2 and NO2− solutions using synchronized pistons.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If high initial concentrations of H2O2 and NO2− are used to ensure sufficient biocidal effect during exposure time, then the disinfection efficacy is improved, but the costs for disinfectant supply increase and the risk for unintended biocidal effects during distribution period increases

Engineering Contradiction:
Improvedisinfection efficacyVSAvoidunintended biocidal effects
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent applies preliminary action by adding the retarding solvent to the reactant mixture before the distribution step begins. This pre-prepared mixture ensures that the reaction rate is controlled from the start, preventing excessive consumption of reactants during the distribution period while maintaining sufficient concentrations for effective disinfection during exposure time.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent changes the physical-chemical parameters of the reaction system by introducing a retarding solvent that modifies the reaction kinetics. This solvent reduces the reaction rate constant, allowing the system to maintain stable reactant concentrations throughout the distribution period, thereby eliminating the need for high initial concentrations and their associated risks.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If high initial concentrations of H2O2 and NO2− are used to ensure sufficient biocidal effect during exposure time, then the disinfection efficacy is improved, but the costs for disinfectant supply increase

Engineering Contradiction:
Improvedisinfection efficacyVSAvoidreactant consumption
Core Design Contradiction:
ReliabilityVSQuantity of substance

Solution Approach 1:

The patent changes the reaction kinetics parameters by introducing a retarding solvent, which reduces the reaction rate constant. This allows the system to maintain reactant concentrations at moderate levels throughout the distribution period, ensuring that sufficient reactants remain available for the exposure phase without requiring high initial concentrations, thereby reducing overall reactant consumption and costs.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If the reaction rate is high directly after mixing H2O2 and NO2−, then the biocidal effect is strong, but the reactants are consumed before the disinfection process begins, reducing availability during exposure time

Engineering Contradiction:
Improvebiocidal effect strengthVSAvoidreactant availability duration
Core Design Contradiction:
ReliabilityVSDuration of action of moving object

Solution Approach 1:

The patent modifies the reaction rate parameter by adding a retarding solvent to the mixture. This solvent reduces the reaction rate constant, creating a balanced profile where the reaction proceeds at a moderate pace during distribution, preserving reactant availability for the exposure phase while still delivering effective biocidal action during the intended treatment period.

Inventive Principle:
Principle #35Parameter changes

4Duration of action of moving object

If a retarding solvent is added to reduce the reaction rate, then the processing time is prolonged and reactant availability is improved, but the concentration of the retarding solvent must be controlled

Engineering Contradiction:
Improveprocessing timeVSAvoidsolvent concentration control
Core Design Contradiction:
Duration of action of moving objectVSDevice complexity

Solution Approach 1:

The patent utilizes parameter changes by selecting a retarding solvent with specific physical properties (boiling point below 100°C) that allow for automatic concentration control through evaporation. This self-regulating mechanism reduces the need for complex external control systems, as the solvent naturally evaporates during the process, maintaining optimal concentration levels without requiring sophisticated monitoring or adjustment equipment.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method achieves effective disinfection with reduced reactant consumption and prolonged efficacy, ensuring biocidal action on surfaces, including sporicidal effects, while minimizing environmental release of harmful substances.

Implementation Method 1

a solvent with a boiling temperature below 100°C is used to retard the reaction rate between H2O2 and NO2−, allowing for controlled and prolonged processing times

Methodology Applied
Scientific EffectEvaporation: Evaporation

Implementation Method 2

the biocidal effect of the reaction products of hydrogen peroxide (H2O2) and nitrite (NO2−) with the addition of an acid is already known in literature

Methodology Applied
Scientific EffectChemical reaction: Chemical Bonding

Data Source

PatentUS12582735B2Disinfection method comprising a disinfectant formed by reaction of H<sub>2</sub>O<sub>2 </sub>and NO<sub>2 </sub>in situ with retarded release of the active substance
Publication Date: 2026.03.24 NEBULA BIOCIDES GMBH
  • US12582735B2 patent drawing
  • US12582735B2 patent drawing
  • US12582735B2 patent drawing

AI summary

The invention relates to a method for disinfecting surfaces comprising providing an active solution comprising the reactants H2O2 and NO2−, wherein the active solution comprises at least one stopping agent, wherein the stopping agent is a solvent having a boiling temperature below 100° C. Furthermore, the invention relates to a device for the application of this process.