Hydrogen Sulfide Scavenger Blend Optimization

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Solution Overview

Problem

Conventional hydrogen sulfide scavengers face challenges in effectively removing H2S from fluid streams due to high costs and insufficient removal efficiency, while also causing scale formation issues due to pH increases, which can lead to corrosive and flammable conditions.

Innovation Solution

A method involving a blend of hydrogen sulfide scavengers, utilizing statistical methods like response surface methodology to optimize scavenging capacity and pH, balancing scavenging efficiency with scale minimization by varying blend parameters such as component proportions and pH, to achieve synergistic effects and reduce antagonistic interactions.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional hydrogen sulfide scavengers are used to remove H2S from fluid streams, then H2S removal is achieved, but scale formation occurs due to pH increases

Engineering Contradiction:
ImproveH2S removal efficiencyVSAvoidscale formation
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent applies parameter changes by modifying the pH level parameter of the scavenger system. Instead of operating at high pH levels that cause scale formation, the invention operates at lower pH levels (below 9.0, preferably below 8.5) while maintaining effective H2S scavenging capacity through the use of specific scavenger blends and formulations that are effective at these lower pH conditions.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite materials by using blends of multiple scavengers rather than a single scavenger compound. These composite scavenger systems combine different chemicals that work synergistically to maintain high H2S removal efficiency while operating at lower pH levels, thereby preventing scale formation that would occur with conventional single-scavenger high-pH systems.

Inventive Principle:
Principle #40Composite materials

2Reliability

If scavenger blend parameters are optimized to improve scavenging capacity, then H2S removal efficiency increases, but the complexity of blend formulation increases

Engineering Contradiction:
Improvescavenging capacityVSAvoidblend formulation complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent systematically varies and optimizes blend parameters including the types of scavengers used, their proportions, pH levels, and other formulation parameters. Through response surface methodology and statistical analysis, the invention identifies optimal parameter combinations that maximize scavenging capacity while managing formulation complexity, providing a structured approach to blend optimization.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The optimized blend achieves improved hydrogen sulfide scavenging capacity at lower pH levels, minimizing scale formation and maintaining effective scavenging performance without increasing the risk of corrosive conditions.

Implementation Method 1

selective reaction of H2S with a reagent to produce a readily separable product

Methodology Applied
Scientific EffectChemical reaction: Chemical Bonding

Implementation Method 2

The optimized blend achieves improved hydrogen sulfide scavenging capacity at lower pH levels, minimizing scale formation

Methodology Applied
Scientific EffectpH control:

Data Source

PatentUS10745633B2Method of predicting/optimizing hydrogen sulfide scavenging capacity and reduction of scale formation
Publication Date: 2020.08.18 SHCLUMBERGER NORGE AS
  • US10745633B2 patent drawing
  • US10745633B2 patent drawing
  • US10745633B2 patent drawing

AI summary

A method of optimizing a hydrogen sulfide scavenger blend that includes selecting a hydrogen sulfide scavenger blend comprising at least two hydrogen sulfide scavengers; determining a scavenging capacity for the blend; modifying at least one blend parameter based on the determined scavenging capacity; redetermining the scavenging capacity for the modified blend; and selecting an optimized blend from the blend and the modified blend is disclosed.