Conductive Hafnium Silicate Seed Layer for Magnetic Tunnel Junctions

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Solution Overview

Problem

Current semiconductor memory devices face challenges in achieving low resistance and high tunneling magnetoresistance characteristics while maintaining reliable data storage due to issues with parasitic resistance and incoherent tunneling effects, particularly in magnetic tunnel junctions with insulating seed layers.

Innovation Solution

The use of a conductive hafnium silicate seed layer with an oxygen content of 1-10% improves the anisotropy energy and retention characteristics of magnetic layers, enhancing the low resistance and TMR characteristics by forming a stacked structure with magnetic layers and a tunnel barrier layer, and incorporating a dual phase barrier layer with different crystal structures to stabilize the magnetic properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If an insulating seed layer is used in magnetic tunnel junctions, then the tunneling magnetoresistance characteristics can be achieved, but parasitic resistance increases and low resistance characteristics deteriorate

Engineering Contradiction:
Improvetunneling magnetoresistance characteristicsVSAvoidparasitic resistance
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent employs a composite seed layer structure consisting of a conductive hafnium silicate layer combined with magnetic layers (CoFeB, CoFe) and tunnel barrier layers (MgO). This composite structure integrates both conductive and magnetic properties, enabling simultaneous achievement of low parasitic resistance and high tunneling magnetoresistance characteristics through the synergistic interaction of different materials.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent optimizes the oxygen content in the hafnium silicate seed layer within a specific range (1-10%) to achieve the desired balance between conductivity and magnetic properties. By controlling the oxygen concentration parameter, the seed layer maintains sufficient electrical conductivity while providing adequate magnetic anisotropy energy for stable magnetization.

Inventive Principle:
Principle #35Parameter changes

2Speed

If the magnetic layer thickness is reduced to improve switching characteristics, then the switching speed improves, but the retention characteristics and data storage reliability worsen

Engineering Contradiction:
Improveswitching speedVSAvoidretention characteristics
Core Design Contradiction:
SpeedVSReliability

Solution Approach 1:

The patent utilizes perpendicular magnetic anisotropy (PMA) induced by the conductive hafnium silicate seed layer to achieve stable magnetization at reduced thickness. The PMA effect allows the magnetic layers to maintain sufficient coercive force and retention characteristics even when thickness is reduced to 3-5 nm, enabling fast switching while preserving data storage reliability.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The combination of conductive hafnium silicate with specific magnetic materials (CoFeB, CoFe) creates a composite structure where the interface between layers generates perpendicular magnetic anisotropy. This composite approach enables the magnetic layers to achieve both thin thickness for fast switching and sufficient magnetic stability for reliable data retention.

Inventive Principle:
Principle #40Composite materials

3Stability of the object's composition

If a dual phase barrier layer with different crystal structures is introduced to stabilize magnetic properties, then the magnetic stability improves, but the device structure complexity increases

Engineering Contradiction:
Improvemagnetic stabilityVSAvoidstructure complexity
Core Design Contradiction:
Stability of the object's compositionVSDevice complexity

Solution Approach 1:

The patent employs a dual phase barrier layer comprising MgO with different crystal structures (cubic and tetragonal phases) in a composite configuration. The cubic phase provides good electrical insulation and tunneling properties, while the tetragonal phase contributes to magnetic anisotropy and stability. This composite barrier structure achieves enhanced magnetic stability without requiring additional separate functional layers.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach results in improved switching and retention characteristics, lower resistance, and higher TMR, effectively addressing the limitations of existing semiconductor memory devices by stabilizing magnetic properties and enhancing data storage reliability.

Implementation Method 1

The conductive hafnium silicate seed layer with an oxygen content of 1-10% improves the anisotropy energy and retention characteristics of magnetic layers

Methodology Applied
Scientific EffectAnisotropy energy: Anisotropy

Implementation Method 2

enhancing the low resistance and TMR characteristics by forming a stacked structure with magnetic layers and a tunnel barrier layer

Methodology Applied
Scientific EffectTunneling magnetoresistance: Magnetoresistance

Data Source

PatentUS10305030B2Electronic device and method for fabricating the same
Publication Date: 2019.05.28 SK HYNIX INC
  • US10305030B2 patent drawing
  • US10305030B2 patent drawing
  • US10305030B2 patent drawing

AI summary

Electronic devices and systems having semiconductor memory are provided. In one implementation, for example, an electronic device may include a substrate; an under layer disposed over the substrate and including conductive hafnium silicate; a free layer disposed over the under layer and having a variable magnetization direction; a tunnel barrier layer disposed over the free layer; and a pinned layer disposed over the tunnel barrier layer and having a pinned magnetization direction, and wherein the free layer includes: a first ferromagnetic material; a second ferromagnetic material having a coercive force smaller than that of the first ferromagnetic material; and an amorphous spacer interposed between the first ferromagnetic material and the second ferromagnetic material.