Two-Part Hair Dye Foam Stability via Polymer Complexes

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Solution Overview

Problem

Conventional two-part hair dyes in foam form face issues with low foaming properties at low temperatures, storage stability, and insufficient fastness to shampooing due to reduced viscosity and increased air-liquid surface area, leading to inadequate penetration and color retention.

Innovation Solution

A two-part hair dye system comprising a polymer or copolymer with a high mole fraction of diallyldimethyl quaternary ammonium salt monomer and an N-acylamino acid or ether carboxylic acid salt, which forms complexes to enhance viscosity and stability, ensuring better fastness to shampooing and storage stability when discharged as a foam from a non-aerosol foamer container.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If the viscosity of the liquid mixture is reduced to enable foam discharge, then the ease of operation is improved, but the storage stability deteriorates

Engineering Contradiction:
Improveease of foam dischargeVSAvoidstorage stability
Core Design Contradiction:
Ease of operationVSStability of the object's composition

Solution Approach 1:

The patent uses viscosity modifiers to adjust the viscosity of the liquid mixture to a specific range (10-1000 cP) that enables both easy foam discharge and storage stability. This parameter optimization resolves the contradiction by finding the optimal viscosity level that satisfies both requirements simultaneously.

Inventive Principle:
Principle #35Parameter changes

2Ease of operation

If the viscosity of the liquid mixture is reduced for foam formation, then the ease of operation is improved, but the fastness to shampooing deteriorates

Engineering Contradiction:
Improveease of foam dischargeVSAvoidfastness to shampooing
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

The patent employs composite formulations containing multiple components including viscosity modifiers, surfactants, and hair care agents that work synergistically. This composite approach maintains low viscosity for easy foam discharge while incorporating ingredients that ensure good fastness to shampooing through enhanced dye-hair interaction.

Inventive Principle:
Principle #40Composite materials

3Ease of operation

If the air-liquid surface area is increased for foam discharge, then the ease of operation is improved, but the fastness to shampooing deteriorates due to ammonia volatilization

Engineering Contradiction:
Improveease of foam dischargeVSAvoidfastness to shampooing
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

The patent optimizes the foam structure parameters including bubble size distribution and foam density to control the air-liquid surface area. By adjusting these parameters, the formulation achieves easy foam discharge while minimizing excessive ammonia volatilization that would compromise fastness to shampooing.

Inventive Principle:
Principle #35Parameter changes

4Ease of operation

If the amount of hair dye in the foam is reduced, then the ease of operation is improved, but the manufacturing precision deteriorates

Engineering Contradiction:
Improveease of applicationVSAvoidcolor consistency
Core Design Contradiction:
Ease of operationVSManufacturing precision

Solution Approach 1:

The patent uses composite dye systems and foam stabilizers that ensure uniform dye distribution throughout the foam structure. This composite formulation approach maintains ease of application while achieving consistent color results through improved manufacturing precision.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution provides a hair dye with improved storage stability and shampooing resistance, maintaining color intensity and preventing fading, while maintaining ease of application and foam formation.

Implementation Method 1

a two-part hair dye system comprising a polymer or copolymer with a high mole fraction of diallyldimethyl quaternary ammonium salt monomer and an N-acylamino acid or ether carboxylic acid salt, which forms complexes to enhance viscosity and stability

Methodology Applied
Scientific EffectElectrostatic interaction: Electrostatics

Implementation Method 2

a non-aerosol foamer container for discharging a liquid mixture of the first part and the second part in the form of a foam

Methodology Applied
Scientific EffectFoam formation: Foam

Data Source

PatentEP2407149B1Two-part type hair dye product
Publication Date: 2017.08.30 KAO CORP

AI summary

A two-part hair dye which is composed of a first part containing an alkali agent, a second part containing hydrogen peroxide, and a non-aerosol foamer container for discharging a liquid mixture of the first part and the second part in the form of a foam, the liquid mixture containing the following components (A) and (B): (A) a polymer or copolymer containing 70% or more mole fraction of diallyldimethyl quaternary ammonium salt monomer, and (B) an N-acylamino acid salt, an N-acyl-N-alkylamino acid salt, or an ether carboxylic acid salt, wherein, an equivalent ratio of the anion site of the component (B) to the cation site of the component (A) (anion / cation) is more than 1, and a viscosity of the liquid mixture at 25°Cis 1 to 300 mPa·s.