Alkali Metal Halide-Coated Metal Oxide Nanoparticles for Moisture Stability

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Solution Overview

Problem

Metal oxides used in semiconductor devices are prone to performance degradation due to water and oxygen exposure, leading to adverse chemical interactions and stability issues.

Innovation Solution

A composite material is developed by coating metal oxide nanoparticles with an alkali metal halide shell layer, which enhances stability and adjusts electron tunneling properties, thereby improving device performance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If metal oxide nanoparticles are used in semiconductor devices, then semiconductor properties are achieved, but performance degradation occurs due to water and oxygen exposure

Engineering Contradiction:
Improvestability of metal oxideVSAvoidwater and oxygen exposure
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

An alkali metal halide shell layer is introduced as an intermediary between the metal oxide nanoparticle core and the external water-oxygen environment. This shell layer acts as a protective barrier that prevents direct contact between harmful external factors and the metal oxide surface, thereby maintaining stability and preventing performance degradation while allowing the semiconductor properties to be preserved.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The invention creates a composite material structure consisting of a metal oxide nanoparticle core coated with an alkali metal halide shell. This composite structure combines the semiconductor properties of metal oxides with the protective characteristics of alkali metal halides, achieving both functional performance and environmental stability in the same material system.

Inventive Principle:
Principle #40Composite materials

2Reliability

If a shell layer is coated on metal oxide nanoparticles to improve stability, then protection against water and oxygen is achieved, but device complexity increases

Engineering Contradiction:
Improvestability against water and oxygenVSAvoidstructure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

A thin film shell layer of alkali metal halide is formed on the metal oxide nanoparticle surface. This thin film approach provides effective protection against water and oxygen exposure while minimizing the added structural complexity and maintaining the nanoscale dimensions necessary for semiconductor device functionality.

Inventive Principle:
Principle #30Flexible shells and thin films

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composite material improves the stability of metal oxides against water and oxygen, reduces electron injection barriers, and enhances the efficiency of optoelectronic devices.

Implementation Method 1

a shell layer coated on a surface of the metal oxide nanoparticle, a material of the shell layer including an alkali metal halide

Methodology Applied
Scientific EffectPhysical barrier protection:

Implementation Method 2

adjusts electron tunneling properties, thereby improving device performance

Methodology Applied
Scientific EffectElectron tunneling:

Data Source

PatentUS20260035260A1Composite material, preparation method thereof, and optoelectronic device
Publication Date: 2026.02.05 SHENZHEN TCL HIGH TECH DEVELOPMENT CO LTD
  • US20260035260A1 patent drawing
  • US20260035260A1 patent drawing

AI summary

The present disclosure provides a composite material, a preparation method thereof and an optoelectronic device. The composite material includes a metal oxide nanoparticle and a shell layer coated on a surface of the metal oxide nanoparticle, a material of the shell layer including an alkali metal halide. In the composite material, the surface of the metal oxide nanoparticle is coated with the alkali metal halide, which is helpful to improve the stability of the metal oxide nanoparticle in the electrification process and reduce electrochemical changes.