Halogen-Free Flame-Retardant Composite Board Recycling

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Solution Overview

Problem

The challenge lies in effectively recycling and reusing waste fiber composite materials from production processes, particularly in making them halogen-free flame-retardant thermoplastic braided fiber reinforced polymer composite boards while maintaining mechanical strength and passing flammability standards, as traditional disposal methods are environmentally and economically unsustainable.

Innovation Solution

A manufacturing method involving the preparation of a recycled material with a halogen-free flame-retardant thermoplastic braided fiber reinforced polymer composite, forming a core layer through extrusion, and hot pressing it with a reinforcement layer to create a composite board where the recycled fiber core penetrates and cross-links with the reinforcement layer, achieving mechanical strength and UL94-V0 flammability compliance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If traditional landfill and incineration treatment methods are used for waste fiber composite materials, then disposal is simple, but environmental harm increases and landfill costs increase

Engineering Contradiction:
Improvedisposal simplicityVSAvoidenvironmental harm
Core Design Contradiction:
Ease of manufactureVSObject-affected harmful factors

Solution Approach 1:

The patent applies the discarding and recovering principle by collecting waste fiber composite materials from production processes and transforming them into reusable core layer materials through extrusion. The recycled fibers are processed into granules, mixed with virgin polymer, and extruded to form a core layer that can be hot-pressed into composite boards, thereby recovering valuable materials instead of discarding them through landfill or incineration.

Inventive Principle:
Principle #34Discarding and recovering

2Productivity

If recycled fiber composite materials are used to manufacture new composite boards, then material recycling is achieved, but mechanical strength may be compromised

Engineering Contradiction:
Improvematerial recycling rateVSAvoidmechanical strength
Core Design Contradiction:
ProductivityVSStrength

Solution Approach 1:

The patent applies the composite materials principle by creating a layered structure where a core layer made of recycled fiber composite materials is sandwiched between reinforcement layers made of virgin or high-performance fibers. This composite structure allows the recycled core to provide bulk material efficiency while the outer reinforcement layers restore and enhance the overall mechanical strength, achieving both recycling goals and structural performance requirements.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent applies the local quality principle by assigning different functional requirements to different parts of the composite board. The core layer made from recycled materials is positioned in the interior where it provides volume and basic structural support, while the reinforcement layers made from higher quality materials are positioned at the surfaces where they bear the primary mechanical loads. This localized material assignment optimizes both recycling utilization and mechanical performance.

Inventive Principle:
Principle #3Local quality

3Reliability

If flame retardant additives are added to achieve flammability standards, then fire safety is improved, but halogen-containing additives may cause environmental and health issues

Engineering Contradiction:
Improvefire safetyVSAvoidhalogen pollution
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent applies the parameter changes principle by changing the chemical composition parameters of the flame retardant system. Instead of using traditional halogen-containing flame retardants, the invention employs halogen-free flame retardant additives that maintain the required fire safety performance (achieving UL94-V0 rating) while eliminating the harmful halogen elements that cause environmental pollution and health issues during combustion.

Inventive Principle:
Principle #35Parameter changes

4Strength

If fiber length is increased to improve mechanical strength, then strength is improved, but processing difficulty and cost increase

Engineering Contradiction:
Improvemechanical strengthVSAvoidprocessing complexity
Core Design Contradiction:
StrengthVSDevice complexity

Solution Approach 1:

The patent applies the local quality principle by using different fiber length specifications in different layers of the composite board. The core layer made from recycled materials uses shorter fiber granules that are easier to process and extrude, while the reinforcement layers use longer, higher-quality fibers that provide the necessary mechanical strength. This localized fiber length assignment optimizes both processing ease and final product performance.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method enables the recovery and recycling of fiber composite waste, enhancing mechanical strength and ensuring compliance with stringent flammability standards, thus addressing environmental and legislative pressures by producing a halogen-free flame-retardant composite board with improved mechanical properties and recyclability.

Implementation Method 1

adding a polymer base material to the recycled material to form a core layer material and extruding the core layer material with a low shear extruder

Methodology Applied
Scientific EffectExtrusion: Extrusion

Implementation Method 2

extruding the core layer material with a low shear extruder

Methodology Applied
Scientific EffectPlastic deformation: Plasticity

Implementation Method 3

hot pressing the core layer material by rollers to obtain a recycled fiber core layer

Methodology Applied
Scientific EffectHot pressing: Heat Treatment

Implementation Method 4

stacking and hot pressing the recycled fiber core layer and the reinforcement layer to cause the halogen-free flame-retardant thermoplastic braided fiber reinforced polymer composite of the recycled fiber core layer penetrating into the pores of the reinforcement layer

Methodology Applied
Scientific EffectPenetration: Permeation

Implementation Method 5

penetrating into the pores of the reinforcement layer to form a composite board in which dissimilar materials of recycled fiber core layer and the reinforcement layer are cross-linked with each other

Methodology Applied
Scientific EffectDiffusion: Diffusion

Implementation Method 6

stacking and hot pressing the recycled fiber core layer and the reinforcement layer

Methodology Applied
Scientific EffectHeating: Heating

Data Source

PatentUS11691354B2Manufacturing method of halogen-free flame-retardant thermoplastic braided fiber reinforced polymer composite board and product thereof
Publication Date: 2023.07.04 COMPLAM MATERIAL
  • US11691354B2 patent drawing
  • US11691354B2 patent drawing
  • US11691354B2 patent drawing

AI summary

A manufacturing method of a halogen-free flame-retardant thermoplastic braided fiber reinforced polymer composite board, comprising steps of: preparing a recycled material containing a halogen-free flame-retardant thermoplastic braided fiber reinforced polymer composite; adding a polymer base material to the recycled material to form a core layer material and extruding the core layer material with a low shear extruder; hot pressing the core layer material by rollers to obtain a recycled fiber core layer; preparing a reinforcement layer containing a fiber material or a fabric with pores; and stacking and hot pressing the recycled fiber core layer and the reinforcement layer.