Halogen-Free Intumescent Coating Using Terpene Binders

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Solution Overview

Problem

Solvent-based fire protection coatings have poor weather resistance due to their porosity and reliance on halogen-containing components, which impair the stability of the coating by allowing water penetration.

Innovation Solution

A halogen-free intumescent fire protection coating using a film-forming binder based on terpenes or polyterpenes, combined with melamine, ammonium phosphates, and carbon-forming substances, along with auxiliaries and additives, to enhance weather stability and fire protection without chlorinated paraffin.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If solvent-based fire protection coatings use halogen-containing components and mineral oil derivatives as binders, then fire protection performance is achieved, but weather resistance deteriorates due to porosity and water penetration

Engineering Contradiction:
Improvefire protection performanceVSAvoidweather resistance
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The patent removes halogen-containing components (specifically chlorinated paraffin) and mineral oil derivative binders from the coating formulation. This extraction eliminates the sources of poor weather resistance while maintaining fire protection through alternative halogen-free flame retardant systems and natural oil-based binders

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent changes the chemical composition parameters by substituting synthetic halogenated compounds with natural oil-based binders (linseed oil, tung oil, soya bean oil) and halogen-free flame retardants. This parameter change transforms the coating from halogen-based to halogen-free, improving weather resistance while preserving fire protection capabilities

Inventive Principle:
Principle #35Parameter changes

2Stability of the object's composition

If the coating uses natural oil-based binders without halogenated components, then weather resistance improves, but fire protection performance may deteriorate

Engineering Contradiction:
Improveweather resistanceVSAvoidfire protection performance
Core Design Contradiction:
Stability of the object's compositionVSReliability

Solution Approach 1:

The patent creates a composite coating system combining natural oil-based binders with halogen-free flame retardant components (ammonium polyphosphate, melamine, pentaerythritol, zinc borate). This composite approach integrates the weather resistance benefits of natural oils with the fire protection capabilities of inorganic flame retardants, achieving both objectives simultaneously

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent replicates the fire protection function previously achieved by halogenated compounds through alternative chemical mechanisms. Instead of using chlorinated paraffin for flame retardancy, the system uses combinations of ammonium polyphosphate, melamine, and zinc borate that provide equivalent or superior fire protection without compromising weather resistance

Inventive Principle:
Principle #26Copying

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The coating achieves improved weathering stability and maintains effective fire protection properties, preventing water penetration and ensuring durability even when the pigment volume concentration reaches the supercritical range.

Implementation Method 1

Intumescent fire protection coatings, also known as insulating coatings, are characterized by the fact that they foam up in the event of a fire under the influence of appropriate temperatures

Methodology Applied
Scientific EffectIntumescent foaming: Intumescent Materials

Implementation Method 2

this foaming of the aforementioned fire protection coating prevents or at least hinders the transmission of heat to ceilings, steel structures, walls, cables, pipes and other materials

Methodology Applied
Scientific EffectThermal insulation: Thermal Insulation

Data Source

PatentEP3426731B1Halogen-free, intumescent fire-proof coating, and use thereof
Publication Date: 2021.05.12 CLARIANT INT LTD
  • EP3426731B1 patent drawing
  • EP3426731B1 patent drawing

AI summary

The invention relates to a halogen-free, intumescent fire-proof coating, characterised in that it contains at least one terpene- and/or polyterpene-based film-forming binder, and to the use thereof.