Halogen-Free Intumescent Composite Coatings

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Solution Overview

Problem

Current thermosetting compositions for intumescent composite parts face challenges in achieving excellent fire resistance, mechanical strength, reduced toxicity and opacity of fumes, and stability, while maintaining ease of application and handling, without using halogens or toxic compounds.

Innovation Solution

A specific thermosetting composition is developed, comprising unsaturated polyester or vinyl ester resins, reactive diluents, melamine derivatives, aluminum trihydrate, carbonization precursors, phosphorus derivatives, and metal oxides, which work together to create a synergistic effect that enhances intumescent behavior, mechanical strength, and reduces toxicity and smoke opacity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If thermosetting compositions use halogenated additives or compounds to improve fire resistance, then fire resistance performance is improved, but toxicity and harmful environmental effects increase

Engineering Contradiction:
Improvefire resistanceVSAvoidtoxicity
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent converts potentially harmful halogenated compounds into beneficial fire-retardant intumescent coatings through careful formulation. The composition uses halogenated additives specifically to create protective char layers that insulate the substrate from fire, while the overall formulation is designed to minimize toxic smoke generation and meet M1F1 classification standards for low smoke toxicity.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Solution Approach 2:

The patent employs composite material formulation by combining multiple components including halogenated additives, intumescent agents, resins, and fillers in specific proportions. This composite approach allows the composition to achieve both fire resistance and reduced toxicity by leveraging the synergistic effects of different materials, where the halogenated components provide fire retardancy while other components suppress smoke and toxic gas formation.

Inventive Principle:
Principle #40Composite materials

2Reliability

If thermosetting compositions use halogenated additives to improve fire resistance, then fire resistance performance is improved, but environmental harmfulness increases

Engineering Contradiction:
Improvefire resistanceVSAvoidenvironmental harmfulness
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent transforms the environmental concerns around halogenated compounds by formulating them into controlled-release fire-retardant systems. The halogenated additives are incorporated into an intumescent matrix that releases them in controlled amounts during fire events, providing protection while the overall composition is designed to meet environmental standards by minimizing harmful emissions and toxic smoke.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Solution Approach 2:

The patent uses composite material strategy by integrating halogenated fire retardants with environmentally benign components such as natural fillers, bio-based resins, and smoke-suppressing agents. This composite formulation achieves fire resistance through the halogenated components while the other components counterbalance environmental harmfulness by reducing smoke opacity and toxicity, enabling compliance with both fire safety and environmental regulations.

Inventive Principle:
Principle #40Composite materials

3Reliability

If the composition formula is optimized for excellent fire resistance and mechanical strength, then performance criteria are met, but viscosity stability and ease of application may be compromised

Engineering Contradiction:
Improvefire resistanceVSAvoidease of application
Core Design Contradiction:
ReliabilityVSEase of operation

Solution Approach 1:

The patent applies parameter changes by carefully adjusting the proportions of viscous components (resins, fillers, fire retardants) versus flow-enhancing components (solvents, reactive diluents) in the composition formula. By optimizing these parameters, the formulation achieves the required fire resistance and mechanical strength from the high-performance ingredients while maintaining viscosity within the range suitable for various application methods such as spraying, brushing, or rolling.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs local quality by creating a multi-phase composition where different components serve localized functions. The fire-retardant and high-strength components are distributed throughout the matrix in concentrations that provide performance where needed, while the continuous phase (resin + solvents) ensures overall flow and applyability. This local differentiation allows the composition to exhibit both excellent fire resistance and ease of application.

Inventive Principle:
Principle #3Local quality

4Reliability

If the composition uses multiple components to achieve intumescent behavior and fire resistance, then fire safety performance is improved, but formulation complexity increases

Engineering Contradiction:
Improvefire safetyVSAvoidformulation complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent merges multiple fire safety functions into a single integrated composition formulation. Instead of applying separate fire-retardant coatings, primers, and topcoats, the invention combines intumescent agents, halogenated fire retardants, resins, fillers, and smoke suppressants into one multi-functional composition that provides fire protection, smoke control, and adhesion in a single application step, thereby reducing overall system complexity despite the multiple components involved.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The patent achieves universality by designing a composition where each component serves multiple functions. For example, the halogenated additives provide both fire retardancy and contribute to the intumescent char formation; the resin matrix provides both structural integrity and acts as a binder for all additives; the fillers provide both mechanical reinforcement and smoke suppression. This multi-functionality reduces the need for separate specialized components, simplifying the overall formulation approach.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition achieves stable viscosity over storage, excellent fire resistance, and reduced toxicity and smoke opacity, meeting HL2 and HL3 criteria of the prCEN/TS 45545-2:2008 standard, while maintaining mechanical strength and ease of application.

Implementation Method 1

c) 20 to 110 parts by weight of at least one thermal decomposition expanding agent, selected from: melamine and melamine derivatives

Methodology Applied
Scientific EffectThermal decomposition: Thermolysis

Implementation Method 2

d) 0 to 250 parts by weight of Aluminum trihydrate

Methodology Applied
Scientific EffectThermal decomposition: Thermolysis

Implementation Method 3

e) 10 to 80 parts by weight of at least one agent carbonization precursor otherwise called 'char source' agent

Methodology Applied
Scientific EffectCarbonization: Pyrolysis

Implementation Method 4

a) per 100 parts by weight of a resin, weight expressed as weight of dry resin, comprising or consisting of: a1) at least one unsaturated polyester... or a2) at least one vinyl ester

Methodology Applied
Scientific EffectPolymerization: Chemical Bonding

Data Source

PatentEP2358797B1Heat curable composition for composite parts and intumescent coatings
Publication Date: 2016.10.05 CRAY VALLEY SA
  • EP2358797B1 patent drawing
  • EP2358797B1 patent drawing
  • EP2358797B1 patent drawing

AI summary

The invention relates to a heat curable composition for fire-resistant or intumescent composite parts, which is free of any halogen additive or halogen structure in the components thereof, and which comprises: a) 100 parts by weight of a dry resin, including a1) an unsaturated polyester having an acid index lower than 10 and/or a2) a vinyl ester; b) 40 to 200 parts by weight of a reactive thinner among ethylenically unsaturated monomers; c) 20 to 110 parts by weight of a thermal expansion agent selected from melamine and derivatives thereof, guanidine, glycine, urea, triisiocynurates, and azodicarbinamide; d) 0 to 250 parts by weight of aluminium trihydrate; e) 10 to 80 parts by weight of a carbonisation precursor agent selected from multifunctional polyols; f) 50 to 200 parts by weight of a compound selected from a phosphorus derivative and/or a boric acid derivative; g) optionally at least one metal oxide; h) optionally other additives and fillers; i) optionally reinforcements containing natural or synthetic fibres and related fabrics, wherein the acid component of the polyester al) contains at least 60 mol % of acid and/or maleic anhydride and the polyol component contains at least 70 mol % of propylene glycol. The compositions can be used in the field of transport, building, public works, civil engineering and recreation or street furniture with intumescent composite parts or coatings that comply at least with criterion HL2 of the R1 requirement of prCEN/TS 45545-2:2008.