Halogen-Based Rubber Composition for Corrosion-Resistant Semiconductor Seals

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Solution Overview

Problem

Existing rubber members used in semiconductor manufacturing are susceptible to corrosion and metal elution when exposed to corrosive substances, which compromises their durability and performance.

Innovation Solution

A rubber member composed of halogen-based rubber, such as chlorosulfonated ethylene rubber or chlorinated polyethylene rubber, optionally containing an acid acceptor like lead oxide or epoxidized polybutadiene, is formulated with specific crosslinking agents and additives to enhance corrosion resistance and reduce metal elution.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional rubber members are used in semiconductor manufacturing, then they provide basic sealing and structural functions, but they suffer from corrosion and metal elution when exposed to corrosive substances

Engineering Contradiction:
Improvecorrosion resistanceVSAvoidmetal elution
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent changes the chemical composition parameters of the rubber member by incorporating halogen-based rubber (containing chlorine, bromine, or iodine) and acid acceptors (such as lead compounds or epoxy compounds) in specific proportions. This compositional parameter change enables the rubber to resist corrosion from acidic and basic substances while minimizing metal elution, directly resolving the contradiction between reliability and harmful factors.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite rubber material by combining halogen-based rubber with acid acceptors and crosslinking agents. This composite structure synergistically enhances corrosion resistance (improving reliability) while the acid acceptor components neutralize corrosive substances, reducing metal elution (reducing harmful factors).

Inventive Principle:
Principle #40Composite materials

2Reliability

If halogen-based rubber with acid acceptors is used to improve corrosion resistance, then reliability increases, but the complexity of material formulation and processing increases

Engineering Contradiction:
Improvedurability in corrosive environmentVSAvoidmaterial composition complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent specifies precise parameter ranges for the rubber composition: halogen-based rubber (10-50 parts by mass), acid acceptor (1-35 parts by mass based on halogen-based rubber), and crosslinking agent amounts. These controlled parameter changes achieve optimal corrosion resistance while managing formulation complexity through quantified specifications.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent applies different functional components to different aspects of the rubber's performance: halogen-based rubber provides base corrosion resistance, acid acceptors specifically target acidic and basic substance neutralization, and crosslinking agents enhance structural integrity. This localized functional assignment improves overall reliability while organizing the material complexity into distinct functional zones.

Inventive Principle:
Principle #3Local quality

3Strength

If crosslinking agents are added to enhance structural integrity, then strength increases, but the risk of metal elution from crosslinking components increases

Engineering Contradiction:
Improvestructural integrityVSAvoidmetal elution from crosslinking agents
Core Design Contradiction:
StrengthVSObject-affected harmful factors

Solution Approach 1:

The patent introduces acid acceptors (lead compounds or epoxy compounds) as intermediary substances that neutralize corrosive substances before they can attack the crosslinked structure. This intermediary layer protects the crosslinking network from corrosion, maintaining structural integrity while preventing metal elution from the crosslinking agents.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent converts the potential harm of crosslinking agents (which could leach metals in corrosive environments) into a benefit by using acid acceptors to neutralize the corrosive substances. The crosslinking structure that would normally be vulnerable to corrosion becomes protected, and the metal elution issue is transformed into a controlled neutralization process.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The rubber member exhibits excellent corrosion resistance and minimal metal elution, maintaining integrity when immersed in various corrosive chemicals, ensuring durability in semiconductor manufacturing environments.

Implementation Method 1

a rubber member containing a halogen-based rubber containing at least one selected from the group consisting of chlorine, bromine, and iodine... the rubber member comes into contact with a corrosive substance

Methodology Applied
Scientific EffectChemical resistance:

Implementation Method 2

the rubber member contains at least one acid acceptor selected from the group consisting of a lead compound and an epoxy compound

Methodology Applied
Scientific EffectAcid-base reaction:

Implementation Method 3

the halogen-based rubber is crosslinked using at least one of a peroxide crosslinking agent or a sulfur-based crosslinking agent

Methodology Applied
Scientific EffectCrosslinking: Chemical Bonding

Data Source

PatentEP4685184A1Rubber member, and semiconductor manufacturing-related device
Publication Date: 2026.01.28 DAIKIN INDUSTRIES LTD
  • EP4685184A1 patent drawing
  • EP4685184A1 patent drawing

AI summary

The disclosure provides a rubber member excellent in corrosion resistance and a semiconductor manufacturing-related apparatus using the rubber member. Provided is a rubber member containing a halogen-based rubber containing at least one selected from the group consisting of chlorine, bromine, and iodine. The rubber member includes at least one selected from the group consisting of an architectural finishing material member, a mobility member, an aerospace member, a semiconductor member, and an information and communication member. The rubber member comes into contact with a corrosive substance.