Halogenated Epoxy Resin Formulation for Aircraft Interior Fire Safety

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Solution Overview

Problem

Epoxy resin-based prepregs for aircraft interior components lack sufficient fire retarding, low smoke emission, low smoke toxicity, and low heat release properties, while maintaining good mechanical and processing properties, which are essential for stringent safety standards.

Innovation Solution

A formulation comprising 10-80% halogenated epoxy resin, 1-15% antimony-based fire retardant, 1-10% inorganic or non-polymeric organic phosphorous containing fire retardant, and 1-30% curative system, which forms a prepreg with excellent FST and heat release properties when cured, along with improved mechanical and processing characteristics.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If epoxy resin based prepregs are used to improve surface finish and mechanical properties, then surface quality and mechanical strength are improved, but fire retarding properties and smoke emission characteristics deteriorate

Engineering Contradiction:
Improvemechanical propertiesVSAvoidfire retarding properties
Core Design Contradiction:
StrengthVSObject-affected harmful factors

Solution Approach 1:

The patent applies composite materials by combining epoxy resin with specific flame retardant additives (antimony oxide, phosphorous compounds, nitrogen-containing compounds) to create a multi-component resin system that simultaneously achieves good mechanical properties and fire safety performance. The synergistic interaction between these components resolves the contradiction between mechanical strength and fire retarding properties.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent modifies the chemical composition parameters of the epoxy resin system by incorporating specific ratios of halogenated epoxy resin (10-80%), antimony-based fire retardant (1-15%), phosphorous containing fire retardant (1-10%), and curative system (1-30%). These parameter changes enable the resin to achieve both improved mechanical properties and enhanced fire safety characteristics.

Inventive Principle:
Principle #35Parameter changes

2Object-affected harmful factors

If phenolic resin based formulations are used to achieve reasonable fire retarding properties, then fire safety is improved, but surface finish quality and mechanical properties deteriorate

Engineering Contradiction:
Improvefire retarding propertiesVSAvoidmechanical properties
Core Design Contradiction:
Object-affected harmful factorsVSStrength

Solution Approach 1:

The patent changes the resin base from phenolic to epoxy resin, fundamentally altering the chemical composition parameters. This parameter change enables the system to achieve superior mechanical properties and surface finish while maintaining fire safety through the addition of flame retardant additives.

Inventive Principle:
Principle #35Parameter changes

3Object-affected harmful factors

If high resin loadings and thicknesses are used to achieve excellent FST properties, then fire safety performance is improved, but processing difficulty and manufacturing complexity increase

Engineering Contradiction:
ImproveFST propertiesVSAvoidprocessing properties
Core Design Contradiction:
Object-affected harmful factorsVSEase of manufacture

Solution Approach 1:

The patent optimizes the chemical composition parameters of the resin system, specifically the ratios of epoxy resin to flame retardants and the selection of curative systems, to achieve excellent FST properties at manageable thicknesses. This enables good fire safety performance without requiring excessive resin loadings that would complicate processing.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The formulation achieves excellent fire retarding, low smoke emission, low smoke toxicity, and low heat release properties, passing industry standard tests at high resin loadings and thicknesses, while maintaining superior mechanical and processing properties, such as interlaminar shear strength and flexural modulus.

Implementation Method 1

The formulation achieves excellent fire retarding, low smoke emission, low smoke toxicity, and low heat release properties

Methodology Applied
Scientific EffectFire retarding:

Implementation Method 2

low smoke emission, low smoke toxicity and low heat release properties

Methodology Applied
Scientific EffectSmoke emission reduction:

Implementation Method 3

low heat release properties, passing industry standard tests

Methodology Applied
Scientific EffectHeat release reduction:

Implementation Method 4

a curative system, which forms a prepreg with excellent FST and heat release properties when cured

Methodology Applied
Scientific EffectChemical bonding: Chemical Bonding

Data Source

PatentUS11332607B2Epoxy resin formulations
Publication Date: 2022.05.17 HEXCEL COMPOSITES LTD (GB)
  • US11332607B2 patent drawing
  • US11332607B2 patent drawing
  • US11332607B2 patent drawing

AI summary

Formulations comprising from 10 to 80% by weight of the formulation of a halogenated epoxy resin; from 1 to 15% by weight of the formulation of an antimony based fire retardant; from 1 to 10% by weight of the formulation of an inorganic or non-polymeric organic phosphorous containing fire retardant; and from 1 to 30% by weight of the formulation of a curative system are provided. The formulations are particularly suitable for producing aircraft interior composite components having good fire retarding properties, low smoke emission, low smoke toxicity and low heat release properties. The formulations also have excellent processing and mechanical properties. Further components may be included in the compositions to improve various properties, including the fire retarding, low smoke emission, low smoke toxicity and low heat release properties and to also further improve the processing and mechanical properties, including toughness. Compositions produced from the formulations have excellent processing and mechanical properties, and may also have good surface finishes.