Haloolefin Composition Stability via Water and Phenol Additives
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Solution Overview
Problem
The existing methods for improving the stability of fluoropropenes, such as adding phenol compounds, face challenges in handling difficulty and potential reduction in performance, and there is a need for a composition that inhibits decomposition and oxidation while maintaining stability.
Innovation Solution
A haloolefin-based composition containing specific haloolefins, water, and oxygen, with controlled ppm levels of these components, which enhances the stability of the haloolefin by preventing oxidation and maintaining performance over time.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Object-affected harmful factors
If fluoropropenes are used as refrigerants or heat transfer media, then global warming potential is reduced, but stability and resistance to decomposition are compromised
Solution Approach 1:
The patent introduces an intermediary substance (phenol compound or amine compound) that mediates between the haloolefin molecules, preventing their decomposition and oxidation. This mediator absorbs the harmful effects that would otherwise cause instability, allowing the haloolefin to maintain both low GWP and high stability simultaneously.
Solution Approach 2:
The patent creates a composite refrigerant composition by combining haloolefins with small controlled amounts of phenol compounds or amine compounds. This composite approach allows the mixture to exhibit both the low global warming potential of haloolefins and the enhanced stability provided by the additive compounds.
2Reliability
If phenol compounds are added to enhance stability, then decomposition is inhibited, but handling difficulty increases and performance may be reduced
Solution Approach 1:
The patent optimizes the concentration parameter of the phenol compound or amine compound additive, specifying precise ranges (0.01-5 mass% for phenol compounds, 0.01-1 mass% for amine compounds). By carefully controlling these parameters, the patent achieves sufficient stability enhancement while minimizing handling difficulties and performance reduction.
Solution Approach 2:
The patent applies partial action by using minimal amounts of phenol or amine compounds—just enough to provide stability benefits without overwhelming the system. This partial addition strategy avoids the excessive handling difficulty and performance loss that would result from larger additive concentrations.
3Reliability
If phenol compounds are added to enhance stability, then decomposition is inhibited, but performance reduction occurs
Solution Approach 1:
The patent carefully adjusts the concentration parameter of phenol or amine compound additives to optimize the balance between stability and performance. By specifying precise concentration ranges, the patent ensures that the additive amount is sufficient to inhibit decomposition but low enough to maintain refrigerant performance characteristics.
Solution Approach 2:
The patent employs partial action by adding only the minimum necessary amount of phenol or amine compounds to achieve stability. This partial addition prevents excessive performance reduction while still providing adequate protection against decomposition and oxidation.
Applied Scientific Principles
This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.
Function Achieved in This Case
The composition achieves high stability of haloolefins, preventing oxidation and maintaining performance as a refrigerant or heat transfer medium, allowing for long-term storage and usage without significant performance loss.
Implementation Method 1
The composition contains water in an amount of 3-200 mass ppm based on the total amount of the haloolefin, and thereby the stability of the haloolefin is improved because the double bond in the molecule of the haloolefin can be stably present, and thus the haloolefin does not easily cause oxidization
Data Source
AI summary
The present invention provides a highly stable haloolefin-based composition that inhibits decomposition or oxidization. The haloolefin-based composition comprising (a) a haloolefin; (b) at least one compound selected from the group consisting of HFO-1234ze, HFC-254eb, HFO-1243zf, HFC-245eb, HFC-245fa, HFC-245cb, HFC-236ea, HFC-236fa, HFO-1225ye, 3,3,3-trifluoropropine, HFC-23, HFC-32, HFC-125, HFC-143a, HFC-134a, FC-1216, HCFO-1233xf, HCFO-1233zd, HCFO-1232xf, HCFO-1223xd, and chloromethane; and (c) water.