Haloolefin Composition Stability via Water and Phenol Additives

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Solution Overview

Problem

The existing methods for improving the stability of fluoropropenes, such as adding phenol compounds, face challenges in handling difficulty and potential reduction in performance, and there is a need for a composition that inhibits decomposition and oxidation while maintaining stability.

Innovation Solution

A haloolefin-based composition containing specific haloolefins, water, and oxygen, with controlled ppm levels of these components, which enhances the stability of the haloolefin by preventing oxidation and maintaining performance over time.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If fluoropropenes are used as refrigerants or heat transfer media, then global warming potential is reduced, but stability and resistance to decomposition are compromised

Engineering Contradiction:
Improveglobal warming potentialVSAvoidstability
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The patent introduces an intermediary substance (phenol compound or amine compound) that mediates between the haloolefin molecules, preventing their decomposition and oxidation. This mediator absorbs the harmful effects that would otherwise cause instability, allowing the haloolefin to maintain both low GWP and high stability simultaneously.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent creates a composite refrigerant composition by combining haloolefins with small controlled amounts of phenol compounds or amine compounds. This composite approach allows the mixture to exhibit both the low global warming potential of haloolefins and the enhanced stability provided by the additive compounds.

Inventive Principle:
Principle #40Composite materials

2Reliability

If phenol compounds are added to enhance stability, then decomposition is inhibited, but handling difficulty increases and performance may be reduced

Engineering Contradiction:
ImprovestabilityVSAvoidhandling difficulty
Core Design Contradiction:
ReliabilityVSEase of operation

Solution Approach 1:

The patent optimizes the concentration parameter of the phenol compound or amine compound additive, specifying precise ranges (0.01-5 mass% for phenol compounds, 0.01-1 mass% for amine compounds). By carefully controlling these parameters, the patent achieves sufficient stability enhancement while minimizing handling difficulties and performance reduction.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent applies partial action by using minimal amounts of phenol or amine compounds—just enough to provide stability benefits without overwhelming the system. This partial addition strategy avoids the excessive handling difficulty and performance loss that would result from larger additive concentrations.

Inventive Principle:
Principle #16Partial or excessive action

3Reliability

If phenol compounds are added to enhance stability, then decomposition is inhibited, but performance reduction occurs

Engineering Contradiction:
ImprovestabilityVSAvoidperformance
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The patent carefully adjusts the concentration parameter of phenol or amine compound additives to optimize the balance between stability and performance. By specifying precise concentration ranges, the patent ensures that the additive amount is sufficient to inhibit decomposition but low enough to maintain refrigerant performance characteristics.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs partial action by adding only the minimum necessary amount of phenol or amine compounds to achieve stability. This partial addition prevents excessive performance reduction while still providing adequate protection against decomposition and oxidation.

Inventive Principle:
Principle #16Partial or excessive action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition achieves high stability of haloolefins, preventing oxidation and maintaining performance as a refrigerant or heat transfer medium, allowing for long-term storage and usage without significant performance loss.

Implementation Method 1

The composition contains water in an amount of 3-200 mass ppm based on the total amount of the haloolefin, and thereby the stability of the haloolefin is improved because the double bond in the molecule of the haloolefin can be stably present, and thus the haloolefin does not easily cause oxidization

Methodology Applied
Scientific EffectOxidation prevention: Oxidation

Data Source

PatentEP3130649B1Haloolefin-based composition
Publication Date: 2024.11.27 DAIKIN INDUSTRIES LTD

AI summary

The present invention provides a highly stable haloolefin-based composition that inhibits decomposition or oxidization. The haloolefin-based composition comprising (a) a haloolefin; (b) at least one compound selected from the group consisting of HFO-1234ze, HFC-254eb, HFO-1243zf, HFC-245eb, HFC-245fa, HFC-245cb, HFC-236ea, HFC-236fa, HFO-1225ye, 3,3,3-trifluoropropine, HFC-23, HFC-32, HFC-125, HFC-143a, HFC-134a, FC-1216, HCFO-1233xf, HCFO-1233zd, HCFO-1232xf, HCFO-1223xd, and chloromethane; and (c) water.