Electrochemical Hard-Metal Machining With Binder-Tuned Pulsed Current

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Solution Overview

Problem

Current electrochemical machining methods for hard metal materials with a hard phase and binder phase face challenges in achieving uniform material removal over time, as the hard phase and binder phase are often removed at different rates, leading to uneven surface finishes and the need for subsequent mechanical polishing.

Innovation Solution

The method involves using an aqueous, alkaline electrolyte with a complexing agent and a pulsed electrical current, where the pulse sequence is adjusted based on the binder phase content, preventing the formation of an electron-conducting passive layer and ensuring balanced removal of both phases, thereby allowing for homogeneous material removal without the need for electrode exchange or thermal energy input.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If mechanical machining with diamond-coated tools is used, then material removal is achieved, but high energy input causes thermal damage and material impairment

Engineering Contradiction:
Improvematerial removal capabilityVSAvoidthermal damage to material
Core Design Contradiction:
ProductivityVSObject-affected harmful factors

Solution Approach 1:

The patent replaces mechanical machining with electrochemical machining. Instead of using mechanical cutting tools that generate heat through friction, the invention uses electrochemical reactions to remove material. The electrolyte chemically dissolves the material at the anode, eliminating the need for mechanical contact and the associated thermal damage, while still achieving effective material removal.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Productivity

If thermal machining processes are used, then material removal is achieved, but melting and solidification create microcracks and monophase structures

Engineering Contradiction:
Improvematerial removal capabilityVSAvoidsurface quality and material structure
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The invention substitutes thermal machining processes with electrochemical machining. Instead of melting and vaporizing material through high energy beams or sparks, the electrolyte chemically dissolves material through electrochemical reactions. This eliminates the melting-s Solidification cycle that creates microcracks and monophase structures, preserving the original material structure and surface quality.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent changes the fundamental mechanism of material removal from thermal to chemical/electrochemical. By controlling electrochemical parameters such as current density, electrolyte composition, and pulse duration, the process achieves precise material removal without the thermal effects that cause surface degradation and structural damage.

Inventive Principle:
Principle #35Parameter changes

3Productivity

If halogen-containing electrolyte is used, then material removal occurs through oxidizing effect, but binder phase dissolves preferentially causing rough surface

Engineering Contradiction:
Improvematerial removal rateVSAvoidsurface uniformity
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The patent changes the electrolyte composition from halogen-containing to halogen-free, using alternative chemical systems that provide controlled dissolution of both hard phase and binder phase. This modification to the electrolyte parameters achieves uniform material removal without the preferential dissolution of binder phase that occurs with halogen-based electrolytes, resulting in smoother, more uniform surfaces.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables uniform and prolonged removal of both hard and binder phases, reducing thermal energy input and preventing surface melting or cracking, allowing for both coarse and fine machining in a single process step with improved surface quality and reduced operational risks.

Implementation Method 1

supply of a pulsed electrical current to the material via the current source for electrochemical oxidation of the material

Methodology Applied
Scientific EffectElectrochemical oxidation: Oxidation

Implementation Method 2

aqueous, alkaline complexing agent-containing electrolyte and at least partial contacting of the material to be machined with the electrolyte and with a current source

Methodology Applied
Scientific EffectElectrolysis: Electrolysis

Implementation Method 3

the electrolyte comprises a complexing agent which is suitable for complexing at least one metal ion of the binder phase

Methodology Applied
Scientific EffectComplexing: Solvation

Implementation Method 4

simultaneous anodic dissolving process for hard- and binder phase

Methodology Applied
Scientific EffectElectrochemical dissolution: Oxidation

Data Source

PatentUS11554432B2Device and method for electrochemically processing a material
Publication Date: 2023.01.17 FRAUNHOFER GESELLSCHAFT ZUR FORDERUNG DER ANGEWANDTEN FORSCHUNG EV
  • US11554432B2 patent drawing
  • US11554432B2 patent drawing

AI summary

The invention relates to a method and a device for electrochemically processing a material, which contains a hard phase and a binder phase. The method comprises preparing an aqueous, alkaline, complexing-agent-containing electrolyte and bringing the material to be processed into contact at least in part with the electrolyte and with a current source. In order to electrochemically oxidize the material, a pulsed electrical current is delivered to the material by means of the current source, the pulse sequence of the delivered electrical current being adjusted to the amount of the binder phase in the material to be processed. By means of the method and by means of the device, it is also possible to process materials having a high content of binder phase in such a way that matter can be removed from the material evenly (homogeneously), i.e. both from the hard phase and from the binder phase of the material.