Hard Shell Microencapsulated Latent Heat Transport Materials

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Solution Overview

Problem

Conventional microencapsulated latent heat materials face challenges with mechanical strength and heat resistance, making it difficult to recover and transport high-temperature waste heat effectively.

Innovation Solution

Development of hard shell microencapsulated latent heat transport materials using non-porous hollow silica particles coated with silica, which encapsulate phase change materials capable of phase transitions up to 600 °C, enhancing mechanical strength and heat resistance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Temperature

If conventional microencapsulated latent heat materials are used, then heat transportation is enabled, but mechanical strength and heat resistance are insufficient for high-temperature applications

Engineering Contradiction:
Improveheat resistanceVSAvoidmechanical strength
Core Design Contradiction:
TemperatureVSReliability

Solution Approach 1:

The patent employs a composite shell structure combining silica (inorganic) and polymer (organic) materials. The silica component provides high-temperature stability and mechanical strength, while the polymer component ensures encapsulation integrity. This composite approach resolves the contradiction by integrating materials with complementary properties to achieve both heat resistance and mechanical strength simultaneously.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent modifies the shell composition parameters by incorporating silica particles into the polymer matrix, changing the material parameters to enhance thermal stability. By adjusting the silica content and distribution, the shell can withstand high temperatures while maintaining structural integrity, thus resolving the contradiction between heat resistance and mechanical strength.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If polymer shells are used for microencapsulation, then latent heat material containment is achieved, but mechanical strength and heat resistance deteriorate at high temperatures

Engineering Contradiction:
Improvecontainment integrityVSAvoidheat resistance
Core Design Contradiction:
ReliabilityVSTemperature

Solution Approach 1:

The patent creates a hybrid shell system where silica particles are embedded in a polymer matrix. The silica provides thermal stability and structural support at high temperatures, while the polymer ensures proper encapsulation of the latent heat material. This composite structure maintains containment integrity even when exposed to elevated temperatures that would degrade pure polymer shells.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent applies different material properties to different regions of the shell. The silica-rich regions provide heat resistance and structural strength, while the polymer-rich regions ensure encapsulation functionality. This local differentiation of material quality allows the shell to simultaneously achieve containment integrity and heat resistance.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The hard shell microencapsulated latent heat transport materials can efficiently recover and transport high-temperature waste heat, offering improved mechanical strength and heat resistance, enabling applications in various temperature ranges and environments.

Implementation Method 1

a latent heat material that changes its phase from solid to liquid by melting at a desired temperature

Methodology Applied
Scientific EffectLatent heat: Latent Heat

Implementation Method 2

the phase change material inside the non-porous hollow silica particle does not include a super cooling prevention agent and has a super cooling degree smaller than that of the phase change material

Methodology Applied
Scientific EffectPhase change: Phase Change

Implementation Method 3

hard shell microencapsulated latent heat transport materials using non-porous hollow silica particles coated with silica, which encapsulate phase change materials capable of phase transitions up to 600 °C, enhancing mechanical strength and heat resistance

Methodology Applied
Scientific EffectThermal resistance: Thermal Insulation

Implementation Method 4

non-porous hollow silica particles encapsulating a phase change material

Methodology Applied
Scientific EffectPhysical containment: Physical Containment

Data Source

PatentEP3037496B1Latent heat transfer material micro-encapsulated in hard shell, and production method for same
Publication Date: 2020.05.06 KOBE UNIV
  • EP3037496B1 patent drawingFigure 1
  • EP3037496B1 patent drawingFigure 2(a)~2(f)
  • EP3037496B1 patent drawingFigure 3~4

AI summary

Provided is a latent heat transfer material that is micro-encapsulated, said material exhibiting superior mechanical strength and heat resistance. A production method for the latent heat transfer material that is micro-encapsulated in a hard shell comprises: 1) a step in which a perforate hollow silica particle is manufactured; 2) a step in which the phase change material is sealed inside the perforate hollow silica particle by inserting the perforate hollow silica particle in a molten solution of the phase change material and repeatedly subj ecting the same to vibrations such as ultrasound oscillations; 3) a step in which the perforate hollow silica particle having the phase change material sealed within is washed in a saturated aqueous solution of the phase change material; and 4) a step in which perhydropolysilazane is used to coat the outer shell of the perforate hollow silica particle with silica.