Hard Surface Cleaning Composition for Stable Oily Soil Emulsification

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Solution Overview

Problem

There is a need for a hard surface cleaning composition with a good environmental profile that provides effective emulsification and oily soil removal without compromising consumer satisfaction and/or product appeal, and existing technologies fail to address the challenges of temperature stability and product appeal, including the challenges of temperature stability and product appeal.

Innovation Solution

A liquid detergent composition comprising a surfactant system comprising a specific combination of anionic surfactants, polyethylene oxide, and betaine, with a surfactant system free of alkylbenzene sulphonates, and a weight ratio of surfactants optimized for temperature stability and cleaning efficacy.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If polyethylene oxide and betaine are used in liquid detergent formulations, then emulsification and oily soil removal properties are improved, but temperature stability deteriorates

Engineering Contradiction:
Improvetemperature stabilityVSAvoidemulsification and oily soil removal properties
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent modifies the chemical composition parameters by introducing a specific anionic surfactant system (surfactants A and B with defined formulas and ratios) to replace or supplement polyethylene oxide and betaine. This parameter change maintains emulsification and oily soil removal properties while achieving temperature stability across different storage conditions.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite surfactant system combining multiple surfactant types (anionic surfactants A and B with specific chemical structures) that work synergistically. This composite approach provides both the desired cleaning performance (emulsification and oily soil removal) and temperature stability that individual components could not achieve alone.

Inventive Principle:
Principle #40Composite materials

2Reliability

If alkylbenzene sulphonates are used, then cleaning efficacy is improved, but environmental profile deteriorates

Engineering Contradiction:
Improvecleaning efficacyVSAvoidenvironmental impact
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent extracts and removes alkylbenzene sulphonates from the formulation entirely, replacing them with environmentally friendlier anionic surfactants (surfactants A and B) that maintain cleaning efficacy while reducing environmental harm. This extraction eliminates the harmful component while preserving the functional performance.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent changes the chemical identity parameter of the surfactant system by substituting alkylbenzene sulphonates with alternative anionic surfactants having different molecular structures (formulas I and II). This parameter change maintains cleaning efficacy through equivalent or superior surfactant activity while improving the environmental profile by selecting biodegradable or less toxic alternatives.

Inventive Principle:
Principle #35Parameter changes

3Object-affected harmful factors

If total amount of surfactant is lowered, then environmental profile is improved, but cleaning efficacy deteriorates

Engineering Contradiction:
Improveenvironmental profileVSAvoidcleaning efficacy
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The patent optimizes the concentration parameter of surfactants in the formulation, finding the minimum effective amount that delivers adequate cleaning performance while minimizing environmental impact. The specific anionic surfactant system (A and B) achieves higher cleaning efficiency per unit mass, allowing lower total surfactant levels without sacrificing cleaning efficacy.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses a composite surfactant system where multiple surfactant components (A and B) work synergistically to enhance cleaning efficacy at lower concentrations. This composite approach maximizes the cleaning performance per unit of surfactant, enabling reduced total surfactant content while maintaining or improving cleaning effectiveness.

Inventive Principle:
Principle #40Composite materials

4Ease of manufacture

If clear and transparent product formulation is used, then product appeal is improved, but temperature stability deteriorates

Engineering Contradiction:
Improveproduct appearanceVSAvoidtemperature stability
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent adjusts the chemical composition parameters by incorporating a specific anionic surfactant system that is compatible with clear and transparent formulations. This parameter change allows the product to maintain aesthetic appeal (clear and transparent appearance) while achieving temperature stability through the improved surfactant chemistry that prevents clouding and sedimentation across temperature variations.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition maintains temperature stability and cleaning performance, providing effective emulsification and oily soil removal while maintaining consumer satisfaction and a clear, transparent appearance.

Implementation Method 1

a specific combination of anionic surfactants provides temperature stability

Methodology Applied
Scientific EffectSurfactant: Surfactant

Implementation Method 2

providing effective emulsification and oily soil removal

Methodology Applied
Scientific EffectEmulsification: Emulsion

Implementation Method 3

effective emulsification and oily soil removal

Methodology Applied
Scientific EffectAdsorption: Adsorption

Data Source

PatentEP4536791B1A hard surface cleaning composition
Publication Date: 2025.12.24 UNILEVER IP HLDG BV
  • EP4536791B1 patent drawing

AI summary

The present invention relates to liquid aqueous detergent compositions comprising a surfactant system comprising a primary surfactant being anionic surfactant, a secondary surfactant being amphoteric surfactant, polyethylene oxide and one or more enzymes whilst the surfactant system is free of alkylbenzene sulphonates and derivatives thereof. The invention further relates to a method of cleaning a stainless- steel hard surface using the composition of the invention, as well as the use thereof.