Harmonic RF Control for Ion Energy Distribution in Plasma Etching

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Solution Overview

Problem

Current plasma processing technologies face challenges in controlling ion energy distribution in plasma systems, particularly for substrates with shrinking geometries, due to limitations in directly measuring and manually adjusting plasma properties, which affects process performance and controllability.

Innovation Solution

The method involves using multiple harmonic frequency components for plasma excitation, controlling relative amplitude and phase shifts between frequency components to achieve desired ion energy distributions, monitored through electrical characteristics like impedance and RF signals within the plasma processing apparatus, allowing for dynamic control of ion energy without direct measurement.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If multiple harmonic frequency components are used for plasma excitation, then ion energy distribution control is improved, but device complexity increases

Engineering Contradiction:
Improveion energy distribution controlVSAvoiddevice complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The plasma excitation is segmented into multiple harmonic frequency components (fundamental frequency and harmonic frequencies). Each frequency component is independently controlled through separate RF sources or frequency multiplication circuits, allowing precise control over ion energy distribution by adjusting the relative amplitudes and phases of each component.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The system changes the frequency parameters of plasma excitation by introducing harmonic frequencies (2f, 3f, etc.) in addition to the fundamental frequency. By varying the amplitude ratios and phase differences between these frequency components, the ion energy distribution can be dynamically adjusted to achieve desired process outcomes.

Inventive Principle:
Principle #35Parameter changes

2Measurement precision

If direct ion energy measurement is implemented, then measurement precision is improved, but device complexity and cost increase

Engineering Contradiction:
Improveion energy measurementVSAvoiddevice complexity
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

Instead of directly measuring ion energy, the system uses electrical characteristics (impedance, voltage, current) as intermediary parameters that correlate with ion energy distribution. These electrical measurements are easier to obtain and do not require complex ion energy sensors, while still providing sufficient control feedback.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent replaces direct physical measurement of ion energy with electrical measurement methods. By monitoring electrical characteristics of the plasma load, the system infers ion energy distribution without requiring mechanical or complex sensing equipment that would directly interact with the plasma.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Ease of operation

If manual adjustment of plasma variables is used, then ease of operation is maintained, but productivity and dynamic control capability deteriorate

Engineering Contradiction:
Improveease of operationVSAvoidproductivity
Core Design Contradiction:
Ease of operationVSProductivity

Solution Approach 1:

The system implements feedback control by continuously monitoring electrical characteristics of the plasma and automatically adjusting the amplitude and phase of harmonic frequency components. This closed-loop control enables dynamic adaptation to process conditions, improving productivity while maintaining ease of operation through automated control.

Inventive Principle:
Principle #23Feedback

Solution Approach 2:

The system transitions from static manual adjustment to dynamic automated control. The control circuitry continuously adjusts plasma parameters in real-time based on process requirements and feedback signals, enabling rapid response to changing conditions and improving overall process efficiency and productivity.

Inventive Principle:
Principle #15Dynamics

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables in-situ ion energy optimization and maintains optimal operating conditions during plasma processing, enhancing control over ion energy distribution and process characteristics, such as selective etching and layer modification, without the need for an ion energy sensor.

Implementation Method 1

one or more RF sources coupled to the process chamber and configured to provide RF power to the process chamber through at least a base frequency voltage at a base frequency and a second frequency voltage at a second frequency

Methodology Applied
Scientific EffectRadio frequency plasma excitation: Plasma

Implementation Method 2

monitoring one or more electrical characteristics within the plasma apparatus, such as for example, impedance levels, electrical signals in the radio frequency (RF) generator

Methodology Applied
Scientific EffectElectrical impedance measurement: Electrical Impedance Tomography

Data Source

PatentUS10998170B2Method for ion mass separation and ion energy control in process plasmas
Publication Date: 2021.05.04 MKS INSTR INC
  • US10998170B2 patent drawing
  • US10998170B2 patent drawing
  • US10998170B2 patent drawing

AI summary

Plasma ion energy distribution for ions having different masses is controlled by controlling the relationship between a base RF frequency and a harmonic RF frequency. By the controlling the RF power frequencies, characteristics of the plasma process may be changed based on ion mass. The ions that dominate etching may be selectively based upon whether an ion is lighter or heavier than other ions. Similarly, atomic layer etch processes may be controlled such that the process may be switched between a layer modification step and a layer etch step though adjustment of the RF frequencies. Such switching is capable of being performed within the same gas phase of the plasma process. The control of the RF power includes controlling the phase difference and/or amplitude ratios between a base RF frequency and a harmonic frequency based upon the detection of one or more electrical characteristics within the plasma apparatus.