Nano-Structured hBN Relief Patterning for Arbitrary Nanoshapes

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Solution Overview

Problem

Existing methods for producing hexagonal boron nitride (hBN) elements are limited by standard patterning techniques that constrain design choices, making it difficult to achieve arbitrarily shaped structures with nanometer-scale features for controlling photons, electrons, and excitons.

Innovation Solution

A method involving the creation of a relief structure in a resist, followed by transferring it into the hBN element through etching, allows for the arbitrary shaping of hBN elements with freely varying profiles and nanometer-scale features, enabling more sophisticated structures for controlling photons, electrons, and excitons.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Adaptability or versatility

If standard patterning techniques such as electron-beam lithography and focused ion-beam milling are used, then hBN elements can be produced, but the design choices are severely constrained

Engineering Contradiction:
Improvedesign choice freedomVSAvoidmanufacturing complexity
Core Design Contradiction:
Adaptability or versatilityVSEase of manufacture

Solution Approach 1:

A polymer resist is introduced as an intermediary material between the hBN flake and the final structure. The resist is first patterned using standard lithography techniques, then transferred to the hBN flake through controlled oxidation, enabling complex designs without directly patterning the hBN

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The polymer resist is pre-patterned with the desired relief structure before transfer to the hBN flake. This preliminary patterning step allows complex designs to be created using well-established lithography methods, which are then replicated onto the hBN surface

Inventive Principle:
Principle #10Preliminary action

2Manufacturing precision

If standard patterning techniques are used, then hBN elements can be produced, but arbitrarily shaped structures with nanometer-scale features are difficult to achieve

Engineering Contradiction:
Improvefeature dimension precisionVSAvoidshape flexibility
Core Design Contradiction:
Manufacturing precisionVSAdaptability or versatility

Solution Approach 1:

The oxidation time is used as a controllable parameter to precisely adjust the transfer depth of the relief structure into the hBN flake. By varying oxidation time, different feature depths and profiles can be achieved, enabling nanometer-scale precision while maintaining shape flexibility

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The relief structure in the polymer resist creates locally varied oxidation rates when exposed to oxygen plasma. Areas with different relief depths experience different oxidation, resulting in precisely controlled material removal and formation of complex nanometer-scale features in the hBN flake

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables the production of nano-structured hBN elements with precise and varied shapes, facilitating advanced applications in hyperbolic metamaterials, polaritonics, twistronics, quantum materials, and two-dimensional optoelectronic devices.

Implementation Method 1

The relief structure is transferred into the hBN-flake by means of oxidation, in particular by means of oxidation with oxygen plasma

Methodology Applied
Scientific EffectOxidation: Oxidation

Data Source

PatentUS12566372B2Method for producing a nano-structured element made of hexagonal boron nitride and device comprising such an element
Publication Date: 2026.03.03 ETH ZURICH
  • US12566372B2 patent drawing
  • US12566372B2 patent drawing
  • US12566372B2 patent drawing

AI summary

A method is indicated for producing a nano-structured element (1) made of hexagonal boron nitride (hBN). The method comprises the steps of a.) generating a relief structure (4) in the surface (31) of a resist (3), the resist in particular being a polymer resist (3); of b.) placing the resist (3) on the hBN-element (1); and of c.) transferring the relief structure (4) from the resist (3) into the hBN-element (1) by means of etching. Furthermore, a device is indicated comprising one or several nano-structured hBN-elements (1), the one or several hBN-elements (1) having a relief structure (4) provided for the targeted influencing of the electronic, optical and/or mechanical properties of the device.