hBNC Graphene Transistor Channel for Stable Band Gap and Mobility

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Solution Overview

Problem

The implementation of 2D transistors on physical wafers faces challenges such as unstable band gap of channel material, leakage, molecular absorption, and carrier mobility degradation.

Innovation Solution

A method involving the formation and transfer of a hexagonal boron nitride carbon (hBNC) layer, comprising hBN flakes and a graphene layer, onto a wafer, utilizing a copper film with a single-crystalline structure as a substrate, to stabilize the band gap and enhance carrier mobility.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional 2D channel materials are used in transistors, then the device structure can be implemented, but the band gap becomes unstable and carrier mobility degrades

Engineering Contradiction:
Improveband gap stabilityVSAvoidmaterial stability in fabrication
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent uses a composite channel structure consisting of hexagonal boron nitride (hBN) and carbon (graphene) layers, forming hBNC material. This composite structure combines the wide band gap properties of hBN with the high carrier mobility of graphene, achieving both stable band gap and high carrier mobility that conventional single-material 2D channels cannot provide

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent changes the material composition parameters by introducing controlled amounts of carbon into the hBN lattice to form hBNC. By adjusting the carbon concentration and distribution, the band gap and carrier mobility parameters are optimized simultaneously, resolving the contradiction between band gap stability and carrier mobility

Inventive Principle:
Principle #35Parameter changes

2Length of moving object

If 2D channel materials are used, then atomic-scale thin channel can be achieved, but leakage and molecular absorption problems occur

Engineering Contradiction:
Improvechannel thicknessVSAvoidleakage and molecular absorption
Core Design Contradiction:
Length of moving objectVSObject-affected harmful factors

Solution Approach 1:

The hBNC composite channel layer combines hBN's excellent insulating properties and chemical stability with graphene's atomic thickness. The hBN component provides barrier against leakage and molecular absorption, while the graphene component maintains atomic-scale thinness for high carrier mobility, solving the contradiction between thin channel dimension and harmful effects

Inventive Principle:
Principle #40Composite materials

3Ease of manufacture

If polycrystalline copper film is used as substrate, then deposition process is simpler, but the resulting hBNC layer has misaligned orientations and degraded performance

Engineering Contradiction:
Improvesubstrate deposition simplicityVSAvoidhBNC layer orientation alignment
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The patent performs preliminary thermal annealing treatment on the copper film substrate before depositing hBN and carbon layers. This preliminary action transforms the copper substrate into a single-crystalline structure with well-defined orientation, which then templates the hBNC layer to grow with aligned orientations, ensuring high manufacturing precision while maintaining process simplicity

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The hBNC layer achieves a stable band gap and high carrier mobility, resulting in excellent device performance for transistors, overcoming previous issues of instability and mobility degradation.

Implementation Method 1

utilizing a copper film with a single-crystalline structure as a substrate, to stabilize the band gap

Methodology Applied
Scientific EffectLattice matching:

Implementation Method 2

The hBNC layer achieves a stable band gap and high carrier mobility, resulting in excellent device performance for transistors

Methodology Applied
Scientific EffectCarrier mobility enhancement:

Data Source

PatentUS20240387642A1Transistor, manufacturing method of semiconductor device, and manufacturing method of hbnc layer
Publication Date: 2024.11.21 TAIWAN SEMICONDUCTOR MANUFACTURING CO LTD
  • US20240387642A1 patent drawing
  • US20240387642A1 patent drawing
  • US20240387642A1 patent drawing

AI summary

A transistor includes a channel layer, a gate stack, and source/drain regions. The channel layer includes a graphene layer and hexagonal boron nitride (hBN) flakes dispersed in the graphene layer. Orientations of the hBN flakes are substantially aligned. The gate stack is over the channel layer. The source/drain regions are aside the gate stack.