Semiconductor Etching Sequence Using HCl and Cl2 for Speed and Selectivity

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Solution Overview

Problem

Existing semiconductor device fabrication processes face challenges with slow etching at low temperatures, leading to reduced throughput and limited selectivity, which can hinder device performance and increase processing times.

Innovation Solution

A method involving initial etching with hydrogen chloride and fast etching with chlorine gas, utilizing varying pressures, temperatures, and flow rates to enhance processing speed and selectivity, including cyclic deposition and etch operations to form doped semiconductor layers.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If low temperature processing is used, then device performance is improved, but etching speed decreases and throughput is reduced

Engineering Contradiction:
Improvedevice performanceVSAvoidthroughput
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The etching process is divided into two distinct stages: initial etching using HCl at low temperature for selectivity, and fast etching using Cl2 at higher temperature for speed. This segmentation allows each stage to optimize for its specific function, resolving the contradiction between device performance and throughput.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The process dynamically transitions between different etching conditions - starting with low-temperature HCl etching and then switching to high-temperature Cl2 etching. This dynamic adjustment of processing parameters enables the system to achieve both selectivity and speed throughout the etching sequence.

Inventive Principle:
Principle #15Dynamics

2Reliability

If low temperature processing is used, then device performance is improved, but etching selectivity is limited

Engineering Contradiction:
Improvedevice performanceVSAvoidetching selectivity
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The etching process is segmented into two stages with different chemistries: HCl for initial etching providing high selectivity, and Cl2 for fast etching. This segmentation ensures that selectivity requirements are met in the initial stage while maintaining overall process control.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The process changes chemical parameters by switching from HCl to Cl2 gas, and changes temperature parameters from low to high. These parameter changes enable the system to achieve both high selectivity and fast etching rates at different stages.

Inventive Principle:
Principle #35Parameter changes

3Manufacturing precision

If cyclic processing is used, then layer formation is achieved, but processing time increases to 1 hour or higher

Engineering Contradiction:
Improvelayer formationVSAvoidprocessing time
Core Design Contradiction:
Manufacturing precisionVSLoss of time

Solution Approach 1:

The cyclic processing is made dynamic by varying the etching conditions between cycles - using fast Cl2 etching for most cycles and switching to selective HCl etching only when needed. This dynamic approach maintains layer formation quality while dramatically reducing total processing time.

Inventive Principle:
Principle #15Dynamics

Solution Approach 2:

The process uses parameter changes by alternating between different gas compositions (HCl vs Cl2) and temperature settings during cyclic processing. This allows the system to achieve both precise layer formation and reduced processing time by optimizing parameters for each cycle's specific requirements.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method enables fast and selective etching of semiconductor layers, reducing processing time and improving device performance by forming doped semiconductor epitaxial layers efficiently.

Implementation Method 1

etching a layer of a substrate using a first pressure and a first composition including hydrogen chloride

Methodology Applied
Scientific EffectChemical etching: Chemical Bonding

Implementation Method 2

etching the layer using a second pressure and a second composition including chlorine (Cl2) gas

Methodology Applied
Scientific EffectChemical etching: Chemical Bonding

Implementation Method 3

depositing a layer on a substrate using a first temperature and a first pressure

Methodology Applied
Scientific EffectChemical vapor deposition: Chemical Vapour Deposition

Data Source

PatentUS20260060016A1Substrate processing including initial etching and fast etching, and related methods, apparatus, systems, and chambers
Publication Date: 2026.02.26 APPLIED MATERIALS INC
  • US20260060016A1 patent drawing
  • US20260060016A1 patent drawing
  • US20260060016A1 patent drawing

AI summary

Embodiments described herein generally relate to semiconductor device fabrication, and more particularly, to systems and methods that include initial etching and fast etching. In one or more embodiments, a method of substrate processing includes etching a layer of a substrate using a first pressure and a first composition including hydrogen chloride. The etching includes flowing the first composition for a first time period and at a first flow rate. The method includes etching the layer using a second pressure and a second composition including chlorine (Cl2) gas, and the etching includes flowing the second composition for a second time period less than the first time period and at a second flow rate less than the first flow rate. The second time period is a time ratio of the first time period, and the time ratio is 1:15 or less.