Parallel HCL Dosing Trains for Continuous Isomerization

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Solution Overview

Problem

Current methods for introducing hydrogen chloride in moisture-sensitive process systems, such as refinery isomerization units, face challenges including labor-intensive manual operations, temperature extremes leading to gas release and component failure, and extended process cycles due to pressure loss, which are hazardous and costly.

Innovation Solution

A system with multiple HCL trains and an electronic monitoring and control system that manages HCL supply, allowing for continuous operation by switching between active and inactive trains, evacuating, and purging modes to maintain consistent pressure and flow, using heating devices to manage temperature and prevent pressure drops.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If hydrogen chloride is fed into the system in repeated cycles with high flow injection, then full reaction with ferric oxide is achieved, but temperature extremes and cooling cycles result in gas release, leaks, and catastrophic failure of cylinders or supply system components

Engineering Contradiction:
Improvereaction effectivenessVSAvoidtemperature extremes and gas release
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The system is divided into multiple independent HCL supply trains (at least two parallel trains), allowing one train to be actively dosing while another undergoes evacuation or purging operations. This segmentation enables continuous operation without temperature cycling of the same supply system.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Evacuation and purging operations are performed in advance on standby trains before they are needed for dosing. This preliminary action removes moisture and prepares the system for the next dosing cycle without interrupting current operations, preventing temperature extremes during critical phases.

Inventive Principle:
Principle #10Preliminary action

2Reliability

If hydrogen chloride is fed into the system in repeated cycles with high flow injection, then full reaction with ferric oxide is achieved, but labor intensive manual operations and extended process cycles result in added labor, material and project costs

Engineering Contradiction:
Improvereaction effectivenessVSAvoidprocess cycle time
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

While one HCL train is actively dosing the system, another train simultaneously undergoes evacuation and purging. This parallel operation ensures continuous useful action without idle time, eliminating extended process cycles and associated costs.

Inventive Principle:
Principle #20Continuity of useful action

Solution Approach 2:

The use of multiple parallel trains with coordinated operation accelerates the overall process by eliminating sequential waiting time, effectively speeding up the acidification curing process without compromising reaction effectiveness.

Inventive Principle:
Principle #38Strong oxidants (Accelerated oxidation)

3Reliability

If hydrogen chloride is fed into the system in repeated cycles with high flow injection, then full reaction with ferric oxide is achieved, but manual operations and cylinder exchanges create hazardous situations with gas release

Engineering Contradiction:
Improvereaction effectivenessVSAvoidsafety and operational simplicity
Core Design Contradiction:
ReliabilityVSEase of operation

Solution Approach 1:

The system is equipped with electronic monitoring and control that automatically manages the complex multi-train operations, evacuation, purging, and coordination. This automation makes the system self-sufficient and reduces manual intervention, thereby eliminating safety hazards associated with manual cylinder exchanges while maintaining effective HCL dosing.

Inventive Principle:
Principle #25Self-service

4Productivity

If heating devices are applied to maintain elevated temperature of gas containers, then hydrogen chloride flow and pressure are maintained, but excessive heat results in catastrophic failure of vessels or gas handling and control components

Engineering Contradiction:
ImproveHCL flow rateVSAvoidsystem integrity
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

Multiple independent HCL trains allow the system to distribute heating requirements across separate units. Each train can be heated independently at moderate temperatures, avoiding the need to excessively heat a single large container, thereby maintaining productivity while preserving system integrity.

Inventive Principle:
Principle #1Segmentation

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach reduces labor and material costs, minimizes hazardous situations by maintaining consistent hydrogen chloride flow and pressure, and prevents catastrophic failures by automating temperature management and ensuring continuous operation.

Implementation Method 1

application of direct or indirect heat to the gas container

Methodology Applied
Scientific EffectHeating: Heating

Implementation Method 2

Removal of gas from cylinders or small bulk tanks at high flow rates results in quickly cooling of the container and lowering of the gas head pressure

Methodology Applied
Scientific EffectJoule-Thomson effect: Joule-Thomson Effect

Data Source

PatentUS11155758B2Method of dosing a system with HCL then evacuating and purging
Publication Date: 2021.10.26 AIRGAS INC
  • US11155758B2 patent drawing
  • US11155758B2 patent drawing
  • US11155758B2 patent drawing

AI summary

A method of dosing a system with HCL is provided. The method includes at least two parallel trains. The method utilizes a first operating mode, wherein at least one primary train is actively providing HCL to an end user, and at least one secondary train is either inactive or also providing HCL to the end user. The method utilizes a second operating mode, wherein the least one primary train is evacuating the contents of the train to a disposal system, and the at least one secondary train is providing HCL to the end user. And the system utilizes a third operating mode, wherein the at least one primary train is purging the train, and the at least one secondary train is providing HCL to the end user. The first operating mode, the second operating mode, and the third operating mode are controlled by an electronic monitoring and control system.