H&E Stain Removal for Multi-Target Tissue Analysis

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Solution Overview

Problem

Current methods for cancer diagnosis face challenges in analyzing multiple biological targets from limited sample sizes, particularly when using hematoxylin and eosin (H&E) stained slides, as the H&E stains interfere with subsequent immunohistochemistry (IHC) and fluorescence in situ hybridization (FISH) analyses, limiting the ability to perform detailed molecular assessments.

Innovation Solution

A method is developed to remove the fluorescent H&E signal from stained biological samples using a series of washes, charge transfer agents, hydrogen peroxide with metal salts, and photo-induced chemical bleaching (PICB) agents, allowing for the detection of multiple targets on the same tissue section without residual interference.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If H&E staining is performed on biological samples for morphological assessment, then diagnostic accuracy for cancer detection is improved, but the H&E stains interfere with subsequent IHC and FISH analyses

Engineering Contradiction:
Improvediagnostic accuracyVSAvoidstain interference
Core Design Contradiction:
Measurement precisionVSObject-generated harmful factors

Solution Approach 1:

The patent removes H&E stains from tissue sections through a multi-step process involving differentiation in acid alcohol, washing in water, and treatment with oxidizing agents like hydrogen peroxide. This extraction of the harmful stain component allows the same tissue section to be used for subsequent IHC and FISH analyses without interference from the original H&E staining.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent discards the H&E stain by removing it through differentiation and washing steps, then recovers the tissue section for additional molecular analyses. This enables the same valuable tissue sample to be reused for multiple diagnostic purposes, maximizing the utility of limited biopsy materials.

Inventive Principle:
Principle #34Discarding and recovering

2Quantity of substance

If multiple targets are analyzed using IHC or FISH on separate tissue sections, then molecular characterization is achieved, but limited sample size restricts the ability to perform various analyses on the same sample

Engineering Contradiction:
Improvesample sizeVSAvoidanalysis capability
Core Design Contradiction:
Quantity of substanceVSAdaptability or versatility

Solution Approach 1:

The patent makes a single tissue section serve multiple functions by first performing H&E staining for morphological assessment, then removing the stain to enable subsequent IHC and FISH analyses. This multi-functional use of the same tissue section maximizes the diagnostic information obtained from limited biopsy samples.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The patent performs H&E staining and initial morphological assessment as a preliminary action before removing the stain for molecular analyses. This allows the tissue to be evaluated for both morphological and molecular characteristics in sequence, ensuring comprehensive diagnostic workup from a single sample.

Inventive Principle:
Principle #10Preliminary action

3Adaptability or versatility

If H&E stains are removed from tissue sections to enable IHC and FISH, then molecular analysis feasibility is improved, but residual eosin fluorescence prevents IF and FISH detection

Engineering Contradiction:
Improvemolecular analysis feasibilityVSAvoidresidual fluorescence
Core Design Contradiction:
Adaptability or versatilityVSObject-generated harmful factors

Solution Approach 1:

The patent uses strong oxidizing agents, particularly hydrogen peroxide, to treat the tissue sections after H&E staining removal. This oxidation process effectively eliminates residual eosin fluorescence that would otherwise interfere with fluorescence-based IHC and FISH detections, enabling clear fluorescence signal detection.

Inventive Principle:
Principle #38Strong oxidants (Accelerated oxidation)

Solution Approach 2:

The patent converts the harmful residual eosin fluorescence into a benefit by using it as a target for oxidation. The hydrogen peroxide treatment specifically addresses the fluorescence interference problem, transforming the previously harmful residual stain into a non-interfering state that allows successful fluorescence-based molecular analyses.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables the effective removal of H&E signals, enabling subsequent IHC and FISH analyses on the same tissue section, facilitating detailed molecular characterization and targeted therapy selection for cancer patients.

Implementation Method 1

photo-induced chemical bleaching (PICB) agents

Methodology Applied
Scientific EffectPhoto-induced chemical bleaching: Photo-oxidation

Implementation Method 2

hydrogen peroxide with metal salts

Methodology Applied
Scientific EffectHydroxyl radical generation: Oxidation

Implementation Method 3

charge transfer agents

Methodology Applied
Scientific EffectCharge transfer: Electron Paramagnetic Resonance

Data Source

PatentEP2965087B1Methods of analyzing an h&e stained biological sample
Publication Date: 2018.10.17 GENERAL ELECTRIC CO
  • EP2965087B1 patent drawingFigure 1~2
  • EP2965087B1 patent drawingFigure 3A~3B
  • EP2965087B1 patent drawingFigure 4

AI summary

Methods comprising probing multiple targets in an H&E stained biological sample are provided. The methods include the steps of providing a hematoxylin and eosin stained biological sample containing multiple targets, optionally detecting H&E staining of the sample, removing the hematoxylin and eosin signals, and detecting additional features or targets in the biological sample. The detecting step may include performing the steps of binding at least one probe to one or more targets to the sample, detecting a signal from the probe and contacting the sample with a bleaching agent. The process of binding, detecting and bleaching may be iteratively repeated.