Hydrogen Evolution Assisted Electroplating Nozzle for Rapid Circuit Prototyping

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Solution Overview

Problem

Current 3D printing methods struggle to efficiently prototype electronic circuits due to unsuitable patterning methods for sensitive circuits, high costs, and the challenge of soldering electronic components on low-melting-point plastic substrates without damaging the structure.

Innovation Solution

The development of a hydrogen evolution assisted (HEA) electroplating method for rapid and localized electrochemical copper deposition in 3D printed structures, enabling the direct integration of electronic circuits into larger 3D printed structures and allowing for low-temperature soldering of surface mount electronic devices.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional electroplating methods are used for copper deposition in 3D printed structures, then the process is compatible with existing technology, but the deposition rate is slow and inefficient

Engineering Contradiction:
Improvedeposition rateVSAvoidtime for copper deposition
Core Design Contradiction:
ProductivityVSLoss of time

Solution Approach 1:

The patent changes the electrochemical parameters by applying a high current density (10-100 mA/cm²) to enable hydrogen evolution reaction alongside copper deposition. This parameter change transforms the conventional slow electroplating process into a rapid HEA electroplating process, achieving deposition rates up to 100 times faster than conventional methods while maintaining copper layer quality

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent replaces the conventional mechanical/electrical electroplating system with an electrochemical system that utilizes hydrogen evolution reaction. By substituting the traditional pure copper ion reduction mechanism with a hydrogen-assisted electrochemical process, the system achieves dramatically enhanced deposition rates without requiring complex mechanical adjustments

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Reliability

If conventional soldering methods are used on 3D printed plastic substrates, then electronic components can be soldered, but the high temperature damages the plastic structure

Engineering Contradiction:
Improvesoldering reliabilityVSAvoidthermal damage to plastic substrate
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent introduces a copper layer as an intermediary between the plastic substrate and electronic components. This copper intermediary serves dual purposes: it provides a thermally stable surface for reliable soldering while protecting the underlying plastic substrate from direct exposure to high soldering temperatures, thus preventing thermal damage

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent performs preliminary copper deposition on the plastic substrate before soldering electronic components. This preliminary action creates a thermal barrier layer that protects the plastic from subsequent high-temperature soldering processes, enabling reliable component attachment without substrate damage

Inventive Principle:
Principle #10Preliminary action

3Ease of manufacture

If existing patterning methods are used for conductive materials in 3D printed structures, then circuits can be formed, but the methods are either not suitable for sensitive electronic circuits or too expensive

Engineering Contradiction:
Improvepatterning feasibilityVSAvoidsuitability for sensitive circuits
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent utilizes the 3D printed conductive tracks themselves as the cathode substrate for copper deposition. The printed tracks serve dual functions: as the structural support and as the electrochemical substrate for metal deposition. This self-service approach eliminates the need for separate expensive patterning processes while ensuring compatibility with sensitive circuits through precise localized deposition

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The HEA electroplating method significantly enhances the deposition rate, enabling fast printing of copper tracks and reliable soldering of electronic components at room temperature, thus overcoming the limitations of existing 3D printing technologies for electronic circuit prototyping.

Implementation Method 1

rapid and localized electrochemical copper deposition

Methodology Applied
Scientific EffectElectrochemical deposition: Electrodeposition

Implementation Method 2

hydrogen evolution assisted (HEA) electroplating

Methodology Applied
Scientific EffectHydrogen evolution reaction: Electrolysis

Implementation Method 3

electrolyte and anode, the inner coaxial tube configured to dispense the electrolyte

Methodology Applied
Scientific EffectElectrical conduction: Conduction (electrical)

Data Source

PatentUS12320028B2Electrochemical three-dimensional printing and soldering
Publication Date: 2025.06.03 UNIV OF SOUTH FLORIDA
  • US12320028B2 patent drawing
  • US12320028B2 patent drawing
  • US12320028B2 patent drawing

AI summary

A hydrogen evolution assisted electroplating nozzle includes a nozzle tip configured to interface with a portion of a substructure. The nozzle also includes an inner coaxial tube connected to a reservoir containing an electrolyte and an anode, the inner coaxial tube configured to dispense the electrolyte through the nozzle tip onto the portion of the substructure. The nozzle also includes an outer coaxial tube encompassing the inner coaxial tube, the outer coaxial tube configured to extract the electrolyte from the portion of the substructure. The nozzle also includes at least one contact pin configured to make electrical contact with a conductive track on the substrate.