Headspace Gas Oxygen Measurement via Circulating Pump and Sensor Unit

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Solution Overview

Problem

Current methods for measuring oxygen content in the headspace of beverage containers are inefficient, often requiring complex procedures, are temperature-dependent, and struggle with foaming liquids, leading to inaccurate or incomplete oxygen content determination.

Innovation Solution

A method and device that circulate headspace gas through a sensor unit using a pump, allowing for precise measurement of oxygen content and partial pressure without direct sensor insertion, and includes features like foam handling and temperature adjustment to improve measurement accuracy.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If the oxygen content in headspace gas is measured by introducing a sensor directly into the headspace, then the measurement can be performed directly, but the measurement is highly temperature-dependent and requires precise temperature measurement which is difficult to place due to lack of space

Engineering Contradiction:
Improvedirect measurement capabilityVSAvoidtemperature dependency
Core Design Contradiction:
Ease of operationVSMeasurement precision

Solution Approach 1:

The sensor is extracted from the headspace environment and placed in an external measurement chamber. The headspace gas is sampled and introduced into this chamber for measurement, separating the sensor from the temperature-fluctuating headspace environment while maintaining measurement capability

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

A measurement chamber serves as an intermediary between the headspace gas and the oxygen sensor. This chamber provides a controlled environment for the sensor while allowing headspace gas to be introduced for analysis, decoupling the sensor from direct exposure to headspace temperature variations

Inventive Principle:
Principle #24Intermediary (Mediator)

2Device complexity

If headspace gas is measured without flow, then the measurement setup is simple, but the sensor adjustment is very slow or does not take place completely

Engineering Contradiction:
Improvemeasurement setup simplicityVSAvoidsensor adjustment time
Core Design Contradiction:
Device complexityVSLoss of time

Solution Approach 1:

A pump continuously circulates headspace gas through the measurement chamber and back to the container. This continuous flow ensures constant supply of fresh gas to the sensor, maintaining steady-state conditions and enabling complete sensor adjustment without interruption

Inventive Principle:
Principle #20Continuity of useful action

Solution Approach 2:

A pumping system creates controlled gas flow through the measurement chamber. The pump forces headspace gas to circulate continuously through the sensor, ensuring adequate flow for proper sensor adjustment and measurement while maintaining system simplicity

Inventive Principle:
Principle #29Pneumatics and hydraulics

3Quantity of substance

If only a few milliliters of headspace gas are available, then the sampling is minimal, but it becomes difficult to flow the headspace gas past the oxygen sensor and achieve stable adjustment

Engineering Contradiction:
Improveheadspace gas volumeVSAvoidsensor adjustment stability
Core Design Contradiction:
Quantity of substanceVSMeasurement precision

Solution Approach 1:

The pump creates a continuous circulation loop that repeatedly passes the limited headspace gas volume through the measurement chamber. This continuous recycling allows the sensor to adjust progressively using the same small gas sample, achieving stable measurements without requiring large gas volumes

Inventive Principle:
Principle #20Continuity of useful action

Solution Approach 2:

The measurement chamber serves multiple functions: it accommodates the oxygen sensor, provides a controlled measurement environment, and enables continuous circulation of limited headspace gas through the pump system, maximizing the utility of small gas volumes

Inventive Principle:
Principle #6Universality (Multi-functionality)

4Measurement precision

If the measurement is performed by chemical method using soda solution, then the oxygen content can be calculated, but the method cannot be automated and requires exact knowledge of headspace gas composition

Engineering Contradiction:
Improveoxygen content determinationVSAvoidmanual operation requirement
Core Design Contradiction:
Measurement precisionVSExtent of automation

Solution Approach 1:

The manual chemical absorption method is replaced with an electronic oxygen sensor that directly measures oxygen content. The pump-based gas circulation system automates the sample handling and delivery, eliminating manual operations while providing direct electrical measurement of oxygen concentration

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The oxygen sensor automatically detects and measures the oxygen content in the circulated headspace gas without requiring external intervention. The system self-regulates the measurement process through continuous gas circulation and automatic sensor reading, eliminating the need for manual calculation based on gas composition assumptions

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables precise and efficient determination of oxygen content in headspace gas, independent of temperature and volume, with improved handling of foaming liquids, ensuring accurate and reliable results.

Implementation Method 1

the headspace gas in the headspace of the container is pumped to a sensor unit containing a number of sensors, by means of a pump via the sampling tube and/or the hollow piercer

Methodology Applied
Scientific EffectPumping: Pump

Implementation Method 2

the oxygen content and/or the oxygen partial pressure and especially the headspace volume of the headspace gas is determined by the sensor unit

Methodology Applied
Scientific EffectOxygen sensing:

Data Source

PatentUS11726009B2Method and device for measuring the oxygen content of the headspace gas in a container
Publication Date: 2023.08.15 ANTON PAAR GMBH
  • US11726009B2 patent drawing

AI summary

A device determines an oxygen content of a headspace gas in a liquid-filled container. The device contains a piercer, a sampling tube, a piercing head on which the piercer and the sampling tube are disposed, a pump, a ring line, and a sensor unit disposed within the ring line and used to determine the oxygen content and/or an oxygen partial pressure of the headspace gas of the liquid-filled container. The ring line is configured such that the headspace gas of the liquid-filled container can be sampled via the piercer or the piercing head by use of the pump and can be returned into the headspace of the liquid-filled container via the sampling tube.