Heat Cycle Circuit Protection for HFO-1123 Decomposition Risk

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Solution Overview

Problem

Trifluoroethylene (HFO-1123) used as a working fluid in heat cycles undergoes self-decomposition at high temperatures or high pressures, posing risks during abnormal operation states.

Innovation Solution

A heat cycle system with a current-limiting apparatus that limits current within milliseconds upon abnormal operation, suppressing energy from spark sources to prevent self-decomposition, and using a working fluid composition with HFO-1123 in excess of 50% and optional components like difluoromethane and 2,3,3,3-tetrafluoro-1-propene to maintain low global warming potential and refrigerating capacity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If HFO-1123 is used as a working fluid for heat cycle, then global warming influence is reduced and cycle performance is improved, but self-decomposition reaction occurs at high temperature or high pressure

Engineering Contradiction:
Improveglobal warming influenceVSAvoidself-decomposition resistance
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

A current-limiting apparatus is introduced as an intermediary protective device in the electrical circuit of the compressor. This apparatus limits the current to 6A or less within 6 milliseconds when abnormal operation is detected, preventing spark-induced self-decomposition of HFO-1123 while allowing normal operation to proceed

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The current-limiting apparatus is configured to act preemptively by detecting abnormal operation states (such as excessive current or voltage) and limiting the current before a dangerous spark can occur. This preliminary protective action prevents the self-decomposition reaction from initiating in the first place

Inventive Principle:
Principle #10Preliminary action

2Reliability

If current-limiting apparatus is added to prevent self-decomposition, then safety is improved, but device complexity increases

Engineering Contradiction:
Improveself-decomposition preventionVSAvoidelectrical circuit complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The current-limiting apparatus is designed to operate automatically based on pre-set parameters (6A current limit, 6ms response time). When abnormal conditions are detected, the apparatus self-activates to limit the current without requiring external control systems, microprocessors, or complex control logic, thereby maintaining system simplicity while providing effective protection

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The system effectively prevents self-decomposition of HFO-1123 during abnormal operations, ensuring safe and efficient heat cycle performance while minimizing global warming impact.

Implementation Method 1

trifluoroethylene (HFO-1123) is known to undergo self-decomposition with an ignition source at high temperature or under high pressure

Methodology Applied
Scientific EffectSelf-decomposition reaction: Decomposition (biological)

Implementation Method 2

suppressing an energy which the working fluid for heat cycle receives from a spark energy generated in the heat cycle system

Methodology Applied
Scientific EffectSpark energy: Electric Spark

Data Source

PatentUS10830518B2Heat cycle system
Publication Date: 2020.11.10 AGC INC
  • US10830518B2 patent drawing
  • US10830518B2 patent drawing
  • US10830518B2 patent drawing

AI summary

A heat cycle system with high durability, which employs a working fluid for heat cycle containing trifluoroethylene having a low global warming potential. A heat cycle system, having a circulation path in which a working fluid for heat cycle containing trifluoroethylene is circulated from a compressor via a condenser, an expansion valve and an evaporator to the compressor, wherein the compressor has in its electrical circuit a current-limiting apparatus capable of limiting the current within 6 milliseconds after the heat cycle system enters into an abnormal operation state.