Heat Exchanger Coating Composition for Durable Antisoiling Control

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Solution Overview

Problem

Existing methods for suppressing dirt adhesion on air conditioner heat exchangers are inefficient due to high labor requirements, limited applicability, and insufficient durability, and they fail to maintain antisoiling performance over time, leading to condensation splash issues.

Innovation Solution

A coating composition comprising ultrafine silica particles and fluororesin particles dispersed in water with specific mass ratios, forming a coating film that balances hydrophilic and hydrophobic portions to prevent dirt adhesion and condensation splash, while maintaining the appearance and texture of the surface.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If hydrophilic polymer or water glass treatment is applied to fin surfaces to prevent water bridge formation, then condensation splash is prevented, but dirt adhesion increases and hydrophilicity deteriorates over time

Engineering Contradiction:
Improvecondensation splashVSAvoidantisoiling performance durability
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The patent applies composite materials by combining hydrophilic inorganic particles (such as silica, alumina, or titania) with hydrophobic fluororesin particles to form a dual-functional coating film. This composite structure simultaneously provides hydrophilicity for preventing water bridge formation and hydrophobicity for suppressing dirt adhesion, resolving the contradiction between preventing condensation splash and maintaining long-term antisoiling performance

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent implements local quality by creating a coating film with microphase-separated structure where hydrophilic portions and hydrophobic portions are independently exposed in minute regions. The hydrophilic inorganic particles are distributed throughout the coating to provide water repellency, while hydrophobic fluororesin particles are positioned at the surface to prevent dirt adhesion, allowing each component to function in its optimal local environment

Inventive Principle:
Principle #3Local quality

2Reliability

If photocatalytic oxide and hydrophobic resin coating is applied to suppress dirt adhesion, then antisoiling performance improves, but photoirradiation requirement limits practical application

Engineering Contradiction:
Improveantisoiling performanceVSAvoidapplication condition limitation
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent extracts the photocatalytic oxide component from the coating system and replaces it with hydrophilic inorganic particles that do not require photoirradiation to maintain their hydrophilic properties. This extraction eliminates the limitation of requiring photoirradiation for practical application while maintaining the antisoiling performance through the hydrophobic fluororesin particles

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent changes the functional mechanism from photocatalytic activity requiring light irradiation to inherent hydrophilicity of inorganic particles that functions without external energy input. This parameter change in the activation condition makes the coating more practical for general application while maintaining effective antisoiling performance

Inventive Principle:
Principle #35Parameter changes

3Reliability

If conventional coating methods are used to suppress dirt adhesion, then initial antisoiling performance is achieved, but coating film peeling and deterioration occur over time

Engineering Contradiction:
Improveinitial antisoiling performanceVSAvoidcoating film durability
Core Design Contradiction:
ReliabilityVSDuration of action of stationary object

Solution Approach 1:

The patent utilizes porous materials by forming a coating film containing inorganic particles with porous structures that provide mechanical interlocking with the fin surface. This porous structure enhances coating adhesion and prevents peeling over time, while the particle morphology maintains the microphase-separated structure for sustained antisoiling performance

Inventive Principle:
Principle #31Porous materials

Solution Approach 2:

The patent applies preliminary action by using surface treatment methods such as plasma treatment or corona discharge before coating application to enhance the adhesion between the coating film and fin surface. This preliminary surface modification ensures long-term durability and prevents coating peeling, allowing the antisoiling performance to be maintained over extended periods

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The coating composition provides excellent antisoiling performance and durability, preventing dirt adhesion and condensation splash, and maintaining the surface's appearance and texture, making it suitable for various articles and heat exchangers.

Implementation Method 1

a coating film having a balanced hydrophilic and hydrophobic nature... preventing dirt adhesion

Methodology Applied
Scientific EffectHydrophobic interaction: Hydrophobe

Implementation Method 2

forming a film in which hydrophilic portions and hydrophobic portions are mutually independently exposed in a minute region... excellent antisoiling performance

Methodology Applied
Scientific EffectSurface energy reduction: Surface Tension

Data Source

PatentEP2112207B1Coating composition, coating method, heat exchanger and air conditioner
Publication Date: 2012.09.12 MITSUBISHI ELECTRIC CORP
  • EP2112207B1 patent drawingFigure 1~2
  • EP2112207B1 patent drawingFigure 3~4
  • EP2112207B1 patent drawingFigure 5~6

AI summary

The present invention provides a coating composition comprising ultrafine silica particles having an average particle diameter of 15 nm or less and fluororesin particles, in which ultrafine silica particle content is 0.1 to 5 mass%, and the mass ratio of the ultrafine silica particles to the fluororesin particles is 70:30 to 95:5. According to the coating composition of the present invention, there is provided a coating film which makes it possible to readily coat the surfaces of various articles without impairing the color tone and the texture and which is excellent in antisoiling performance and durability.